Robust palladium hydride catalyst for electrocatalytic formate formation with high co tolerance
A supported catalyst for reducing CO 2 is provided. The supported catalyst includes a plurality of support particles; and a plurality of catalyst particles disposed over each support particle. Characteristically, the catalyst particles has formula PdH x /C wherein x is 0.3 to 0.7. Methods for making the support particles and using the support particles to reduce carbon dioxide are also provided.
1. A supported catalyst comprising:
a plurality of support particles; and
a plurality of catalyst particles disposed over each support particle, the catalyst particles having formula PdH x /C wherein x is 0.3 to 0.7 and C is a carbon support, wherein the supported catalyst has a BET surface area from about 90 m 2 /g to 110 m 2 /g and wherein the plurality of catalyst particle includes kink sites, step sites, and terrace sites.
2. The supported catalyst of claim 1 , wherein the catalyst particles have formula PdH 0.5 /C.
3. The supported catalyst of claim 1 , wherein the support particles are carbon particles.
4. The supported catalyst of claim 1 , wherein the catalyst particles have an average particle diameter of about 1 to 10 nm.
5. The supported catalyst of claim 1 , wherein the catalyst particles have an average particle diameter of about 2.5 to 4 nm.
6. The supported catalyst of claim 1 , wherein the supported catalyst has a faradaic efficiently greater than 90% for formate at −0.4 V (vs RHE) after 4 hours of initial operation.
7. The supported catalyst of claim 1 , wherein the supported catalyst has a BET surface area greater than 100 m 2 /g.