Coated steel sheet
A pre-coated steel sheet includes a steel sheet precoated with a metallic coating, the coating including: 2.0 to 24.0% by weight of zinc; 1.1 to 7.0% by weight of silicon; optionally from 0.5 to 3.0% by weight of magnesium when the amount of silicon is between 1.1 and 4.0%, and optionally additional elements chosen from Pb, Ni, Zr or Hf, a content by weight of each additional element being less than 0.3% by weight, a balance being aluminum, unavoidable impurities and residual elements resulting from feeding ingots or from a passage of the steel sheet in a molten bath; a ratio Al/Zn by weight greater than 2.9, wherein the coating does not include In and the coating does not include Sn.
1. A heat treatable coated steel sheet, comprising a steel sheet coated with a metallic coating, the coating including:
2.0 to 24.0% by weight of zinc;
1.1 to 2% by weight of silicon;
and optionally additional elements chosen from Pb, Ni, Zr or Hf, a content by weight of each additional element being less than 0.3% by weight,
a balance being aluminum, unavoidable impurities and residual elements resulting from feeding ingots or from a passage of the steel sheet in a molten bath;
a ratio Al/Zn by weight greater than 2.9;
a ratio Zn/Si by weight between 2.9 and 8; and
wherein the coating is free from magnesium, does not include In and does not include Sn;
wherein the steel sheet has a base with a composition by weight percentage including 0.20%≤C≤0.25%; 0.15%≤Si≤0.35%; 1.10%≤Mn≤1.40%; 0%≤Cr≤0.30%; 0%≤Mo≤0.35%; 0%≤P≤0.025%; 0%≤S≤0.005%; 0.020%≤Ti≤0.060%; 0.020%≤Al≤0.060%; 0.002%≤B≤0.004%, a balance of the steel sheet base composition being iron and unavoidable impurities from the manufacture of steel;
wherein the coated steel sheet is heat treatable in a furnace under non protective atmosphere at an austenitization temperature between 84° and 950° C. and a dwell time between 1 and 12 minutes and is suitable for hot forming at a temperature between 60° and 830° C.
2. The coated steel sheet according to claim 1 , wherein the coating comprises at least one of the additional elements chosen from Pb, Ni, Zr, or Hf.
3. The coated steel sheet according to claim 1 , wherein the ratio Al/Zn is between 5 and 9.
4. The coated steel sheet according to claim 1 , wherein the coating comprises from 1.5 to 2% 3.5% by weight of silicon.
5. The coated steel sheet according to claim 4 , wherein the coating comprises from 5.0 to 10.0% by weight of zinc.
6. The coated steel sheet according to claim 1 , wherein the coating comprises from 5.0 to 19.0% by weight of zinc.
7. The coated steel sheet according to claim 1 , wherein the coating comprises from 5.0 to 15.0% by weight of zinc.
8. The coated steel sheet according to claim 1 , wherein the coating comprises from 5.0 to 10.0% by weight of zinc.
9. The coated steel sheet according to claim 1 , wherein the coating comprises greater than 71% by weight of aluminum.
10. The coated steel sheet according to claim 1 , wherein the coating comprises greater than 76% by weight of aluminum.
11. The coated steel sheet according to claim 1 , wherein a thickness of the coating is between 5 and 50 μm.
12. The coated steel sheet according to claim 11 , wherein the thickness is between 10 and 35 μm.
13. The coated steel sheet according to claim 11 , wherein the thickness is between 12 and 18 μm.
14. The coated steel sheet according to claim 11 , wherein the thickness is between 26 and 31 μm.
15. The coated steel sheet according to claim 1 , wherein the coating does not comprise elements selected among Cr, Mn, Ti, Ce, La, Nd, Pr, Ca, Bi, In, Sn and Sb or combinations thereof.
16. The coated steel sheet according to claim 1 wherein the steel sheet has a base made of 22MnB5 steel.
17. The coated sheet according to claim 1 , wherein the coated steel sheet, after said heat treatment and after a subsequent hot stamping, exhibits microcracks, and no microcrack has a depth greater than 50 μm.
18. The coated sheet according to claim 1 , wherein the coated steel sheet, after said heat treatment and after a subsequent hot stamping, exhibits microcracks having a depth between 0 and 50 μm.
19. The coated sheet according to claim 1 , wherein the ratio Al/Zn is 5.6 or less.
20. The coated sheet according to claim 1 , wherein the metallic coating has a ratio Al/Zn between 5.3 and 8.8%, and a ratio Zn/Si by weight between 3 and 7.5.
21. A heat treatable coated steel sheet, comprising a steel sheet coated with a metallic coating, the coating including:
2.0 to 24.0% by weight of zinc;
1.1 to 2% by weight of silicon;
and optionally additional elements chosen from Pb, Ni, Zr or Hf, a content by weight of each additional element being less than 0.3% by weight,
a balance being aluminum, unavoidable impurities and residual elements resulting from feeding ingots or from a passage of the steel sheet in a molten bath;
a ratio Al/Zn by weight greater than 2.9;
a ratio Zn/Si by weight between 2.9 and 8; and
wherein the coating is free from magnesium, does not include In and does not include Sn;
wherein the steel sheet has a base with a composition by weight percentage including: 0.24%≤C≤0.38%; 0.40%≤Mn≤3%; 0.10%≤Si≤0.70%; 0.015%≤Al≤0.070%; 0%≤Cr≤2%; 0.25%≤Ni≤2%; 0.020%≤Ti≤0.10%; 0%≤Nb≤0.060%; 0.0005%≤B≤0.0040%; 0.003%≤N≤0.010%; 0.0001%≤S≤0.005%; 0.0001%≤P≤0.025%; it being understood that the contents of titanium and nitrogen satisfy Ti/N>3.42, and that the contents of carbon, manganese, chromium and silicon satisfy 2.6C+Mn/5.3+Cr/13+Si/15≥1.1%, the composition optionally comprising one or more of the following: 0.05%≤Mo≤0.65%; 0.001%≤W≤0.30%; 0.0005%≤Ca≤0.005%, a balance of the steel sheet base composition being iron and unavoidable impurities from manufacture;
wherein the coated steel sheet is heat treatable in a furnace under non protective atmosphere at an austenitization temperature between 84° and 950° C. and a dwell time between 5 and 10 minutes and is suitable for hot forming at a temperature between 60° and 830° C.
22. The coated sheet according to claim 21 , wherein the coating comprises greater than 71% by weight of aluminum.
23. The coated sheet according to claim 22 , wherein the coating comprises greater than 76% by weight of aluminum.
24. The coated sheet according to claim 21 , wherein the coated steel sheet, after said heat treatment and after a subsequent hot stamping, exhibits microcracks, and no microcrack has a depth greater than 50 μm.
25. The coated sheet according to claim 21 , wherein the ratio Al/Zn is 5.6 or less.
26. The coated sheet according to claim 21 , wherein the metallic coating has a ratio Al/Zn between 5.3 and 8.8%, and a ratio Zn/Si by weight between 3 and 7.5.
27. A heat treatable coated steel sheet, comprising a steel sheet coated with a metallic coating, the coating including:
2.0 to 24.0% by weight of zinc;
1.1 to 2% by weight of silicon;
and optionally additional elements chosen from Pb, Ni, Zr or Hf, a content by weight of each additional element being less than 0.3% by weight,
a balance being aluminum, unavoidable impurities and residual elements resulting from feeding ingots or from a passage of the steel sheet in a molten bath;
a ratio Al/Zn by weight greater than 2.9;
a ratio Zn/Si by weight between 2.9 and 8; and
wherein the coating is free from magnesium, does not include In and does not include Sn;
wherein the steel sheet has a base with a composition by weight percentage including: 0.040%≤C≤0.100%; 0.80%≤Mn≤2.00%; 0%≤Si≤0.30%; 0%≤S≤0.005%; 0%≤P≤0.030%; 0.010%≤Al≤0.070%; 0.015%≤Nb≤0.100%; 0.030%≤Ti≤0.080%; 0%≤N≤0.009%; 0%≤Cu≤0.100%; 0%≤Ni≤0.100%; 0%≤Cr≤0.100%; 0%≤Mo≤0.100%; 0%≤Ca≤0.006%, a balance of the steel sheet base composition being iron and unavoidable impurities from manufacture;
wherein the coated steel sheet is heat treatable in a furnace under non protective atmosphere at an austenitization temperature between 84° and 950° C. and a dwell time between 5 and 10 minutes and is suitable for hot forming at a temperature between 60° and 830° C.
28. The coated sheet according to claim 27 , wherein the coated steel sheet, after said heat treatment and after a subsequent hot stamping, exhibits microcracks, and no microcrack has a depth greater than 50 μm.
29. The coated sheet according to claim 27 , wherein the ratio Al/Zn is 5.6 or less.
30. The coated sheet according to claim 27 , wherein the metallic coating has a ratio Al/Zn between 5.3 and 8.8%, and a ratio Zn/Si by weight between 3 and 7.5.
31. A heat treatable coated steel sheet, comprising a steel sheet coated with a metallic coating, the coating including:
2.0 to 24.0% by weight of zinc;
1.1 to 7.0% by weight of silicon;
and optionally additional elements chosen from Pb, Ni, Zr or Hf, a content by weight of each additional element being less than 0.3% by weight,
a balance being aluminum, unavoidable impurities and residual elements resulting from feeding ingots or from a passage of the steel sheet in a molten bath;
a ratio Al/Zn by weight between 8.6 and 9;
a ratio Zn/Si by weight between 2.9 and 8; and
wherein the coating is free from magnesium, does not include In and does not include Sn,
the thickness of the coating is between 10 and 35 μm, and
the coated steel sheet is heat treatable in a furnace under non protective atmosphere at an austenitization temperature between 84° and 950° C. and a dwell time between 1 and 12 minutes and is suitable for hot forming at a temperature between 60° and 830° C.
32. A heat treatable coated steel sheet, comprising a steel sheet coated with a metallic coating, the coating including:
15 to 24.0% by weight of zinc;
1.1 to 7.0% by weight of silicon;
and optionally additional elements chosen from Pb, Ni, Zr or Hf, a content by weight of each additional element being less than 0.3% by weight,
a balance being aluminum, unavoidable impurities and residual elements resulting from feeding ingots or from a passage of the steel sheet in a molten bath;
a ratio Al/Zn by weight greater than 2.9;
a ratio Zn/Si by weight between 5 and 8; and
wherein the coating is free from magnesium, does not include In and does not include Sn,
the thickness of the coating is between 10 and 35 μm, and
the coated steel sheet is heat treatable in a furnace under non protective atmosphere at an austenitization temperature between 84° and 950° C. and a dwell time between 1 and 12 minutes and is suitable for hot forming at a temperature between 60° and 830° C.