Solid electrolytic capacitor element and solid electrolytic capacitor
A solid electrolytic capacitor element includes an anode body, a dielectric layer disposed on a surface of the anode body, and a cathode part covering at least a part of the dielectric layer are provided. The cathode part includes a solid electrolyte layer covering the at least the part of the dielectric layer. The solid electrolyte layer contains a first polymer and a second polymer component. The first polymer component includes a monomer unit corresponding to a thiophene compound. The second polymer component includes a polymer anion. A Raman spectrum of a surface layer in the solid electrolyte layer has a peak characteristic for the first polymer component.
1. A solid electrolytic capacitor element comprising:
an anode body;
a dielectric layer disposed on a surface of the anode body; and
a cathode part covering at least a part of the dielectric layer,
wherein:
the cathode part includes a solid electrolyte layer covering the at least the part of the dielectric layer,
the solid electrolyte layer contains a first polymer component and a second polymer component, the first polymer component including a monomer unit corresponding to a thiophene compound, the second polymer component including a polymer anion,
a weight-average molecular weight of the polymer anion ranges from 300 to 250,000, inclusive, and
a Raman spectrum of a surface layer in the solid electrolyte layer has a peak characteristic for the first polymer component.
2. The solid electrolytic capacitor element according to claim 1 , wherein the peak characteristic for the first polymer component includes a first peak observed at a wavenumber ranging from 1200 cm −1 to 1600 cm −1 , inclusive.
3. The solid electrolytic capacitor element according to claim 1 , wherein the peak characteristic for the first polymer component includes a second peak observed at a wavenumber ranging from 2750 cm −1 to 3000 cm −1 , inclusive.
4. The solid electrolytic capacitor element according to claim 1 , wherein the polymer anion includes a monomer unit M 1 corresponding to an organic sulfonic acid compound.
5. The solid electrolytic capacitor element according to claim 1 , wherein:
the peak characteristic for the first polymer component includes a first peak observed at a wavenumber ranging from 1200 cm −1 to 1600 cm −1 , inclusive,
the polymer anion includes a monomer unit M 2 corresponding to an aromatic sulfonic acid compound,
the Raman spectrum of the surface layer in the solid electrolyte layer has a third peak characteristic for the polymer anion, the third peak being observed at a wavenumber ranging from 800 cm −1 to 1050 cm −1 , inclusive, and
a ratio (=I p1 /I p3 ) of an intensity I p1 of the first peak to an intensity I p3 of the third peak is 2 or more.
6. The solid electrolytic capacitor element according to claim 1 , wherein the first polymer component includes at least a monomer unit corresponding to a 3,4-ethylenedioxythiophene compound as the monomer unit corresponding to the thiophene compound.
7. The solid electrolytic capacitor element according to claim 1 , wherein:
the anode body includes an anode lead-out part and a cathode formation part, the anode lead-out part including a first end part of the anode body, the cathode formation part including a second end part of the anode body, and
in a cross section of the solid electrolytic capacitor element, a ratio T 1 /T 2 of a thickness T 1 of the solid electrolyte layer formed at a corner part of the anode body to a thickness T 2 of the solid electrolyte layer formed at a central part of a principal surface of the anode body is in a range from 0.8 to 1.7, inclusive, the cross section being taken at an arbitrary position in a part of the cathode part at a side close to the first end part and in a plain perpendicular to a direction from the first end part toward the second end part.
8. A solid electrolytic capacitor comprising the solid electrolytic capacitor element according to claim 1 .