Double-sided adhesive film
The purpose of the present invention is to provide a double-sided adhesive film which has a generally equal elongation in the XY (longitudinal and transverse) directions, more preferably in the thickness direction, while being prevented from the occurrence of adhesive protrusion or glue burr, and which has higher adhesive force and higher holding power in comparison to similar single-layer adhesive articles, while being applicable to a stretchable or flexible adherend. A double-sided adhesive film according to the present invention is a substrate-less double-sided adhesive film which is composed of a center layer that is formed of a resin adhesive, and adhesive layers that are superposed on the front surface and the back surface of the center layer, said adhesive layers being formed of a resin that is the same as or similar to the resin that constitutes the center layer, wherein the weight average molecular weight or the crosslinking degree of the resin that constitutes the center layer is higher than the weight average molecular weight or the crosslinking degree of the resin that constitutes the adhesive layers. This double-sided adhesive film is characterized in that the tolerance between the elongation in the longitudinal direction and the elongation in the transverse direction is ±20% or less relative to one of the elongations, more preferably, the elongation in the longitudinal direction and the elongation in the transverse direction are equal to each other.
1. A double-sided adhesive film without base, comprising:
a center layer formed of an adhesive made from a resin; and
adhesive layers laminated on a front face and a rear face of the center layer and formed of a resin that is same as or belongs to a same family as the resin that forms the center layer:
a weight average molecular weight and an extent of crosslinking of the resin that forms the center layer being higher than a weight average molecular weight and an extent of crosslinking of the resins that form the adhesive layers,
the film having a structure in which a gradient of the molecular weight and a gradient of the extent of crosslinking are produced in the interface region between the center layer and the adhesive layers, and
a tolerance between an elongation ratio in a longitudinal direction and an elongation ratio in a transverse direction being ±20% or less with respect to one elongation ratio.
2. The double-sided adhesive film according to claim 1 , wherein
the elongation ratios in both the longitudinal and transverse directions are in a range of 20% to 300%.
3. The double-sided adhesive film according to claim 1 , wherein
the double-sided adhesive film has a total thickness of from 5 μm to 300 μm.
4. The double-sided adhesive film according to claim 1 , wherein
a ratio between the elongation ratio of the resin that forms the center layer and the elongation ratio of the resin that forms the adhesive layers is from 1:1 to 1:20.
5. The double-sided adhesive film according to claim 1 , wherein
the center layer and the adhesive layers are not oriented.
6. The double-sided adhesive film according to claim 1 , wherein
molecules in the resin that forms the center layer and molecules in the resin that forms the adhesive layers are crosslinked in an interface region between the center layer and the adhesive layer.
7. The double-sided adhesive film according to claim 1 , wherein
each of the elongation ratios in the longitudinal direction, the transverse direction, and a thickness direction has a tolerance of ±20% or less with respect to the elongation ratios in the other two directions.
8. The double-sided adhesive film according to claim 1 , wherein
the center layer is formed of a resin selected from natural or synthetic rubber, acrylic resin, olefin resin, silicone resin, urethane resin, and polyester resin.
9. The double-sided adhesive film according to claim 1 , wherein
the adhesive layer laminated on the front face of the center layer and the adhesive layer laminated on the rear face of the center layer are formed of resins having different adhesive strengths.
10. The double-sided adhesive film according to claim 1 , wherein:
an electrically conductive material is added to the center layer and the adhesive layers, and
a weight percentage of the electrically conductive material added to the center layer with respect to the resin that forms the center layer is higher than a weight percentage of the electrically conductive material added to the adhesive layers with respect to the resin that forms the adhesive layers.
11. The double-sided adhesive film according to claim 1 , wherein:
a thermally conductive material is added to the center layer and the adhesive layers, and
a weight percentage of the thermally conductive material added to the center layer with respect to the resin that forms the center layer is higher than a weight percentage of the thermally conductive material added to the adhesive layers with respect to the resin that forms the adhesive layers.
12. The double-sided adhesive film according to claim 1 , wherein
fiber fragments are dispersed in the center layer.
13. The double-sided adhesive film according to claim 2 , wherein
the double-sided adhesive film has a total thickness of from 5 μm to 300 μm.
14. The double-sided adhesive film according to claim 13 , wherein
a ratio between the elongation ratio of the resin that forms the center layer and the elongation ratio of the resin that forms the adhesive layers is from 1:1 to 1:20.
15. The double-sided adhesive film according to claim 5 , wherein
molecules in the resin that forms the center layer and molecules in the resin that forms the adhesive layers are crosslinked in an interface region between the center layer and the adhesive layer.
16. The double-sided adhesive film according to claim 4 , wherein
each of the elongation ratios in the longitudinal direction, the transverse direction, and a thickness direction has a tolerance of ±20% or less with respect to the elongation ratios in the other two directions.
17. The double-sided adhesive film according to claim 14 , wherein
each of the elongation ratios in the longitudinal direction, the transverse direction, and a thickness direction has a tolerance of ±20% or less with respect to the elongation ratios in the other two directions.
18. The double-sided adhesive film according to claim 6 , wherein
the adhesive layer laminated on the front face of the center layer and the adhesive layer laminated on the rear face of the center layer are formed of resins having different adhesive strengths.
19. The double-sided adhesive film according to claim 8 , wherein:
a thermally conductive material is added to the center layer and the adhesive layers, and
a weight percentage of the thermally conductive material added to the center layer with respect to the resin that forms the center layer is higher than a weight percentage of the thermally conductive material added to the adhesive layers with respect to the resin that forms the adhesive layers.
20. The double-sided adhesive film according to claim 8 , wherein
fiber fragments are dispersed in the center layer.