Granted Patent B1

US 12,366,534 · App. 19/189,730 · Granted Jul 22, 2025

Inventors: Abdulaziz Abdulrahman Al-Saadi (Dhahran, SA); Sathiyamoorthy Murugesan (Dhahran, SA); Muhammad Haroon (Dhahran, SA); Tawfik A. Saleh (Dhahran, SA)

Assignee: KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS

G01N21/658B22F1/056B22F1/18B22F2301/255B22F2304/056B22F2304/058G01N2201/06113

Abstract

Claims (23)

1. A surface-enhanced Raman scattering (SERS) substrate for fuel oil analysis, comprising:

a transparent substrate; and

a nanocomposite composition comprising:

a silver-loaded silica (Ag—SiO 2 ) nanocomposite having a silica core and a silver/silica shell disposed around the silica core; and

a zeolitic material having a nano porous structure;

wherein the silver/silica shell contains silver nanoparticles uniformly distributed therein;

wherein the Ag—SiO 2 nanocomposite is uniformly disposed on a surface of the zeolitic material;

wherein the nanoparticles of the Ag—SiO 2 nanocomposite are spherical and have a mean particle size of 250 to 350 nanometers (nm);

wherein the silver/silica shell of the Ag—SiO 2 nanocomposite has a mean thickness of 50 to 350 nm and the silver nanoparticles in the silver/silica shell of the Ag—SiO 2 nanocomposite have a mean particle size of 10 to 50 nm; and

wherein the SERS substrate has a specific surface area in a range of 150 to 300 m 2 /g, a cumulative specific pore volume in a range of 0.2 to 0.3 cm 3 /g, and an average pore diameter of 4 to 7 nm.

2. The SERS substrate of claim 1 , wherein the silver nanoparticles are at least one selected from the group consisting of nanospheres, nanorods, nanostars, nanotriangles, nanoprisms, nanocubes, nanofibers, nanoplates, nanowires, nanotetrahedrons, nanocrystals, nanohexagons, nanodisks, nanoribbons, nanocylinders, nanogranules, nanowhiskers, nanoflakes, nanofoils, nanopowders, nanoholes, nanobelts, nanourchins, nanoflowers, nanoislands, and nanomeshes.

3. The SERS substrate of claim 1 , wherein the Ag—SiO 2 nanocomposite has:

a specific surface area in a range of 10 to 100 square meter per gram (m 2 /g); and

a cumulative specific pore volume in a range of 0.1 to 0.15 cubic centimeter per gram (cm 3 /g).

4. The SERS substrate of claim 1 , wherein the Ag—SiO 2 nanocomposite comprises from about 5 to 25 weight percentage (wt. %) of silver.

5. The SERS substrate of claim 1 , wherein a weight ratio of the silver-loaded silica nanocomposite to the zeolitic material in the nanocomposite ranges from about 1:5 to 5:1.

6. The SERS substrate of claim 1 , wherein the zeolitic material has a silicon-to-aluminum molar ratio of greater than 10:1.

7. The SERS substrate of claim 1 , wherein the zeolitic material has:

a specific surface area in a range of 300 to 400 m 2 /g;

a cumulative specific pore volume in a range of 0.15 to 0.2 cm 3 /g; and

an average pore diameter of 3 to 6 nm.

8. The SERS substrate of claim 1 , has a detection limit of 1×10 −9 molar (M) for a sulfur-containing compound.

9. The SERS substrate of claim 1 , wherein the transparent substrate comprises a glass substrate, and wherein the glass substrate is at least one selected from the group consisting of a fluorine doped tin oxide (FTO) coated glass substrate, a tin doped indium oxide (ITO) coated glass substrate, an aluminum doped zinc oxide (AZO) coated glass substrate, a niobium doped titanium dioxide (NTO) coated glass substrate, an indium doped cadmium oxide (ICO) coated glass substrate, an indium doped zinc oxide (IZO) coated glass substrate, a fluorine doped zinc oxide (FZO) coated glass substrate, a gallium doped zinc oxide (GZO) coated glass substrate, an antimony doped tin oxide (ATO) coated glass substrate, a phosphorus doped tin oxide (PTO) coated glass substrate, a zinc antimonate coated glass substrate, a zinc oxide coated glass substrate, a ruthenium oxide coated glass substrate, a rhenium oxide coated glass substrate, a silver oxide coated glass substrate, and a nickel oxide coated glass substrate.

Continuity (1)

References Cited (16)