Binder for secondary battery and secondary battery including the same
A binder for a secondary battery includes a copolymer having a first repeating unit, a second repeating unit, and a third repeating unit. A ratio of a number of the first repeating unit (A) and a sum of a number of the second repeating unit and a number of the third repeating unit (B) is 90:10 to 52:48. A ratio of the number of the second repeating unit and the number of the third repeating unit is 67:33 to 1:99. A weight average molecular weight of the copolymer is 225,000 to 2,000,000.
1. A binder for a secondary battery, comprising:
a copolymer having a first repeating unit represented by Chemical Formula 1 below, a second repeating unit represented by Chemical Formula 2 below, and a third repeating unit represented by Chemical Formula 3 below,
wherein a ratio of a number of the first repeating unit (A) and a sum of a number of the second repeating unit and a number of the third repeating unit (B) is 90:10 to 52:48,
a weight average molecular weight of the copolymer is 225 kDa to 2,000 kDa, and
wherein the copolymer has a pH value of 5 to 10, the pH value is measured at a condition of 15° C. to 25° C. for an aqueous solution containing the copolymer in 8% by weight based on a total weight of the aqueous solution;
wherein, in Chemical Formula 2, R 1 is hydrogen or an alkyl group having 1 to 5 carbon atoms;
wherein, in Chemical Formula 3, R 2 is hydrogen or an alkyl group having 1 to 5 carbon atoms,
M n+ is Li + , Na + , NH 4 + , Ca 2 + , Mg 2 + , Al 3 + or Ga 3 + , and
n is an integer of 1 to 3.
2. The binder for a secondary battery according to claim 1 , wherein a percentage of the number of the first repeating unit with respect to a sum of the number of the first repeating unit, the number of the second repeating unit, and the number of the third repeating unit is 65% to 85%.
3. The binder for a secondary battery according to claim 1 , wherein a ratio of the number of the second repeating unit and the number of the third repeating unit is 50:50 to 1:99.
4. The binder for a secondary battery according to claim 1 , wherein the copolymer is included in an amount of 10% to 100% with respect to a total weight of the binder, wherein the binder further comprises an organic based binder, an aqueous based binder or a thickener, when the amount of the copolymer is less than 100% with respect to a total weight of the binder.
5. The binder for a secondary battery according to claim 1 , wherein R 2 is hydrogen or a methyl group.
6. The binder for a secondary battery according to claim 1 , wherein the copolymer is a random copolymer.
7. An anode for a secondary battery, comprising:
an anode current collector;
an anode active material layer formed on the anode current collector and including the binder for a secondary battery according to claim 1 .
8. The anode for a secondary battery according to claim 7 , wherein the anode active material layer further includes an anode active material including a silicon-based active material.
9. The anode for a secondary battery according to claim 8 , wherein the anode active material further includes a carbon-based active material.
10. The anode for a secondary battery according to claim 9 , wherein the anode active material includes a mixture of the silicon-based active material and the carbon-based active material.
11. A secondary battery, comprising:
a cathode;
a separator; and
an anode facing the cathode with the separator interposed therebetween, and including an anode current collector and an anode active material layer formed on the anode current collector,
wherein the anode active material layer includes the binder for a secondary battery according to claim 1 , and an anode active material including a silicon-based active material.
12. The secondary battery according to claim 11 , wherein the anode active material further includes a carbon-based active material.
13. The secondary battery according to claim 11 , wherein the binder for a secondary battery is included in 0.5% to 40% with respect to a total weight of the anode active material layer.