Granted Patent B2

US 12,384,107 · App. 17/417,080 · Granted Aug 12, 2025

Inventors: Shannon Reuben Woodruff (San Diego, CA); Emre Hiro Discekici (San Diego, CA); Rachael Donovan (San Diego, CA); Carolin Fleischmann (San Diego, CA)

Assignee: Peridot Print LLC

B29C64/165B33Y10/00B33Y30/00B29K2077/00B29K2105/0044

Abstract

Claims (35)

1. A kit for three-dimensional (3D) printing, comprising:

a build material composition including:

a polyamide 6,13 material;

a phosphorus-containing antioxidant including tris(2,4-ditert-butylphenyl) phosphite or a phosphonate-based antioxidant; and

a sulfur-containing antioxidant including dilauryl thiodipropionate (DLTDP) or dioctadecyl 3,3′-thiodipropionate (DSTDP); and

a fusing agent to be applied to at least a portion of the build material composition during 3D printing, the fusing agent including a radiation absorber to absorb radiation to melt or fuse the build material composition in the at least the portion.

2. The kit as defined in claim 1 wherein the phosphorus-containing antioxidant is present in the build material composition in an amount ranging from about 0.2 wt % to about 0.8 wt %, based on a total weight of the build material composition.

3. The kit as defined in claim 1 wherein the sulfur-containing antioxidant is present in the build material composition in an amount ranging from about 0.2 wt % to about 2.4 wt %, based on a total weight of the build material composition.

4. A method for three-dimensional (3D) printing, comprising:

applying a build material composition to form a build material layer, the build material composition including:

a polyamide 6,13 material, a phosphorus-containing antioxidant including tris(2,4-ditert-butylphenyl) phosphite or a phosphonate-based antioxidant, and a sulfur-containing antioxidant including dilauryl thiodipropionate (DLTDP) or dioctadecyl 3,3′-thiodipropionate (DSTDP); or

a polyamide 6 material, the sulfur-containing antioxidant, and a phenolic antioxidant;

based on a 3D object model, selectively applying a fusing agent on at least a portion of the build material composition; and

exposing the build material composition to radiation to fuse the at least the portion to form a layer of a 3D part.

5. The method as defined in claim 4 wherein the build material composition includes the polyamide 6,13 material, the phosphorus-containing antioxidant, and the sulfur-containing antioxidant, and the method is accomplished in an environment containing air.

6. The method as defined in claim 4 wherein the build material composition includes the polyamide 6 material, the sulfur-containing antioxidant, and the phenolic antioxidant, and the method is accomplished in an environment containing 4 vol % or less of oxygen.

7. The method as defined in claim 4 wherein one of:

i) the build material composition includes the polyamide 6,13 material, the phosphorus-containing antioxidant, and the sulfur-containing antioxidant;

the phosphorus-containing antioxidant is present in the build material composition in an amount ranging from about 0.2 wt % to about 0.8 wt %, based on a total weight of the build material composition; and

the sulfur-containing antioxidant is present in the build material composition in an amount ranging from about 0.2 wt % to about 2.4 wt %, based on a total weight of the build material composition; or

ii) the build material composition includes the polyamide 6 material, the sulfur-containing antioxidant, and the phenolic antioxidant;

the phenolic antioxidant is present in the build material composition in an amount ranging from about 0.2 wt % to about 0.8 wt %, based on a total weight of the build material composition; and

the sulfur-containing antioxidant is present in the build material composition in an amount ranging from about 0.2 wt % to about 2.4 wt %, based on a total weight of the build material composition.

8. The method as defined in claim 4 , further comprising repeating the applying of the build material composition, the selectively applying of the fusing agent, and the exposing of the build material composition, wherein the repeating forms the 3D part including the layer.

9. The method as defined in claim 8 wherein the build material composition includes the polyamide 6,13 material, the phosphorus-containing antioxidant, and the sulfur-containing antioxidant, and the 3D part has an ultimate tensile strength greater than or equal to 50 MPa.

10. The method as defined in claim 8 wherein the build material composition includes the polyamide 6,13 material, the phosphorus-containing antioxidant, and the sulfur-containing antioxidant, and the 3D part has an elongation at break greater than or equal to 50%.

11. The method as defined in claim 8 wherein the build material composition includes the polyamide 6 material, the sulfur-containing antioxidant, and the phenolic antioxidant, and the 3D part has an ultimate tensile strength greater than or equal to 65 MPa.

12. The method as defined in claim 8 wherein the build material composition includes the polyamide 6 material, the sulfur-containing antioxidant, and the phenolic antioxidant, and the 3D part has an elongation at break greater than or equal to 5%.

13. The kit as defined in claim 1 wherein the sulfur-containing antioxidant and the phosphorus-containing antioxidant have an average particle size of about 5 μm or less.

14. The method as defined in claim 4 , wherein the sulfur-containing antioxidant and the phosphorus-containing antioxidant have an average particle size of about 5 μm or less.

15. The kit as defined in claim 1 wherein the build material composition consists of the polyamide 6,13 material, the phosphorus-containing antioxidant, and the sulfur-containing antioxidant.

16. The kit as defined in claim 15 wherein:

the phosphorus-containing antioxidant is present in an amount ranging from about 0.2 wt % to about 0.8 wt %, based on a total weight of the build material composition; and

the sulfur-containing antioxidant is present in an amount ranging from about 0.2 wt % to about 1.5 wt %, based on a total weight of the build material composition.

17. The kit as defined in claim 16 wherein the phosphorus-containing antioxidant is the phosphonate-based antioxidant and the sulfur-containing antioxidant is the dioctadecyl 3,3′-thiodipropionate.

Assignments (2)

Continuity (1)

References Cited (37)