Wastewater treatment process in production of nickel cobalt hydroxide
A wastewater treatment process in the production of nickel cobalt hydroxide includes the following steps: S 1 . subjecting a laterite nickel ore acid-leaching solution successively to iron-aluminum removal and nickel-cobalt precipitation to obtain wastewater; S 2 . subjecting the wastewater successively to chromium ions, manganese ions, and silicon ion removal treatments to obtain a suspension; and S 3 . reusing portion of the suspension and continuing iron-aluminum removal; subjecting the remaining suspension successively to homogenizing, alkali adjusting, standing still, CCD counter-current washing, and solid-liquid separation to obtain a supernatant and a residue phase, collecting the residue phase, and discharging the supernatant after neutralization. This method used to treat the laterite nickel ore wastewater can meet the discharge standard, with high safety.
1. A wastewater treatment process in the production of associated with nickel cobalt hydroxide production, comprising the following steps:
S1 subjecting a laterite nickel ore acid-leaching solution successively to iron-aluminum removal and nickel-cobalt precipitation to obtain wastewater;
S2 subjecting the wastewater successively to chromium ions, manganese ions, and silicon ion removal treatments to obtain a suspension; and
S3 reusing a portion of the suspension and continuing iron-aluminum removal; subjecting the remaining suspension successively to homogenizing, alkali adjusting, standing still, CCD counter-current washing, and solid-liquid separation to obtain a supernatant and a residue phase, collecting the residue phase, and discharging the supernatant after neutralization;
wherein the steps of chromium ion removal are as follows: adding a reducing agent to the wastewater to perform a reduction reaction, followed by precipitation and separation to obtain a primary liquid; the reducing agent is a biomass straw hydrolysate; the preparation method of the biomass straw hydrolysate is as follows: grinding biomass straw into powder, and then adding concentrated sulfuric acid for hydrolysis.
2. The wastewater treatment process associated with nickel cobalt hydroxide production according to claim 1 , wherein the number of CCD counter-current washing stages is 9 and the washing ratio is 2.0-2.5.
3. The wastewater treatment process associated with nickel cobalt hydroxide production according to claim 1 , wherein the steps of manganese ion removal are as follows: introducing a mixed gas of SO2 and air into the primary liquid, adjusting the pH of the primary liquid to 3-4 and the temperature to 30-80° C., precipitating, and separating to obtain a secondary liquid.
4. The wastewater treatment process associated with nickel cobalt hydroxide production according to claim 3 , wherein the steps of silicon ion removal are as follows: adjusting the pH of the secondary liquid to 1-2 at a pressure of 4.5-5.5 MPa and controlling the temperature to 150-200° C., precipitating, and separating to obtain the suspension.
5. The wastewater treatment process associated with nickel cobalt hydroxide production according to claim 1 , wherein in step S3, the reused suspension accounts for 20-30% of the total suspension by mass.
6. The wastewater treatment process associated with nickel cobalt hydroxide production according to claim 1 , wherein the step of iron-aluminum removal comprises a first stage iron-aluminum removal and a second stage iron-aluminum removal.
7. The wastewater treatment process associated with nickel cobalt hydroxide production according to claim 6 , wherein the process conditions for the first stage iron-aluminum removal comprise: controlling the temperature to 80-85° C. and the pH to 3.6-4.0.
8. The wastewater treatment process associated with nickel cobalt hydroxide production according to claim 6 , wherein the process conditions for the two-stage second stage iron-aluminum removal comprise: controlling the temperature to 75-80° C. and the pH to 4.6-5.0 by using NaOH.
9. The wastewater treatment process associated with nickel cobalt hydroxide production according to claim 1 , wherein the process conditions for nickel-cobalt precipitation comprise: adjusting the pH to 7.8-8.3 by using NaOH, adjusting the reaction temperature to 70° C., and the reaction time to 3-4 min.