X-ray fluorescence spectrometer
Provided is an X-ray fluorescence spectrometer that achieves a uniform state on a back side of a thin sheet-shaped sample so as to prevent a difference in a measurement condition depending on a measurement position. The X-ray fluorescence spectrometer includes: a sample stage a background correction cover, which is arranged adjacent to an outer side of the sample stage so that a surface of the background correction cover is substantially flush with a surface of the sample stage; and a moving mechanism. The moving mechanism moves the background correction cover based on movement of the sample stage and, when the sample stage is absent on a back side of the sample at a measurement position, moves the background correction cover so that the background correction cover is located on the back side of the sample at the measurement position.
1. An X-ray fluorescence spectrometer, comprising:
an X-ray source configured to radiate primary X-rays to a surface of a sheet-shaped sample;
a detector configured to measure an intensity of fluorescent X-rays emitted from the sample irradiated with the primary X-rays;
a sample stage on which the sample is to be placed;
an analysis unit configured to perform an analysis based on the intensity of the fluorescent X-rays, which has been measured by the detector, at a plurality of measurement positions on the surface of the sample;
at least one background correction cover, which has an outer edge portion with a shape extending along a part of an outer edge of the sample stage, and is arranged adjacent to an outer side of the sample stage so that a surface of the background correction cover is substantially flush with a surface of the sample stage; and
a moving mechanism configured to move the sample stage so that the primary X-rays are radiated to a freely-selected measurement position on the surface of the sample,
wherein the moving mechanism moves the background correction cover based on movement of the sample stage and, when the sample stage is absent on a back side of the sample at a measurement position, moves the background correction cover so that the background correction cover is located on the back side of the sample at the measurement position.
2. The X-ray fluorescence spectrometer according to claim 1 , wherein the background correction cover is made of the same material as a material of the sample stage.
3. The X-ray fluorescence spectrometer according to claim 1 , wherein the sample stage has a holding portion with a protruding shape to be brought into abutment against a part of the sample.
4. The X-ray fluorescence spectrometer according to claim 1 ,
wherein the moving mechanism includes:
a triple sun shaft to be rotationally driven;
a sun arm fixed to the triple sun shaft;
a double planetary shaft being rotatably supported at a rotating end portion of the sun arm;
a planetary arm fixed to the double planetary shaft; and
a sample shaft being rotatably supported at a rotating end portion of the planetary arm,
wherein the sample stage is fixed to the sample shaft, and
wherein the background correction cover is fixed to the planetary arm.
5. The X-ray fluorescence spectrometer according to claim 1 , wherein the moving mechanism includes:
an XY stage configured to move the sample stage in an XY plane being parallel to the surface of the sample stage and the surface of the background correction cover to such a position that the primary X-rays are radiated to the measurement position; and
a rotary mechanism configured to rotate the background correction cover about a center of the sample stage.
6. The X-ray fluorescence spectrometer according to claim 1 ,
wherein a distance from a center to the outer edge of the sample stage is smaller than a distance from a center to an outer edge of the sample, and
wherein a distance from the center of the sample stage to an end portion of the background correction cover is larger than the distance from the center to the outer edge of the sample.
7. The X-ray fluorescence spectrometer according to claim 1 , wherein the analysis unit includes a correction unit configured to perform a correction by subtracting a background intensity from the measured intensity measured by the detector.
8. The X-ray fluorescence spectrometer according to claim 1 ,
wherein the sample stage has a circular shape, and
wherein the outer edge portion of the background correction cover, which has a shape extending along the part of the outer edge of the sample stage, has an arc-like shape extending along the outer edge of the sample stage having the circular shape.
9. The X-ray fluorescence spectrometer according to claim 1 , further comprising a sample detecting unit configured to detect, when the sample has a circular shape with a cutout portion, a position of the cutout portion of the sample, which is arranged on an outer side of the outer edge of the sample stage.