Polyurethane foams with reduced aromatic amine content
Described herein is a process for producing polyurethane foams having a density of 30 g/dm 3 to 70 g/dm 3 , in which (a) aromatic polyisocyanate is mixed with (b) polymeric compounds having isocyanate-reactive groups, (c) optionally chain extender and/or crosslinking agent, (d) catalyst, (e) blowing agent including water, (f) 0.1% to 5% by weight of lactam, and (g) optionally additives, at an isocyanate index of 50 to 95 to form a reaction mixture, and the reaction mixture is converted to the polyurethane foam, wherein the catalyst includes metal catalyst and amine catalyst, and the amine catalyst has tertiary nitrogen atoms and the content of tertiary nitrogen atoms in the amine catalyst is from 0.0001 to 0.003 mol/100 g of foam. Also described herein is a polyurethane foam and a method of using such a flexible polyurethane foam for the production of cushions, seat cushions, or mattresses.
1. A process for producing polyurethane foams having a density of 30 g/dm 3 to 70 g/dm 3 , the process comprising mixing
a) aromatic polyisocyanate,
b) polymeric compounds having isocyanate-reactive groups,
c) optionally chain extender and/or crosslinking agent,
d) catalysts,
e) blowing agent comprising water,
f) lactam in an amount of 0.1% to 5% by weight, based on the total weight of components a) to f), and
g) optionally additives,
at an isocyanate index of 50 to 95 to form a reaction mixture, and
converting the reaction mixture to a flexible polyurethane foam,
wherein the catalysts comprise a metal catalyst and an amine catalyst, and the amine catalyst has tertiary nitrogen atoms and is used in such an amount that a content of tertiary nitrogen atoms in the amine catalyst is from 0.0001 to 0.002 mol/100 g of foam;
wherein the amine catalyst has at least one isocyanate-reactive group;
wherein the catalysts d) are used in amounts such that the reaction mixture has a gel or fiber time in a range of from 60 to 180 seconds;
wherein the reaction mixture is converted to the flexible polyurethane foam in a closed mold.
2. The process according to claim 1 , wherein the catalysts d) are used in amounts such that the reaction mixture has a rise time of 30 to 150 seconds.
3. The process according to claim 1 , wherein a content of water, based on components b) to f), is 1% to 5% by weight.
4. The process according to claim 1 , wherein no further blowing agents other than water are present.
5. The process according to claim 1 , wherein the lactam f) is ε-caprolactam.
6. The process according to claim 1 , wherein the amine catalyst has two tertiary nitrogen atoms.
7. The process according to claim 1 , wherein the tertiary nitrogen atoms of the amine catalyst have at least one methylene radical H 3 C— or ethylene radical H 3 C—H 2 C—.
8. The process according to claim 1 , wherein the amine catalyst is selected from the group consisting of bisdimethylaminopropylurea, bis(N,N-dimethylaminoethoxyethyl)carbamate, dimethylaminopropylurea, N,N,N-trimethyl-N-hydroxyethylbis(aminopropyl ether), N,N,N-trimethyl-N-hydroxyethylbis(aminoethyl ether), diethylethanolamine, bis(N,N-dimethyl-3-aminopropyl)amine, dimethylaminopropylamine, 3-dimethylaminopropyl-N,N-dimethylpropane-1,3-diamine, dimethyl-2-(2-aminoethoxyethanol) and (1,3-bis(dimethylamino)propan-2-ol), N,N-bis(3-dimethylaminopropyl)-N-isopropanolamine, bis(dimethylaminopropyl)-2-hydroxyethylamine, N,N,N-trimethyl-N-(3 aminopropyl)bis(aminoethyl ether), 3-dimethylaminoisopropyldiisopropanolamine, N-[2-[2-(dimethylamino)ethoxy]ethyl]-N-methyl-1,3-propanediamine, and mixtures thereof.
9. The process according to claim 1 , wherein the metal catalyst is a tin(IV) catalyst.
10. The process according to claim 1 , wherein the aromatic polyisocyanate comprises isomers and homologs of diphenylmethane diisocyanate.
11. The process according to claim 1 , wherein, for the preparation of the reaction mixture, an isocyanate component (A), comprising aromatic polyisocyanate (a), and a polyol component (B), comprising a mixture comprising polymeric compounds having isocyanate-reactive groups b), catalysts d), and blowing agent comprising water e), are mixed.
12. A polyurethane foam obtainable by the process according to claim 1 .
13. A method of producing cushions, seat cushions and mattresses comprising preparing the polyurethane foam according to claim 12 in the form of cushions, seat cushions, or mattresses.
14. The process according to claim 1 , wherein the amine catalyst is used in such an amount that a content of tertiary nitrogen atoms in the amine catalyst is from 0.0001 to 0.001 mol/100 g of foam.
15. The process according to claim 1 , wherein the catalysts d) are used in amounts such that the reaction mixture has a cream time in a range of from 10 to 30 seconds.