Doubly oriented electrical steel sheet and manufacturing method therefor
A double oriented electrical steel sheet according to an embodiment of the present invention includes: in wt %, Si at 2.0 to 4.0 wt %, Al at 0.01 to 0.04 wt %, S at 0.0004 to 0.002 at %, Mn at 0.05 to 0.3 wt %, N at 0.008 wt % or less (excluding 0 wt %), C at 0.005 wt % or less (excluding 0 wt %), P at 0.005 to 0.15 wt %, Ca at 0.0001 to 0.005 wt %, Mg at 0.0001 to 0.005 wt %, and the balance including Fe and other impurities unavoidably added thereto.
1. A double oriented electrical steel sheet, including: in wt %, Si at 2.0 to 4.0 wt %, Al at 0.01 to 0.04 wt %, S at 0.0004 to 0.002 wt %, Mn at 0.05 to 0.3 wt %, N at 0.008 wt % or less (excluding 0 wt %), C at 0.005 wt % or less (excluding 0 wt %), P at 0.005 to 0.15 wt %, Ca at 0.00010 to 0.005 wt %, Mg at 0.00010 to 0.005 wt %, and the balance including Fe and other impurities unavoidably added thereto,
wherein an area fraction of a grain with an orientation within 15° is 60 to 99% from {100}<001>,
wherein the double oriented electrical steel sheet satisfies Formula 1:
[Ca]+[Mg]≥[S] [Formula 1]
(in Formula 1, [Ca], [Mg], and [S] represent contents (wt %) of Ca, Mg, and S, respectively).
2. The double oriented electrical steel sheet of claim 1 , further comprising
one or more of Sb at 0.001 to 0.1 wt % and Sn at 0.001 to 0.1 wt %.
3. The double oriented electrical steel sheet of claim 1 , further comprising
one or more of Ti at 0.01 wt % or less, Mo at 0.01 wt % or less, Bi at 0.01 wt % or less, Pb at 0.01 wt % or less, Mg at 0.01 wt % or less, As at 0.01 wt % or less, Be at 0.01 wt % or less, and Sr at 0.01 wt % or less.
4. The double oriented electrical steel sheet of claim 1 , wherein
an average grain size is 20 times or more a thickness of the steel sheet.
5. The double oriented electrical steel sheet of claim 1 , wherein
the steel sheet comprises an oxide layer formed from a surface of a substrate forming the steel sheet in a direction inside the substrate and an insulating layer formed on the surface of the substrate.
6. The double oriented electrical steel sheet of claim 5 , wherein
a thickness of the oxide layer is 5 μm or less.
7. The double oriented electrical steel sheet of claim 5 , wherein
a thickness of the insulating layer is 0.2 to 8 μm.
8. The double oriented electrical steel sheet of claim 5 , further comprising
a forsterite layer interposed between the surface of the substrate and the insulating layer.
9. The double oriented electrical steel sheet of claim 1 , wherein
Br in a rolling direction and Br in a transverse direction are equal to or larger than 1.63 T, Br in a circumferential direction is equal to or larger than 1.56 T, and the Br is calculated by Formula 2:
Br=7.87/(7.87−0.065×[Si]−0.1105×[Al])×B8 [Formula 2]
(in Formula 2, [Si] and [Al] are contents (wt %) of Si and Al, respectively, and
B8 is intensity (Tesla) of a magnetic field induced at 800 A/m).
10. The double oriented electrical steel sheet of claim 1 , wherein
a Br value measured after annealing the steel sheet at a temperature of 750° C. to 880° C. for 1 to 2 hours is equal to or larger than 1.65 T, and the Br is calculated by Formula 2:
Br=7.87/(7.87−0.065×[Si]−0.1105×[Al])×B8 [Formula 2]
(in Formula 2, [Si] and [Al] are contents (wt %) of Si and Al, respectively, and
B8 is intensity (Tesla) of a magnetic field induced at 800 A/m).