IP Library › Granted Patent US 12,410,088
Granted Patent B2
US 12,410,088 · App. 17/127,137 · Granted Sep 9, 2025

Optical component and glass composition as well as use thereof

Inventors: Bianca Schreder (Sulzbach, DE); Ute Wölfel (Mainz, DE); Stephanie Hansen (Gensingen, DE); Ralf Biertümpfel (Mainz-Kastel, DE)
Assignee: Schott AG
C03C3/076C03C3/083C03C3/085C03C3/091C03C3/093C03C4/02C03C4/10C03C21/002C03C2203/10C03C2203/50G01S7/4813G01S17/931G02B5/208G02B5/226
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Quick Facts
Patent No.
US 12,410,088
App. No.
17/127,137
Granted
Sep 9, 2025
Kind
B2
Abstract

A glass includes cations of the following components in the indicated amounts (molar proportion in cat.-%): 30-80 cat.-% silicon; 0-20 cat.-% boron; 0-2 cat.-% aluminum; 5-35 cat.-% sodium; 2-25 cat.-% potassium; 0-0.5 cat.-% nickel; 0-0.5 cat.-% chromium; and 0.03-0.5 cat.-% cobalt. A sum of the molar proportions of cations of sodium and potassium is in a range of from 15 to 50 cat.-%, a sum of the molar proportions of cations of nickel and chromium is in a range of from 0.1 to 0.5 cat.-%, and a ratio of the sum of the molar proportions of cations of sodium and potassium to the sum of the molar proportions of cations of nickel and chromium is in a range of from 70:1 to 200:1.

Claims (63)

1. A glass, comprising cations of the following components in the indicated amounts (molar proportion in cat.-%):

Component

Proportion (cat.-%)

Silicon

30-80

Boron

 0-20

Aluminum

0-2

Sodium

 5-35

Potassium

 2-25

Nickel

  0-0.5

Chromium

  0-0.5

Cobalt

0.03-0.5 

Iron

0-1

wherein a sum of the molar proportions of cations of sodium and potassium is in a range of from 15 to 50 cat.-%, a sum of the molar proportions of cations of nickel and chromium is in a range of from 0.1 to 0.5 cat.-%, and a ratio of the sum of the molar proportions of cations of sodium and potassium to the sum of the molar proportions of cations of nickel and chromium is in a range of from 70:1 to 200:1.

2. The glass of claim 1 , wherein the glass comprises cations of zinc in an amount of from 1 to 12 cat.-%.

3. The glass of claim 1 , wherein the glass is free of cations of arsenic.

4. The glass of claim 1 , wherein a ratio of the molar proportion of potassium cations to the molar proportion of sodium cations in the glass is in a range of from 0.2:1 to <1:1.

5. The glass of claim 1 , wherein the ratio of the sum of the molar proportions of cations of nickel and chromium to the molar proportion of cations of cobalt is in a range of from >1:1 to 5:1.

6. The glass of claim 1 , wherein a ratio of the molar proportion of cations of manganese to the sum of the molar proportions of cations of nickel and chromium is in a range of from 0:1 to <1:1.

7. The glass of claim 1 , wherein at a sample thickness of the glass of 2 mm a ratio of an average transmission for light of a wavelength in a range of from 850 nm to 950 nm and an average transmission for light of a wavelength in a range of from 250 nm to 700 nm is in a range of from 6:1 to 200:1.

8. The glass of claim 1 , wherein at a sample thickness of the glass of 2 mm a ratio of a lowest average transmission of all subranges of 20 nm width within a range of from 850 nm to 950 nm and a highest average transmission of all subranges of 20 nm width within a range of from 250 nm to 700 nm is in a range of from 2.5:1 to 20:1.

9. The glass of claim 1 , wherein at a sample thickness of the glass of 2 mm a ratio of a minimum transmission for light of a wavelength in a range of from 850 nm to 950 nm and a maximum transmission for light of a wavelength in a range of from 250 nm to 700 nm is in a range of from 1.9:1 to 15:1.

10. The glass of claim 1 , wherein at a sample thickness of the glass of 4 mm a ratio of an average transmission for light of a wavelength in a range of from 850 nm to 950 nm and an average transmission for light of a wavelength in a range of from 250 nm to 700 nm is in a range of from 20:1 to 400:1.

11. The glass of claim 1 , wherein at a sample thickness of the glass of 4 mm a ratio of a lowest average transmission of all subranges of 20 nm width within a range of from 850 nm to 950 nm and a highest average transmission of all subranges of 20 nm width within a range of from 250 nm to 700 nm is in a range of from 6:1 to 50:1.

12. The glass of claim 1 , wherein at a sample thickness of the glass of 4 mm a ratio of a minimum transmission for light of a wavelength in a range of from 850 nm to 950 nm and a maximum transmission for light of a wavelength in a range of from 250 nm to 700 nm is in a range of from 3.5:1 to 15:1.

13. The glass of claim 1 , wherein at a sample thickness of the glass of 4 mm and for D65 illuminant a u′ coordinate is in a range of from 0.07 to 0.4, a v′ coordinate is in a range of from 0.09 to 0.51, and a brightness Y is in a range of from 0 to <7 in the 1976 CIE UCS color space system.

14. A system, comprising:

a glass article comprising a glass and having a thickness in a range of from 1 mm to 5 mm, the glass comprising cations of the following components in the indicated amounts (molar proportion in cat.-%):

Component

Proportion (cat.-%)

Silicon

30-80

Boron

 0-20

Aluminum

0-2

Sodium

 5-35

Potassium

 2-25

Nickel

  0-0.5

Chromium

  0-0.5

Cobalt

0.03-0.5 

Iron

0-1

wherein a sum of the molar proportions of cations of sodium and potassium is in a range of from 15 to 50 cat.-%, a sum of the molar proportions of cations of nickel and chromium is in a range of from 0.1 to 0.5 cat.-%, and a ratio of the sum of the molar proportions of cations of sodium and potassium to the sum of the molar proportions of cations of nickel and chromium is in a range of from 70:1 to 200:1.

15. The system of claim 14 , wherein the glass comprises cations of zinc in an amount of from 1 to 12 cat.-%.

16. The system of claim 14 , wherein a ratio of the molar proportion of potassium cations to the molar proportion of sodium cations in the glass is in a range of from 0.2:1 to <1:1.

17. The system of claim 14 , wherein the ratio of the sum of the molar proportions of cations of nickel and chromium to the molar proportion of cations of cobalt is in a range of from >1:1 to 5:1.

18. The system of claim 14 , wherein a ratio of the molar proportion of cations of manganese to the sum of the molar proportions of cations of nickel and chromium is in a range of from 0:1 to <1:1.

19. The system of claim 14 , wherein at a sample thickness of the glass of 2 mm a ratio of an average transmission for light of a wavelength in a range of from 850 nm to 950 nm and an average transmission for light of a wavelength in a range of from 250 nm to 700 nm is in a range of from 6:1 to 200:1.

20. The system of claim 14 , wherein the system is a light detection and ranging (LiDAR) system further comprising a laser and an optical window positioned between the laser and a surrounding, wherein the optical window comprises the glass article.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 8, 2021
From: SCHREDER, BIANCA, DR.; WÖLFEL, UTE; HANSEN, STEFANIE; BIERTÜMPFEL, RALF, DR.
To: SCHOTT AG
Reel/Frame 056472/0220 →
Priority Claims (2)
EP 19401057 · Dec 20, 2019 · regional
DE 10 2020 122 220.3 · Aug 25, 2020 · national
Continuity (1)
Related Publication 20210191014A1 · Jun 24, 2021
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