Negative electrode active material for non-aqueous electrolyte secondary battery comprising silicon oxide composite and manufacturing method thereof
The present disclosure relates to a negative electrode active material for non-aqueous electrolyte secondary battery, and a negative electrode active material for non-aqueous electrolyte secondary battery according to an embodiment of the present disclosure comprises a silicon oxide composite comprising silicon, silicon oxide (SiO x , 0<x≤2) and magnesium silicate, and including pores with a size of 50 to 300 nm therein. The negative electrode active material for non-aqueous electrolyte secondary battery comprising the silicon oxide composite according to the present disclosure solves a swelling problem by allowing the pores inside the silicon oxide composite to play a role of buffering expansion in the charging process, efficiently controls volume expansion by allowing stress caused by expansion and contraction generated during charging or discharging to be concentrated in the pores inside the silicon oxide composite, and can improve lifetime characteristics of the lithium secondary battery accordingly.
1. A negative electrode active material for non-aqueous electrolyte secondary battery, the negative electrode active material comprising a silicon oxide composite and pores disposed inside the silicone oxide composite,
wherein the silicon oxide composite comprises silicon, a silicon oxide (SiOx, 0<x≤2), and a magnesium silicate;
wherein an average diameter of the pores is in a range from 143 nm to 300 nm;
wherein the magnesium silicate comprises MgSiO 3 ;
wherein the negative electrode active material has a ratio of a pore portion area to an entire cross-sectional area of the silicon oxide composite of 3 to 40%,
wherein the negative electrode active material comprises 2 to 40 wt % of magnesium with respect to a total weight of the silicon oxide composite, and
wherein the negative electrode active material comprises 25 to 40 wt % of oxygen with respect to a total weight of the silicon oxide composite.
2. The negative electrode active material for non-aqueous electrolyte secondary battery of claim 1 , wherein the silicon oxide composite is shown at a diffraction peak of 20=27.5° to 29.5° by Si(III) during X-ray diffraction analysis, and has a silicon crystallite size of 1 to 20 nm calculated from Full Width at Half Maximum (FWHM) of the diffraction peak.
3. The negative electrode active material for non-aqueous electrolyte secondary battery of claim 1 , wherein the silicon oxide has a ratio (Si/O) of the number of silicon atoms to that of oxygen atoms of 0.5 to 2.
4. The negative electrode active material for non-aqueous electrolyte secondary battery of claim 1 , wherein the magnesium silicate further includes Mg 2 SiO 4 .
5. The negative electrode active material for non-aqueous electrolyte secondary battery of claim 1 , wherein the silicon oxide composite has a specific gravity of 1.8 to 3.2, an average particle diameter of 0.5 to 20 μm, and a specific surface area of 1 to 40 m 2 /g.
6. The negative electrode active material for non-aqueous electrolyte secondary battery of claim 1 , wherein the silicon oxide composite further comprises a carbon-containing coating layer on a surface thereof, and the coating layer is included in an amount of 2 to 20 wt % with respect to a total weight of the silicon oxide composite.
7. The negative electrode active material for non-aqueous electrolyte secondary battery of claim 6 , wherein the carbon-containing coating layer comprises one or more selected from the group consisting of amorphous carbon, carbon nanofiber, graphene, and graphene oxide.
8. The negative electrode active material for non-aqueous electrolyte secondary battery of claim 6 , wherein the silicon oxide composite has a specific gravity of 1.8 to 3.2, an average particle diameter of 0.5 to 20 μm, and a specific surface area of 1 to 40 m 2 /g.
9. The negative electrode active material for non-aqueous electrolyte secondary battery of claim 1 , wherein the negative electrode active material comprises 4 to 30 wt % of magnesium with respect to the total weight of the silicon oxide composite.
10. A negative electrode comprising a negative electrode active material for non-aqueous electrolyte secondary battery according to claim 1 , and a non-aqueous electrolyte secondary battery including the negative electrode.
11. The negative electrode active material for non-aqueous electrolyte secondary battery of claim 1 , wherein an average diameter of the pores is in a range from 170 nm to 300 nm.