Blown films with improved property profile
Blown films based on a blend of a C 2 C 3 random copolymer and a C 2 -based plastomer, which combine low scaling initiation temperature (SIT), good optical properties and an improved stiffness/impact balance, and which also show an excellent sterilization behaviour.
1. A blown film comprising at least 95.0 wt. % of a blend of component (A) and (B), the blend comprising:
(A) 60.0 wt. % to 95.0 wt.% of a C 2 C 3 random copolymer consisting of:
45.0 to 85.0 wt. % of polymer fraction (A1) having;
(i) an ethylene content in the range of from 1.5 to 5.0 wt. % and
(ii) a melt flow rate MFR 2 (230° C./2.16 kg) measured according to ISO 1133 in the range of from 0.8 to 8.0 g/10 min and 15.0 to 55.0 wt. % of polymer fraction (A-2) having;
(i) an ethylene content in the range of from 4.0 to 10.0 wt. % and
(ii) a melt flow rate MFR 2 (230° C./2.16 kg) measured according to ISO 1133 in the range of from 0.1 to 3.0 g/10 min,
whereby the ethylene content of polymer fraction (A-2) is higher than the ethylene content of polymer fraction (A-1), and the melt flow rate MFR 2 (230° C./2.16 kg) of polymer fraction (A-2) is lower than the MFR 2 (230° C./2.16 kg) of polymer fraction (A-1), and whereby the C 2 C 3 random copolymer has
(a) a total ethylene content in the range of from 1.0 to 7.0 wt. %;
(b) a melt flow rate MFR 2 (230° C./2.16 kg) measured according to ISO 1133 in the range of from 0.5 to less than 4.0 g/10 min and
(c) a melting temperature Tm as determined by DSC according to ISO 11357 of from 110° C. to 140° C.,
wherein said copolymer is prepared using a single site catalyst,
(B) 5.0 wt. % to 40.0 wt. % of an ethylene based plastomer having
(i) a density according to ISO 1183 of 860 kg/m 3 to 900 kg/m 3
(ii) an MFR 2 according to ISO 1133 (190° C.; 2.16 kg) in the range of 0.1 to 50.0 g/10 min, and
(iii) a comonomer selected from a C 4 to C 8 alpha-olefin,
said blown film having
a) a dart-drop impact strength (DDI) determined according to ASTM D1709, method A on a 50 μm blown film of at least 60 g up to more than 1700 g and
b) an Elmendorf tear strength determined in accordance with ISO 6383/2 measured in machine direction (MD), in the range from at least 5.0 N/mm up to 50.0 N/mm and measured in transverse direction (TD) in the range of from at least 80.0 N/mm up to 300.0 N/mm.
2. The blown film according to claim 1 , wherein the C 2 C 3 random copolymer (A) has a xylene cold soluble (XCS) fraction measured according to ISO 16152 at 25° C. in the range of from 0.6 to 12.0 wt. %.
3. The blown film according to claim 1 , wherein the C 2 C 3 random copolymer (A) has:
(a) a total ethylene content in the range of from 1.5 to 6.5 wt. %,
(b) a melt flow rate MFR 2 (230° C./2.16 kg) measured according to ISO 1133 in the range of from 0.7 to 3.5 g/10 min, and
(c) a melting temperature Tm as determined by DSC according to ISO 11357 of from 115° C. to 135° C.
4. The blown film according to claim 1 , wherein the ethylene based plastomer (B) has:
(i) a density according to ISO 1183 of 865 kg/m 3 to 895 kg/m 3 ,
(ii) an MFR 2 according to ISO 1133 (190° C.; 2.16 kg) in the range of 0.3 to 20.0 g/10 min, and
(iii) a comonomer selected from 1 butene or 1 octene.
5. The blown film according to claim 1 , wherein the film comprises at least 95.0 wt. % of a blend comprising 65.0 to 93.0 wt. % of the C 2 C 3 random copolymer (A) and 7.0 to 35.0 wt. % of the ethylene based plastomer (B).
6. The blown film according to claim 1 , wherein the film comprises at least 98.0 wt. % of the blend of Component (A) and Component (B).
7. The blown film according to claim 1 , wherein the film has a dart-drop impact strength (DDI) determined according to ASTM D1709, method A on a 50 μm blown film in the range of 80 g up to more than 1700 g.
8. The blown film according to claim 1 , wherein the film has an Elmendorf tear strength as determined in accordance with ISO 6383/2 as measured in machine direction (MD), in the range of 7.0 up to 45.0 N/mm, and as measured in transverse direction (TD), in the range of 90.0 to 250.0 N/mm.
9. The blown film according to claim 1 , wherein the film has a tensile modulus determined according to ISO 527 at 23° C. on blown films with a thickness of 50 μm in machine direction as well as in transverse direction in the range of from 200 to less than 800 MPa.
10. The blown film according to claim 1 , wherein the film has a sealing initiation temperature (SIT) (determined as described in the experimental part) in the range of from 80° C. to below 115° C.
11. The blown film according to claim 1 , wherein the film has;
a haze (determined according to ASTM D1003-00 on a blown film with a thickness of 50 μm) in the range of from 0.5 to below 5.0%, and
a clarity (determined according to ASTM D1003-00 on a blown film with a thickness of 50 μm) of at least 80.0% up to 100.0%.
12. The blown film according to claim 1 , wherein the film has a haze value (determined according to ASTM D 1003-00 on a 50 μm blown film) after steam sterilization at 121° C. for 30 min in the range of 1.0 to below 10.0%, and a clarity (determined according to ASTM D1003-00 on blown films with a thickness of 50 μm) after sterilization (steam sterilization at 121° C. for 30 min) of at least 70.0%.
13. The blown film according to claim 1 , wherein the film has an optomechanical ability (OMA) according the formula:
OMA
=
Tensile
Modulus
(
MD
)
[
MPa
]
*
Tear
(
MD
)
[
N
/
mm
]
Haze
(
50
µm
)
[
%
]
determined on a 50 μm blown film of at least 900 [MPa*N/mm*%] up to 4000 [MPa*N/mm*%].
14. The blown film according to claim 1 , wherein the film is a monolayer film.