High-pressure and multi-atmosphere assisted SLM gradient material preparation method and aluminum-lithium alloy coating
The present disclosure provides a high-pressure and multi-atmosphere assisted SLM gradient material preparation method and an aluminum-lithium alloy coating. The high-pressure and multi-atmosphere assisted SLM gradient material preparation method includes the following steps: injecting a first gas mixture into a working box, and enabling, by laser irradiation, molten materials in a micro-melt pool to react with a carbon-containing gas to form a carbide-doped first gradient aluminum-lithium alloy coating; injecting a second gas mixture into the working box, and enabling, by laser irradiation, molten materials in a micro-melt pool to react with a carbon and nitrogen-containing gas to form a carbide and nitride-doped second gradient aluminum-lithium alloy coating; and injecting a third gas mixture into the working box, and enabling, by laser irradiation, molten materials in a micro-melt pool to react with a nitrogen-containing gas to form a nitride-doped third gradient aluminum-lithium alloy coating. The present disclosure improves the surface forming quality of an aluminum-lithium alloy material, and the material is hard outside and tough inside.
1. A high-pressure and multi-atmosphere assisted selective laser melting (SLM) gradient material preparation method, comprising the following steps:
continuously injecting a first gas mixture into an airtight working box to maintain a high-pressure environment in the airtight working box, wherein the first gas mixture is a gas mixture of an inert gas and a carbon-containing active gas; and irradiating aluminum-lithium alloy powder laid on a surface of a substrate with a laser to form a micro-melt pool, and enabling molten materials in the micro-melt pool to react with the carbon-containing active gas to form a carbide-doped first gradient aluminum-lithium alloy coating;
discharging the first gas mixture out of the airtight working box; continuously injecting a second gas mixture into the airtight working box to maintain a high-pressure environment in the airtight working box, wherein the second gas mixture is a gas mixture of an inert gas and a carbon and nitrogen-containing active gas; irradiating aluminum-lithium alloy powder laid on a surface of the carbide-doped first gradient aluminum-lithium alloy coating with the laser to form a micro-melt pool, and enabling molten materials in the micro-melt pool to react with the carbon and nitrogen-containing active gas to form a carbide and nitride-doped second gradient aluminum-lithium alloy coating; and
discharging the second gas mixture out of the airtight working box; continuously injecting a third gas mixture into the airtight working box to maintain a high-pressure environment in the airtight working box, wherein the third gas mixture is a gas mixture of an inert gas and a nitrogen-containing active gas; irradiating aluminum-lithium alloy powder laid on a surface of the carbide and nitride-doped second gradient aluminum-lithium alloy coating with the laser to form a micro-melt pool, and enabling molten materials in the micro-melt pool to react with the nitrogen-containing active gas to form a nitride-doped third gradient aluminum-lithium alloy coating,
wherein, a pressure of the high-pressure environment created by the first gas mixture is P 1 , a pressure of the high-pressure environment created by the second gas mixture is P 2 , a pressure of the high-pressure environment created by the third gas mixture is P 3 , and P 1 >P 2 >P 3 ; the pressure P 1 of the high-pressure environment created by the first gas mixture is 3.5-5.0 MPa, the pressure P 2 of the high-pressure environment created by the second gas mixture is 2.0-2.5 MPa, and the pressure P 3 of the high-pressure environment created by the third gas mixture is 1.0-1.5 MPa.
2. The high-pressure and multi-atmosphere assisted SLM gradient material preparation method according to claim 1 , wherein the carbon-containing active gas in the first gas mixture is a CO 2 gas, and a volume ratio of the CO 2 gas in the first gas mixture is 10%-20%; the carbon and nitrogen-containing active gas in the second gas mixture comprises a CO 2 gas and a N 2 gas, a volume ratio of the CO 2 gas in the second gas mixture is 10%-20%, and a volume ratio of the N 2 gas in the second gas mixture is 20%-30%; the nitrogen-containing active gas in the third gas mixture is a N 2 gas, and a volume ratio of the N 2 gas in the third gas mixture is 20%-30%.
3. The high-pressure and multi-atmosphere assisted SLM gradient material preparation method according to claim 1 , wherein in an SLM formation process, a flow rate of the active gases is maintained at 20 L/min-50 L/min to ensure that a concentration of the active gases in a reaction process of the molten materials is within a set range.
4. The high-pressure and multi-atmosphere assisted SLM gradient material preparation method according to claim 3 , wherein the carbide-doped first gradient aluminum-lithium alloy coating and the nitride-doped third gradient aluminum-lithium alloy coating have a thickness of 0.8-1.0 mm, and the carbide and nitride-doped second gradient aluminum-lithium alloy coating has a thickness of 0.6-0.8 mm.
5. The high-pressure and multi-atmosphere assisted SLM gradient material preparation method according to claim 1 , wherein uniform and loose aluminum-lithium alloy powder is laid by means of a porous duster to ensure that part of the active gases is stored in the powder.
6. The high-pressure and multi-atmosphere assisted SLM gradient material preparation method according to claim 1 , wherein surface roughness of the surface of the substrate is increased to improve bonding strength of the formed aluminum-lithium alloy coatings and the substrate; and after being treated with absolute ethyl alcohol, the surface of the substrate is ultrasonically cleaned and dried.
7. The high-pressure and multi-atmosphere assisted SLM gradient material preparation method according to claim 1 , wherein the laser is a pulse laser, and parameters of a pulse laser beam of the pulse laser are as follows: a wavelength is 1075 nm, pulse energy is 1 J-30 J, a pulse period is 80 ms, a pulse duration is 20-60 ms, a duty cycle is 50%, a spot diameter is less than or equal to 50 μm, a laser power is 80-100 W, a scan speed of the pulse laser beam is 100 mm/s, and a scan interval is 100-120 μm.