Separation and recovery system and method of hydrogen from coke oven gas(COG) in steel industry

1. A system for separating and recovering hydrogen from coke oven gas (COG) in steel industry at a concentration of 99.9 volume % or more with a recovery rate of 95% or more, comprising the following units:

a preprocessing unit for removing impurities including tar, moisture, oil, hydrogen sulfide and dust from coke oven gas (COG) containing hydrogen, methane, carbon monoxide, carbon dioxide, nitrogen, light hydrocarbons and impurities comprising tar, moisture, oil, hydrogen sulfide and dust;

a membrane separation unit comprising a plurality of separation membrane packages in which at least two separation membrane packages that selectively permeate hydrogen are connected in series, and a single compressor connected to any one of the plurality of separation membrane packages that produces a hydrogen-enriched gas stream at a concentration of at least 95 volume % by recovering hydrogen from the coke oven gas (COG) with a recovery rate of 90% or more through membrane separation of the coke oven gas (COG) treated in the preprocessing unit; and

a first adsorption unit for separating and recovering hydrogen from the coke oven gas (COG) by contacting the hydrogen-enriched gas stream with a first adsorbent,

wherein the gas stream discharged from the first adsorption unit has a circulation structure supplied to a front end of the compressor.

2. The system for separating and recovering hydrogen from coke oven gas (COG) in steel industry according to claim 1 , wherein the membrane separation unit has a circulation structure for re-supplying the gas stream discharged from a residual outlet of a separation membrane package located at a rear end of the plurality of separation membrane packages to a residual inlet of a separation membrane package located at a front end.

3. The system for separating and recovering hydrogen from coke oven gas (COG) in steel industry according to claim 1 , wherein the compressor compresses the gas stream delivered to the plurality of separation membrane packages to 5 bar to 15 bar.

4. The system for separating and recovering hydrogen from coke oven gas (COG) in steel industry according to claim 1 , wherein each of the plurality of separation membrane packages comprises a polymer separation membrane for selectively separating hydrogen from a mixed gas including hydrogen, carbon monoxide, carbon dioxide, nitrogen, methane and light hydrocarbon gas.

5. The system for separating and recovering hydrogen from coke oven gas (COG) in steel industry according to claim 4 , wherein the polymer separation membrane is composed of at least one selected from the group consisting of polysulfone, polyimide and polybenzimidazole.

6. The system for separating and recovering hydrogen from coke oven gas (COG) in steel industry according to claim 1 , wherein the first adsorption unit is operated by a pressure swing adsorption (PSA) method using an adsorption tower in which a first adsorbent is filled in a single layer or multiple layers, and the first adsorbent is at least one selected from the group consisting of carbon molecular sieve activated carbon (CMS 5A), Ag-doped impregnated activated carbon, zeolite 13X, zeolite 5A, CuCl and Lix-doped zeolite LiX.

7. The system for separating and recovering hydrogen from coke oven gas (COG) in steel industry according to claim 6 , wherein the system further comprises a second adsorption unit operated by a thermal swing adsorption (TSA) method or a vapor pressure swing adsorption (VPSA) method at a rear end of the first adsorption unit operated by a pressure swing adsorption (PSA) method.

8. A method for separating and recovering hydrogen from coke oven gas (COG) in steel industry at a concentration of 99.9 volume % or more with a recovery rate of 95% or more, comprising the following steps:

a step of preprocessing to remove impurities including tar, moisture, oil, hydrogen sulfide and dust from coke oven gas (COG) containing hydrogen, methane, carbon monoxide, carbon dioxide, nitrogen, light hydrocarbons and impurities comprising tar, moisture, oil, hydrogen sulfide and dust;

a step of membrane separation to produce a hydrogen-enriched gas stream at a concentration of at least 95 volume % by recovering hydrogen from the coke oven gas (COG) with a recovery rate of 90% or more through membrane separation of the coke oven gas (COG) treated in the preprocessing unit in the membrane separation unit comprising a plurality of separation membrane packages in which at least two separation membrane packages that selectively permeate hydrogen are connected in series, and a single compressor connected to the plurality of separation membrane packages; and

a step of first adsorption to separate and recover hydrogen from the coke oven gas (COG) by contacting the hydrogen-enriched gas stream with a first adsorbent,

wherein the gas stream discharged from the step of first adsorption has a circulation structure supplied to a front end of the compressor.

9. The method for separating and recovering hydrogen from coke oven gas (COG) in steel industry according to claim 8 , wherein the plurality of separation membrane packages comprises a polymer separation membrane for selectively separating hydrogen from a mixed gas including hydrogen, carbon monoxide, carbon dioxide, nitrogen, methane and light hydrocarbon gas.

10. A method for concentrating hydrogen from coke oven gas (COG) in steel industry that separates and recovers hydrogen at a concentration of 99.9 volume % or more with a recovery rate of 95% or more, comprising the following steps:

a step of preprocessing to remove impurities including tar, moisture, oil, hydrogen sulfide and dust from coke oven gas (COG) containing hydrogen, methane, carbon monoxide, carbon dioxide, nitrogen, light hydrocarbons and impurities comprising tar, moisture, oil, hydrogen sulfide and dust;

a step of membrane separation to produce a hydrogen-enriched gas stream at a concentration of at least 95 volume % by recovering hydrogen from the coke oven gas (COG) with a recovery rate of 90% or more through membrane separation of the coke oven gas (COG) treated in the preprocessing unit in the membrane separation unit comprising a plurality of separation membrane packages in which at least two separation membrane packages that selectively permeate hydrogen are connected in series, and a single compressor connected to the plurality of separation membrane packages; and

a step of first adsorption to separate and recover hydrogen from the coke oven gas (COG) by contacting the hydrogen-enriched gas stream with a first adsorbent,

wherein the gas stream discharged from the step of first adsorption has a circulation structure supplied to a front end of the compressor.