Thermally-conductive silicone gel composition, thermally-conductive silicone gel sheet, and method for producing same
A thermally-conductive silicone gel composition of the present invention contains A to D components below. A: a linear organopolysiloxane having one vinyl group at each terminal end of a molecular chain and a kinematic viscosity of 1 to 600 mm 2 /s, B: a linear organopolysiloxane having three or more Si—H groups in one molecule and an Si—H group content of 0.05 to 6 mol/kg, in an amount such that a ratio of the number of Si—H groups in B component to the number of vinyl groups in A component is 0.2 to 0.5, C: a platinum catalyst in a catalytic amount, and D: a thermally-conductive filler in an amount of 300 to 1000 parts by mass when a total amount of A and B is taken as 100 parts by mass.
1. A thermally-conductive silicone gel composition comprising:
A a linear organopolysiloxane having one vinyl group at each terminal end of a molecular chain and a kinematic viscosity of 1 to 600 mm 2 /s;
B a linear organopolysiloxane having three or more Si—H groups in one molecule and an Si—H group content of 0.05 to 2 mol/kg, in an amount such that a ratio of the number of Si—H groups in B component to the number of vinyl groups in A component is 0.3 to 0.4;
C a platinum group metal-based catalyst in a catalytic amount; and
D a thermally-conductive filler in an amount of 300 to 1000 parts by mass when a total amount of A and B is taken as 100 parts by mass, including
D1 50 to 400 parts by mass of at least one type of spherical alumina with an average particle size of 1 to 5 μm, a part or a whole of the alumina being surface-treated with R a Si(OR′) 4-a , where R represents an unsubstituted or substituted organic group having 8 to 12 carbon atoms, R′ represents an alkyl group having 1 to 4 carbon atoms, and a is 1, and
D2 100 to 950 parts by mass of at least one type of spherical alumina with an average particle size of 10 to 100 μm.
2. The thermally-conductive silicone gel composition according to claim 1 , wherein the linear organopolysiloxane of the B component has a kinematic viscosity of 1 to 10000 mm 2 /s.
3. The thermally-conductive silicone gel composition according to claim 1 , wherein the D2 component is contained in an amount of 200 to 500 parts by mass with respect to 100 parts by mass of the D1 component.
4. The thermally-conductive silicone gel composition according to claim 1 , wherein the spherical alumina of the D2 includes at least two types of alumina including spherical alumina with an average particle size of 10 μm or more and less than 50 μm and spherical alumina with an average particle size of 50 μm or more and 100 μm or less.
5. A thermally-conductive silicone gel sheet obtained by curing the thermally-conductive silicone gel composition according to claim 1 , the sheet having a thermal conductivity of 1 W/m·K or more, an Asker C hardness of 30 or less, and a resilience rate of 20% or more.
6. The thermally-conductive silicone gel sheet according to claim 5 , wherein foaming is not seen by visual observation.
7. A method for producing a thermally-conductive silicone gel sheet comprising uniformly mixing a composition containing A to D components below, forming the mixture into a sheet, and curing the sheet by heat:
A a linear organopolysiloxane having one vinyl group at each terminal end of a molecular chain and a kinematic viscosity of 1 to 600 mm 2 /s;
B a linear organopolysiloxane having three or more Si—H groups in one molecule and an Si—H group content of 0.05 to 2 mol/kg, in an amount such that a ratio of the number of Si—H groups in B component to the number of vinyl groups in A component is 0.3 to 0.4;
C a platinum group metal-based catalyst in a catalytic amount; and
D a thermally-conductive filler in an amount of 300 to 1000 parts by mass when a total amount of A and B is taken as 100 parts by mass, including
D1 50 to 400 parts by mass of at least one type of spherical alumina with an average particle size of 1 to 5 μm, a part or a whole of the alumina being surface-treated with R a Si(OR′) 4-a , where R represents an unsubstituted or substituted organic group having 8 to 12 carbon atoms, R′ represents an alkyl group having 1 to 4 carbon atoms, and a is 1, and
D2 100 to 950 parts by mass of at least one type of spherical alumina with an average particle size of 10 to 100 μm.
8. The method for producing a thermally-conductive silicone gel sheet according to claim 7 , wherein the linear organopolysiloxane of the B component has a kinematic viscosity of 1 to 10000 mm 2 /s.
9. The method for producing a thermally-conductive silicone gel sheet according to claim 7 , wherein the D2 component is contained in an amount of 200 to 500 parts by mass with respect to 100 parts by mass of the D1 component.
10. The method for producing a thermally-conductive silicone gel sheet according to claim 7 , wherein the spherical alumina of the D2 includes at least two types of alumina including spherical alumina with an average particle size of 10 μm or more and less than 50 μm and spherical alumina with an average particle size of 50 μm or more and 100 μm or less.