Fluidized catalytic conversion method for preparing low-carbon olefins
A fluidized catalytic conversion method for producing light olefins includes the following steps: 1) introducing an olefin-rich feedstock into a fluidized catalytic conversion reactor, and contacting with a catalyst having a temperature of 650° C. or higher for reaction; 2) separating the reaction product vapor obtained by the reaction to obtain a stream comprising C5+ olefins; and 3) recycling at least a part of the stream comprising C5+ olefins to step 1) for further reaction. The fluidized catalytic conversion method can effectively improve the yield of light olefins, improve the selectivity and improve the ethylene/propylene ratio of the product.
1. A fluidized catalytic conversion method for producing light olefins, comprising the steps of:
1) Introducing an olefin-rich feedstock through a first inlet into a fluidized catalytic conversion reactor, contacting with a catalytic conversion catalyst, and reacting under first catalytic conversion conditions, wherein the olefin-rich feedstock has an olefin content of 50 wt % or more and the catalyst conversion catalyst is preheated to a temperature of 650° C. or higher;
2) Separating the effluent of the fluidized catalytic conversion reactor to obtain a reaction product vapor and a spent catalyst, and separating the reaction product vapor to obtain ethylene, propylene, butylene and a stream comprising C5+ olefins; and
3) feeding at least a part of the stream comprising C5+ olefins obtained from step 2) to the fluidized catalytic conversion reactor through a second inlet located downstream from the first inlet for further reaction,
wherein the first catalytic conversion conditions include:
a reaction temperature of 600-800° C.;
a reaction pressure of 0.05-1 MPa;
a reaction time of 0.01 to 100 seconds; and
a weight ratio of the catalytic conversion catalyst to the olefin-rich feedstock of (1-200):1;
and
4) feeding at least a part of the butylene obtained from step 2) to the fluidized catalytic conversion reactor at a third inlet located downstream from the first inlet for further reaction under second catalytic conversion conditions,
wherein the second catalytic conversion conversions include:
a reaction temperature of 650-800° C.;
a reaction pressure of 0.05-1 MPa;
a reaction time of 0.01 to 10 seconds; and
a weight ratio of the catalytic conversion catalyst to the butylene of (20-200):1.
2. The method according to claim 1 , wherein the olefin-rich feedstock has an olefin content of 80 wt % or more.
3. The method according to claim 1 , wherein the olefins in the olefin-rich feedstock consist essentially of C5+ olefins.
4. The method according to claim 1 , further comprising the steps of:
1a) introducing an oxygen-containing organic compound into the fluidized catalytic conversion reactor downstream from the first inlet for further reaction under third catalytic conversion conditions, which includes:
a reaction temperature of 300-550° C.;
a reaction pressure of 0.01 to 1 MPa;
a reaction time of 0.01 to 100 seconds; and
a weight ratio of the catalytic conversion catalyst to the oxygen-containing organic compound feedstock of (1-100):1.
5. The method according to claim 1 , wherein the catalytic conversion catalyst comprises 1-50 wt % of a molecular sieve, 5-99 wt % of an inorganic oxide, and 0-70 wt % of a clay, based on the weight of the catalytic conversion catalyst.
6. The method according to claim 1 , wherein the catalytic conversion catalyst comprises 0.1-3 wt % of a modifying element, based on the weight of the catalytic conversion catalyst; and the modifying element is one or more selected from the group consisting of Group VIII metals, Group IVA metals, Group VA metals, and rare earth metals.
7. The method according to claim 1 , wherein the fluidized catalytic conversion reactor is selected from the group consisting of a riser reactor, a constant-linear-velocity fluidized bed, an equal-diameter fluidized bed, an ascending transfer line, a descending transfer line, and a combination of two reactors thereof connected in series, and wherein the riser reactor is an equal-diameter riser reactor or a diameter-transformed fluidized bed reactor.
8. The method according to claim 1 , further comprising the steps of:
5) Regenerating the spent catalyst obtained by the separation in step 2) by coke burning to obtain a regenerated catalyst, having a temperature of 650° C. or higher, and then recycling the regenerated catalyst to the fluidized catalytic conversion reactor for use as the catalytic conversion catalyst.
9. The method according to claim 1 , wherein the stream comprising C5+ olefins has a C5+ olefin content of 50 wt % or more.
10. The method according to claim 1 , wherein the step 2) comprises:
2a) separating the effluent of the fluidized catalytic conversion reactor to obtain reaction product vapor and the spent catalyst;
2b) separating the reaction product vapor in a product fractionator to obtain ethylene, propylene, butylene and a first olefin-containing stream; and
2c) separating the first olefin-containing stream in an olefin separator to obtain the stream comprising C5+ olefins, wherein the olefin content in the stream comprising C5+ olefins is greater than the olefin content in the first olefin-containing stream.
11. The method according to claim 1 , wherein the first catalytic conversion conditions include:
a reaction temperature of 630-780° C.;
a reaction pressure of 0.1-0.8 MPa;
a reaction time of 0.1 to 80 seconds; and
a weight ratio of the catalytic conversion catalyst to the olefin-rich feedstock of (3-180):1.
12. The method according to claim 1 , wherein the olefin-rich feedstock has an olefin content of 90 wt % or more.
13. The method according to claim 1 , wherein the olefin-rich feedstock is a pure olefin feedstock.
14. The method according to claim 3 , wherein the olefin-rich feedstock is one or more of a C5+ fraction produced by an alkane dehydrogenation unit, a C5+ fraction produced by a catalytic cracking unit of an oil refinery, a C5+ fraction produced by a steam cracking unit of an ethylene plant, a C5+ olefin-rich byproduct fraction of an MTO process, and a C5+ olefin-rich byproduct fraction of an MTP process.
15. The method according to claim 1 , wherein the second catalytic conversion conditions include:
a reaction temperature of 680-780° C.;
a reaction pressure of 0.1-0.8 MPa;
a reaction time of 0.05 to 8 seconds; and
a weight ratio of the catalytic conversion catalyst to the butylene of (30-180):1.
16. The method according to claim 4 , wherein the third catalytic conversion conditions include:
a reaction temperature of 400-530° C.;
a reaction pressure of 0.05 to 1 MPa;
a reaction time of 0.1 to 80 seconds; and
a weight ratio of the catalytic conversion catalyst to the oxygen-containing organic compound feedstock of (3-50):1.
17. The method according to claim 4 , wherein the oxygen-containing organic compound comprises at least one selected from the group consisting of methanol, ethanol, dimethyl ether, methyl ethyl ether, and ethyl ether.
18. The method according to claim 5 , wherein the molecular sieve comprises 50-100 wt % of a mesoporous molecular sieve and 0-50 wt % of a microporous molecular sieve, based on the total weight of the molecular sieve.
19. The method according to claim 18 , wherein the mesoporous molecular sieve is a ZSM molecular sieve, and the microporous molecular sieve is a SAPO molecular sieve.