Dendrite formation for secure tagging using multi-fluid systems
View Patent ↗Forming a unique stochastically branching pattern includes providing a first fluid between a surface of a first substrate and a surface of a second substrate and introducing a second fluid between the surface of the first substrate and the surface of the second substrate. The second fluid is in direct contact with the first fluid at a formation temperature, and a viscosity of the first fluid at the formation temperature exceeds a viscosity of the second fluid at the formation temperature. The first substrate and the second substrate are separated to yield a unique stochastically branching pattern comprising the first fluid on the surface of the first substrate.
1. A method for forming a unique stochastically branching pattern, the method comprising:
providing a first fluid between a surface of a first substrate and a surface of a second substrate;
introducing a second fluid between the surface of the first substrate and the surface of the second substrate, wherein the second fluid is in direct contact with the first fluid at a formation temperature, and a viscosity of the first fluid at the formation temperature exceeds a viscosity of the second fluid at the formation temperature; and
separating the first substrate and the second substrate to yield a unique stochastically branching pattern comprising the first fluid on the surface of the first substrate,
wherein the first substrate is a label or a package.
2. The method of claim 1 , wherein the formation temperature is room temperature.
3. The method of claim 1 , wherein providing the first fluid between the first substrate and the second substrate comprises:
disposing the first fluid on the surface of the first substrate; and
contacting the first fluid with the surface of the second substrate.
4. The method of claim 3 , wherein disposing the first fluid on the surface of the first substrate comprises dispensing the first fluid from a nozzle or through a template or applying the first fluid on the surface of the first substrate with a rotogravure.
5. The method of claim 1 , further comprising spreading the first fluid on the surface of the first substrate before introducing the second fluid.
6. The method of claim 1 , wherein the first fluid is in direct contact with the surface of the first substrate and the surface of the second substrate.
7. The method of claim 1 , wherein the surface of the first substrate and the surface of the second substrate at least partially confine the first fluid, and the surface of the first substrate and the surface of the second substrate are separated by the first fluid at a region between the surface of the first substrate and the surface of the second substrate, thereby allowing the second fluid to penetrate the first fluid at the region.
8. The method of claim 7 , wherein separating the first substrate and the second substrate comprises increasing a distance between an edge of the first substrate and an edge of the second substrate such that the region translates away from the first edge of the first substrate and the first edge of the second substrate.
9. The method of claim 1 , wherein introducing the second fluid between the surface of the first substrate and the surface of the second substrate comprises injecting the second fluid under pressure between the surface of the first substrate and the surface of the second substrate.
10. The method of claim 1 , wherein separating the first substrate and the second substrate forms a mirror image of the stochastically branching pattern comprising the first fluid on the surface of the second substrate.
11. The method of claim 10 , further comprising solidifying the unique stochastically branching pattern on the surface of the first substrate, the second substrate, or both.
12. The method of claim 1 , wherein solidifying the unique stochastically branching pattern comprises removing a solvent from the first fluid on the surface of the first substrate.
13. The method of claim 1 , wherein a maximum dimension of the unique stochastically branching pattern is in a range of 5 mm to 5 cm.
14. The method of claim 1 , wherein the unique stochastically branching pattern has a variable height with respect to the surface of the first substrate.
15. The method of claim 1 , wherein the first substrate is flexible.
16. A method for forming a unique stochastically branching pattern, the method comprising:
providing a first fluid between a surface of a first substrate and a surface of a second substrate;
introducing a second fluid between the surface of the first substrate and the surface of the second substrate, wherein the second fluid is in direct contact with the first fluid at a formation temperature, and a viscosity of the first fluid at the formation temperature exceeds a viscosity of the second fluid at the formation temperature; and
separating the first substrate and the second substrate to yield a unique stochastically branching pattern comprising the first fluid on the surface of the first substrate,
wherein the surface of the first substrate and the surface of the second substrate are curved.
17. The method of claim 1 , wherein the surface of the first substrate and the surface of the second substrate are substantially planar.
18. The method of claim 1 , wherein the surface of the first substrate, the surface of the second substrate, or both have a root mean square surface roughness of 50 μm or less or 1 μm or less.
19. The method of claim 1 , wherein the first fluid comprises a gel, an oil, a polymer, or polymerizable monomers.
20. The method of claim 19 , wherein the first fluid comprises a suspension of polymeric particles in water.
21. The method of claim 1 , wherein the first fluid is optically transparent.
22. The method of claim 1 , wherein the first fluid fluoresces under ultraviolet light.
23. The method of claim 1 , wherein the first fluid contains particles that reflect light.
24. The method of claim 1 , wherein a contact angle of the first fluid on the surface of the first substrate is in a range of 60° to 70°.
25. The method of claim 1 , wherein the second fluid comprises an organic solvent.
26. The method of claim 25 , wherein the organic solvent comprises an alcohol.
27. The method of claim 1 , wherein the second fluid comprises air.
28. The method of claim 27 , wherein the second fluid is air.
29. The method of claim 1 , wherein the first fluid comprises a colorant, the second fluid comprises a colorant, or both.
30. The method of claim 1 , wherein an interfacial tension between the first fluid and the second fluid is less than about 40 mJ/m 2 at the formation temperature.
31. The method of claim 1 , wherein the first fluid comprises an additive selected to change color based on exposure to light or heat, a selected chemical, a selected biological agent, or radiation of a selected wavelength or wavelengths.
32. A method for forming a unique stochastically branching pattern, the method comprising:
providing a first fluid between a surface of a first substrate and a surface of a second substrate;
introducing a second fluid between the surface of the first substrate and the surface of the second substrate, wherein the second fluid is in direct contact with the first fluid at a formation temperature, and a viscosity of the first fluid at the formation temperature exceeds a viscosity of the second fluid at the formation temperature; and
separating the first substrate and the second substrate to yield a unique stochastically branching pattern comprising the first fluid on the surface of the first substrate,
wherein the first fluid is in direct contact with protrusions, recessions, or both in the surface of the first substrate, the surface of the second substrate, or both.
33. The method of claim 32 , wherein the protrusions, the recessions, or both form a pattern in the surface of the first substrate, the surface of the second substrate, or both.
34. A method for forming a unique stochastically branching pattern, the method comprising:
providing a first fluid between a surface of a first substrate and a surface of a second substrate;
introducing a second fluid between the surface of the first substrate and the surface of the second substrate, wherein the second fluid is in direct contact with the first fluid at a formation temperature, and a viscosity of the first fluid at the formation temperature exceeds a viscosity of the second fluid at the formation temperature; and
separating the first substrate and the second substrate to yield a unique stochastically branching pattern comprising the first fluid on the surface of the first substrate,
wherein the first fluid comprises electrically conductive material.
35. A method for forming a unique stochastically branching pattern, the method comprising:
providing a first fluid between a surface of a first substrate and a surface of a second substrate;
introducing a second fluid between the surface of the first substrate and the surface of the second substrate, wherein the second fluid is in direct contact with the first fluid at a formation temperature, and a viscosity of the first fluid at the formation temperature exceeds a viscosity of the second fluid at the formation temperature; and
separating the first substrate and the second substrate to yield a unique stochastically branching pattern comprising the first fluid on the surface of the first substrate,
wherein the first fluid is a food safe material.
36. The method of claim 35 , wherein the first fluid comprises one or more of glycerin, gelatin, wax, and polyvinyl alcohol.
37. A method for forming a unique stochastically branching pattern, the method comprising:
providing a first fluid between a surface of a first substrate and a surface of a second substrate;
introducing a second fluid between the surface of the first substrate and the surface of the second substrate, wherein the second fluid is in direct contact with the first fluid at a formation temperature, and a viscosity of the first fluid at the formation temperature exceeds a viscosity of the second fluid at the formation temperature; and
separating the first substrate and the second substrate to yield a unique stochastically branching pattern comprising the first fluid on the surface of the first substrate,
wherein the first fluid comprises an additive selected to change color based on exposure to light or heat, a selected chemical, a selected biological agent, or radiation of a selected wavelength or wavelengths.