Positive electrode active material and lithium secondary battery comprising the same
The present invention relates to a positive electrode active material and a lithium secondary battery using a positive electrode containing the positive electrode active material. More particularly, the present invention relates to a positive electrode active material that is able to solve a problem of increased resistance according to an increase in Ni content by forming a charge transport channel in a lithium composite oxide and a lithium secondary battery using a positive electrode containing the positive electrode active material.
1 . A positive electrode active material, comprising:
a bulk particle consisting of a plurality of primary particles that are lithium composite oxides enabling lithium intercalation and deintercalation,
wherein a first concentration gradient section in which the concentration of at least one of metal elements constituting the primary particles in the bulk particle increases in a direction (transverse direction) perpendicular to a direction (longitudinal direction) toward a surface region of the bulk particle from a core region of the bulk particle, and a second concentration gradient section in which the concentration of at least one of metal elements constituting the primary particles in the bulk particle decreases in a direction (transverse direction) perpendicular to a direction (longitudinal direction) toward a surface region of the bulk particle from a core region of the bulk particle, are present in the bulk particle,
wherein the first concentration gradient and the second concentration gradient section are laterally arranged along a circumferential surface of the bulk particle.
2 . The positive electrode active material of claim 1 , wherein the first concentration gradient section and the second concentration gradient section are present in a surface region of the bulk particle.
3 . The positive electrode active material of claim 1 , wherein the first concentration gradient section and the second concentration gradient section are repeatedly present along the circumferential surface of the bulk particle.
4 . The positive electrode active material of claim 1 , wherein the first concentration gradient section and the second concentration gradient section are not present in a core region of the bulk particle.
5 . The positive electrode active material of claim 1 , wherein a concentration gradient formed by changes in concentration of metal elements constituting the primary particles in the direction toward a surface region of the bulk particle from a core region of the bulk particle is not present in the bulk particle.
6 . The positive electrode active material of claim 1 , wherein the primary particles are the lithium composite oxides comprising nickel, cobalt and manganese other than lithium.
7 . The positive electrode active material of claim 6 , wherein the concentration gradient directions of nickel, cobalt and manganese are different from each other in the first concentration gradient section and/or the second concentration gradient section.
8 . The positive electrode active material of claim 6 , wherein the concentration gradient directions of cobalt and manganese are the same, and the concentration gradient directions of cobalt and manganese are different from that of nickel in the first concentration gradient section and/or the second concentration gradient section.
9 . The positive electrode active material of claim 6 , wherein cobalt in the first concentration gradient section increases to a higher concentration than an average content of cobalt in the bulk particle.
10 . The positive electrode active material of claim 6 , wherein an amount of the cobalt in the second concentration gradient section decreases to be close to an average amount of the cobalt in the bulk particle.
11 . The positive electrode active material of claim 1 , wherein along the circumferential surface of the bulk particle, a concentration increase/decrease part having the first concentration gradient section and the second concentration gradient section and a concentration maintenance part in which the concentration of at least one of metal elements constituting the primary particles in the bulk particle is maintained are present.
12 . The positive electrode active material of claim 11 , wherein a change rate in concentration of at least one of metal elements constituting the primary particles in the concentration maintenance part is 5 wt % or less per 0.1 μm.
13 . The positive electrode active material of claim 1 , further comprising:
a coating layer which covers at least a part of the surface of the bulk particle,
wherein the coating layer contains at least one oxide particle represented by the following formula 2:
Li a A b O c [Formula 2]
(wherein,
A is at least one selected from Ni, Mn, Co, Fe, Cu, Nb, Mo, Ti, Al, Cr, Zr, Zn, Na, K, Ca, Mg, Pt, Au, B, P, Eu, Sm, W, Ce, V, Ba, Ta, Sn, Hf, Gd and Nd, 0≤a≤6, 0≤b≤4, and 2≤c≤8).
14 . A positive electrode slurry composition, comprising:
the positive electrode active material of claim 1 , a conductive material and a binder.
15 . A lithium secondary battery, comprising:
a positive electrode formed by coating a current collector with the positive electrode slurry composition of claim 14 .