One-component moisture-curable adhesive composition
A one-component moisture-curing polyurethane adhesive composition is provided, comprising an isocyanate-functional prepolymer obtainable by reacting (a) one or more polyisocyanates comprising methyl diphenyl diisocyanate; and (b) a polyol mixture comprising (b1) a linear butylene oxide-based diol with two primary hydroxyl groups; and (b2) a polyether triol with three secondary hydroxyl groups wherein 55 to 75% of the hydroxyl groups in polyol mixture (b) are hydroxyl groups from butylene oxide-based diol (b1), wherein the equivalent ratio between isocyanate groups in (a) and hydroxyl groups in (b) is in the range of from 3.5 to 7.0, and wherein the content of free isocyanate groups in the adhesive composition is in the range of from 14 to 17 wt %. A method of bonding a first piece of material to a second piece of material using such adhesive composition, and an object made using the method, are also provided.
1 . A one-component moisture-curable adhesive composition comprising from 80 to 100 wt % of an isocyanate-functional prepolymer obtainable by reacting:
(a) one or more polyisocyanates comprising methyl diphenyl diisocyanate; and
(b) a polyol mixture comprising:
(b1) a linear butylene oxide-based diol with two primary hydroxyl groups; and
(b2) a polyether triol with three secondary hydroxyl groups,
wherein in the range of from 55 to 75% of the hydroxyl groups in polyol mixture (b) are hydroxyl groups from butylene oxide-based diol (b1), wherein the equivalent ratio between isocyanate groups in (a) and hydroxyl groups in (b) is in the range of from 3.5 to 7.0, and wherein the content of free isocyanate groups in the adhesive composition is in the range of from 14 to 17 wt % determined according to ASTM D2572-19.
2 . A one-component moisture-curable adhesive composition according to claim 1 , further comprising a curing catalyst.
3 . A one-component moisture-curable adhesive composition according to claim 2 , wherein the curing catalyst is 2,2′-dimorpholinediethylether.
4 . A one-component moisture-curable adhesive composition according to claim 1 , wherein butylene oxide-based diol (b1) has a number average molecular weight in the range of from 500 to 1,500 g/mol determined by size-exclusion chromatography using polystyrene standards according to ISO 16014-1.
5 . A one-component moisture-curable adhesive composition according to claim 1 , wherein polyether triol (b2) has a number average molecular weight in the range of from 500 to 1,500 g/mol determined by size-exclusion chromatography using polystyrene standards according to ISO 16014-1.
6 . A one-component moisture-curable adhesive composition according to claim 1 , wherein the polyol mixture (b) is substantially free of any polyols other than (b1) and (b2).
7 . A one-component moisture-curable adhesive composition according to claim 1 , wherein in the range of from 60 to 70% of the hydroxyl groups in polyol mixture (b) are hydroxyl groups from butylene oxide-based diol (b1).
8 . A one-component moisture-curable adhesive composition according to claim 1 , wherein the equivalent ratio between isocyanate groups in (a) and hydroxyl groups in (b) is in the range of from 4.0 to 6.5.
9 . A one-component moisture-curable adhesive composition according to claim 1 , wherein the content of free isocyanate groups in the adhesive composition is in the range of from 15.0 to 16.5 wt % determined according to ASTM D2572-19.
10 . A one-component moisture-curable adhesive composition according to claim 1 , wherein the one or more polyisocyanates (a) essentially consists of methyl diphenyl diisocyanate.
11 . A one-component moisture-curable adhesive composition according to claim 1 comprising from 85 to 99.8 wt % of the prepolymer.
12 . A one-component moisture-curable adhesive composition according to claim 1 , further comprising one or more additives.
13 . A one-component moisture-curable adhesive composition according to claim 1 , wherein the equivalent ratio between isocyanate groups in (a) and hydroxyl groups in (b) is in the range of from 4.5 to 6.0.
14 . A one-component moisture-curable adhesive composition according to claim 1 , further comprising a defoaming agent and/or a thickener.
15 . A method of bonding a first piece of material to a second piece of material, comprising contacting a surface of the first material with a surface of the second material, wherein at least one of the contacted surfaces has the adhesive composition according to claim 1 applied to it prior to the contacting.
16 . An object comprising a first piece of material and a second piece of material bonded with the adhesive composition according to claim 1 .
17 . An object according to claim 16 , wherein the material is wood, and the object is a structural wood product.