IP Library › Granted Patent US 12,460,348
Granted Patent B2
US 12,460,348 · App. 16/190,772 · Granted Nov 4, 2025

Polyester composition with improved dyeing properties

Inventor: Robert Alton Usher, Jr. (Charlotte, NC)
Assignee: Parkdale Incorporated
D06P3/8228C08G63/672D01F2/00D01F6/84D01F6/86D06P3/8223D06P3/8233D06P3/8238D06P3/8252D06P3/528D06P3/66D10B2201/02D10B2401/14D10B2501/00
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Quick Facts
Patent No.
US 12,460,348
App. No.
16/190,772
Granted
Nov 4, 2025
Kind
B2
Abstract

A copolymer composition is disclosed with advantages for textile fibers, yarns, blended yarns, fabrics, and garments. The composition includes polyester copolymer, between about 4.5 and 5.5 percent adipic acid based on the amount of copolymer, between about 630 and 770 parts per million (ppm) of pentaerythritol based on the amount of copolymer, and between about 3.4 and 4.2 percent polyethylene glycol based on the amount of copolymer.

Claims (35)

1 . A filament comprising:

a polyester copolymer comprising about 4.5 and 5.5 percent adipic acid based on the total amount of polyester copolymer,

between about 630 and 770 parts per million (ppm) of pentaerythritol based on the total amount of polyester copolymer,

between about 3.4 and 4.2 percent polyethylene glycol based on the total amount of polyester copolymer, and

an amount of diethylene glycol that is less than 2 percent based on the total amount of polyester copolymer.

2 . A textured filament made from the filament of claim 1 .

3 . A fabric formed from the yarn of claim 1 and selected from the group consisting of woven fabrics and knitted fabrics.

4 . A textured filament according to claim 2 that receives and retains reactive dye at atmospheric pressure and at temperatures below 212° F. (100° C.).

5 . Staple fibers cut from the textured filament of claim 2 .

6 . A blend of cotton fibers and the staple fibers of claim 5 .

7 . A blended yarn comprising:

between about 20 percent and 80 percent by weight cotton; and

textured polyester copolymer staple fibers comprising:

a polyester copolymer comprising

between about 4.5 and 5.5 percent adipic acid based on the total amount of polyester copolymer,

between about 630 and 770 parts per million (ppm) of pentaerythritol based on the total amount of polyester copolymer,

between about 3.4 and 4.2 percent polyethylene glycol based on the total amount of polyester copolymer, and

an amount of diethylene glycol that is less than 2 percent based on the total amount of polyester copolymer.

8 . A colorfast yarn according to claim 7 further comprising a reactive dye.

9 . A fabric formed from the yarn of claim 7 .

10 . A fabric according to claim 9 selected from the group consisting of woven fabrics and knitted fabrics.

11 . A fabric formed from the colorfast yarn of claim 8 .

12 . A fabric according to claim 11 selected from the group consisting of woven fabrics and knitted fabrics.

13 . A garment formed from the blended yarn of claim 7 .

14 . A dyed fabric that consists essentially of:

a blended yarn composed of between about 20 percent and 80 percent by weight cotton;

with the remainder being textured polyester copolymer staple fibers comprising:

a polyester copolymer comprising

between about 4.5 and 5.5 percent adipic acid based on the total amount of polyester copolymer,

between about 630 and 770 parts per million (ppm) of pentaerythritol based on the total amount of polyester copolymer,

between about 3.4 and 4.2 percent polyethylene glycol based on the total amount of polyester copolymer, and

an amount of diethylene glycol that is less than 2 percent based on the total amount of polyester copolymer; and

a reactive dye.

15 . A dyed fabric according to claim 14 selected from the group consisting of woven fabrics and knitted fabrics.

16 . A garment formed from the dyed fabric of claim 14 .

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 7, 2025
From: USHER, ROBERT ALTON, JR.
To: PARKDALE INCORPORATED
Reel/Frame 072497/0605 →
Continuity (4)
Continuation 15258308 · Sep 7, 2016
Provisional Application 62324467 · Apr 19, 2016
Provisional Application 62217268 · Sep 11, 2015
Related Publication 20190078256A1 · Mar 14, 2019
References Cited (62)
US 3690942A · Vandermaas · 1972 [cited by applicant]
US 4115621A · Hawkins · 1978 [cited by examiner]
US 4690866A · Kumakawa · 1987 [cited by applicant]
US 5135697A · Roderiguez · 1992 [cited by applicant]
US 5151494A · Munday · 1992 [cited by applicant]
US 5272246A · Roderiguez · 1993 [cited by examiner]
US 5464694A · Heinrich · 1995 [cited by applicant]
US 6261686B1 · Schumann · 2001 [cited by examiner]
US 6497732B1 · Soane · 2002 [cited by examiner]
US 6517933B1 · Soane · 2003 [cited by examiner]
US 6783853B2 · Figuly · 2004 [cited by applicant]
US 10174454B2 · Usher, Jr. · 2019 [cited by examiner]
US 20020019508A1 · Branum · 2002 [cited by examiner]
US 20030134117A1 · Branum · 2003 [cited by applicant]
US 20040143054A1 · Maurer · 2004 [cited by applicant]
US 20040195543A1 · Masuda · 2004 [cited by applicant]
US 20070055043A1 · Nadkarni · 2007 [cited by examiner]
US 20170073887A1 · Usher · 2017 [cited by applicant]
US 20170107662A1 · Usher · 2017 [cited by applicant]
US 20190078256A1 · Usher, Jr. · 2019 [cited by examiner]
EP 0066634 · 1982 [cited by applicant]
EP 0018947 · 1984 [cited by applicant]
EP 0474418 · 1992 [cited by applicant]
EP 0843030 · 1998 [cited by applicant]
GB 903913 · 1962 [cited by applicant]
GB 1152647 · 1969 [cited by applicant]
GB 1431106 · 1976 [cited by applicant]
JP S43004545 · 1968 [cited by applicant]
JP S46800708 · 1971 [cited by applicant]
JP S55158325 · 1980 [cited by applicant]
JP S58149311 · 1983 [cited by applicant]
JP H02229212 · 1990 [cited by applicant]
JP H04300322 · 1992 [cited by applicant]
JP 3114763 · 1994 [cited by applicant]
JP H1121337 · 1999 [cited by applicant]
JP 2002173824 · 2002 [cited by applicant]
JP 2004533553 · 2004 [cited by applicant]
JP 2006063215 · 2006 [cited by applicant]
JP 20131133570 · 2013 [cited by applicant]
Textile Effects Novacron LS reactive dyes, Exhaust Dyeing with Low Salt addition, Huntsman, 2007; pp. 31. [cited by applicant]
Summary of AATCC test method 61—Test No. 1A or Test No. 2A; ISO Test Method 105-C-06-1A or 2A, CAN/CGSB Test Method 19, Colorfastness to Laundering, Home & Commercial Accelerated (Hand Wash) (Machine Wash), 2013. [cited by applicant]
Summary of ASTM D3512 Standard Test Method for Pilling Resistance and Other Related Surface Changes of Textile Fabrics: Random Tumble Pilling Tester; 2016; accessed at https://www.astm.org/Standards/D3512.htm on Aug. 29… [cited by applicant]
Summary of AATCC Test Method 124-2014 Smoothness Appearance of Fabrics after Repeated Home Laundering; 2014; accessed at https://members.aatcc.org/store/tm124/533/ on Aug. 29, 2017. [cited by applicant]
ASTM D5225 Standard Test Method for Measuring Solution Viscosity of Polymers with a Differential Viscometer; ASTM International; 2003; pp. 4. [cited by applicant]
AATCC Test Method 169-2009 Weather Resistance of Textiles: Xenon Lamp Exposure; AATCC Technical Manual/2010; pp. 7. [cited by applicant]
Summary of ASTM D2616-12 Standard Test Method of Evaluation of Visual Color Differences with a Gray Scale; 2012; accessed at https://www.astm.org/Standards/D2616.htm on Aug. 29, 2017. [cited by applicant]
ISO 105-A05—Textiles—Tests for Colour Fastness; Indian Standard; ISO; 1996; pp. 1-4. [cited by applicant]
Summary of ISO 105-E04; Textiles—Tests for colour fastness—Part E04: Colour fastness to perspiration; accessed at: https://www.iso.org/standrd/57973.html on Oct. 6, 2017. [cited by applicant]
Summary of ISO 105-C06:2010; Textiles—Tests for colour fastness—Part C06: Colour Fastness to domestic and commercial laundering; 2010; accessed at: https://www.iso.org/standard/51276.html on Aug. 29, 2017. [cited by applicant]
Summary of AATCC Test Method 8 Colorfastness to Crocking; Crockmeter Method; 2013; accessed at https://members.aatcc.org/store/tm8/481/ on Oct. 5, 2017. [cited by applicant]
Summary of AATCC Test Method 135-2015 Dimensional Changes of Fabrics after Home Laundering; 2015; accessed at: https://members.aatcc.org/store/tm135/543/ on Oct. 5, 2017. [cited by applicant]
Summary of AATCC Test Method 179-2012 Skewness Change in Fabric and Garment Twist; 2012; accessed at https// members.aatcc.org/store.tm179/577/ on Oct. 5, 2017. [cited by applicant]
Summary of ISO 105-B02:2014—Textiles—Tests for colour fastness—Part B02: Colour fastness to artificial light: xenon arc fading lamp test; 2014; accessed at https://www.iso.org/standard/65209.html on Oct. 6, 2017. [cited by applicant]
Summary of ISO 105 E01:2013—Textiles—Tests for colour fastness—Part E01: Colour fastness to water; accessed at: https://www.iso.org/standard/57962.html on Oct. 5, 2017. [cited by applicant]
Summary of ISO 105-A06:1995—Textiles—Tests for colour fastness—Part A06: Instrumental determination of 1/1 standard depth of colour; accessed at: https://ww.iso.org/standard/3790.html on Oct. 5, 2017. [cited by applicant]
Ho, et al.; Effects of Spinning Conditions on Properties of Polyester Yarn Prepared using an Ultra-high-speed Melt Spinning Technique Equipped with a Steam Chamber; Bull. Korean Chem. Soc. 2010, vol. 31, No. 11, pp. 325… [cited by applicant]
Berkowitz, “Viscosity-molecular weight relationships for poly(ethlene trerphthalate) in hexafluoroisopropanol-pentafluorophenol using SEC-LALLS,” Journal of Applied Polymer Science, vol. 29, No. 12; Dec. 1, 1984, pp. 43… [cited by applicant]
Rushing et al., “Intrinisic viscosity dependence on plymer molecular weight and fluid temperature,” Journal of Applied Polymer Science, vol. 89, No. 10, Sep. 6, 2003; pp. 2831-2835. [cited by applicant]
Definition of “dye”—Tortora, Fairchild's Dictionary of Textiles, 7th Edition, 2009 Fairchild Publications. [cited by applicant]
Extended Search Report of counterpart Application No. EP16188132.1 mailed Nov. 1, 2016. [cited by applicant]
Akra Polyester Material Data Sheet (MSDS), 2009; p. 4. [cited by applicant]
Office Action issued Dec. 27, 2017 of counterpart Japanese Patent Appication No. 2016-177308. [cited by applicant]