IP Library › Granted Patent US 12,463,047
Granted Patent B2
US 12,463,047 · App. 18/587,477 · Granted Nov 4, 2025

Methods for forming stacked layers and devices formed thereof

Inventors: Shih-Yao Lin (New Taipei, TW); Kuei-Yu Kao (Hsinchu, TW); Chen-Ping Chen (Toucheng Township, TW); Chih-Han Lin (Hsinchu, TW)
Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.
H01L21/30655H01L21/30608H01L21/76831H10D84/0128H10D84/0158H10D84/038H10D84/834H01L21/02236H01L21/02247H01L21/02381H01L21/0243H01L21/0245H01L21/02488H01L21/02507H01L21/02532H01L21/3065
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Quick Facts
Patent No.
US 12,463,047
App. No.
18/587,477
Granted
Nov 4, 2025
Kind
B2
Abstract

A method includes etching a semiconductor substrate to form a trench, with the semiconductor substrate having a sidewall facing the trench, and depositing a first semiconductor layer extending into the trench. The first semiconductor layer includes a first bottom portion at a bottom of the trench, and a first sidewall portion on the sidewall of the semiconductor substrate. The first sidewall portion is removed to reveal the sidewall of the semiconductor substrate. The method further includes depositing a second semiconductor layer extending into the trench, with the second semiconductor layer having a second bottom portion over the first bottom portion, and a second sidewall portion contacting the sidewall of the semiconductor substrate. The second sidewall portion is removed to reveal the sidewall of the semiconductor substrate.

Claims (47)

1 . A method comprising:

forming a first semiconductor layer;

forming a passivation layer over the first semiconductor layer;

forming a second semiconductor layer over the passivation layer;

removing the first semiconductor layer and the passivation layer to leave a space under the second semiconductor layer; and

forming a gate stack, with a portion of the gate stack being in the space.

2 . The method of claim 1 , wherein the first semiconductor layer and the second semiconductor layer are formed of different semiconductor materials.

3 . The method of claim 1 , wherein the gate stack comprises a first portion overlapping, and a second portion overlapped by, the second semiconductor layer.

4 . The method of claim 1 , wherein the forming the first semiconductor layer and the forming the passivation layer comprise:

depositing the first semiconductor layer through a conformal process, wherein the first semiconductor layer comprises a bottom portion at a bottom of a trench in a semiconductor substrate, and a sidewall portion on a sidewall of the semiconductor substrate;

passivating a surface portion of the first semiconductor layer to form the passivation layer; and

removing the sidewall portion of the passivation layer, with the bottom portion left.

5 . The method of claim 4 , wherein the passivating is anisotropic, and the removing the sidewall portion of the passivation layer comprises an isotropic etching process.

6 . The method of claim 4 , wherein the passivating the first semiconductor layer results in both of a horizontal portion and a vertical portion of the first semiconductor layer to be partially converted into the passivation layer.

7 . The method of claim 4 , wherein the passivating comprising oxidizing.

8 . The method of claim 1 , wherein the forming the first semiconductor layer comprises depositing a silicon germanium layer or a carbon-doped silicon layer, and the forming the second semiconductor layer comprises depositing a silicon layer.

9 . The method of claim 1 further comprising patterning the first semiconductor layer, the passivation layer, and the second semiconductor layer to form a multi-layer stack.

10 . The method of claim 1 further comprising etching a semiconductor substrate to form a trench, wherein the first semiconductor layer, the passivation layer, and the second semiconductor layer comprise lower portions in the trench.

11 . The method of claim 10 further comprising:

patterning the lower portions to form a narrowed multi-layer stack; and

forming shallow trench isolations on opposite sides of the narrowed multi-layer stack.

12 . The method of claim 11 , wherein the removing the first semiconductor layer and the passivation layer are performed after the shallow trench isolations are formed.

13 . A method comprising:

forming a trench in a substrate;

depositing a first semiconductor layer comprising a portion in the trench;

forming a first passivation layer on the first semiconductor layer, wherein the first passivation layer is formed by adding first elements into a surface layer of the first semiconductor layer;

depositing a second semiconductor layer on the first passivation layer, wherein the first semiconductor layer and the second semiconductor layer comprise different semiconductor materials;

forming a second passivation layer on the second semiconductor layer, wherein the second passivation layer is formed by adding second elements into a second surface layer of the second semiconductor layer; and

forming a gate-all-around (GAA) transistor based on the first semiconductor layer, the first passivation layer, the second semiconductor layer, and the second passivation layer, wherein the second semiconductor layer acts as a channel of the GAA transistor.

14 . The method of claim 13 , wherein the forming the GAA transistor further comprises:

patterning the first semiconductor layer, the first passivation layer, the second semiconductor layer, and the second passivation layer to form a multi-layer stack;

removing the first semiconductor layer, the first passivation layer, and the second passivation layer from the multi-layer stack; and

forming a gate stack encircling the second semiconductor layer.

15 . The method of claim 14 , wherein in the patterning, a portion of the substrate underlying the substrate is etched to form a semiconductor strip, and wherein the multi-layer stack overlaps the semiconductor strip.

16 . The method of claim 13 , wherein a first top surface of the second passivation layer is lower than a second top surface of the substrate.

17 . A method comprising:

repeating a plurality of cycles to form a multi-layer stack in a trench in a substrate, wherein a cycle in the plurality of cycles comprises:

growing a first semiconductor layer in the trench;

forming a first passivation layer overlapping the first semiconductor layer; and

forming a second semiconductor layer over the first passivation layer;

patterning the multi-layer stack;

generating a space overlapping the first semiconductor layer, wherein the generating the space comprises removing the first passivation layer and the second semiconductor layer; and

forming a gate stack, with a portion of the gate stack in the space.

18 . The method of claim 17 , wherein the cycle further comprises:

forming a second passivation layer over the second semiconductor layer, wherein the generating the space further comprises removing the second passivation layer.

19 . The method of claim 18 , wherein the gate stack encircles the first semiconductor layer.

20 . The method of claim 18 , wherein the trench has a top width and a bottom width greater than the top width.

Continuity (4)
Continuation 17818608 · Aug 9, 2022
Continuation 16870389 · May 8, 2020
Provisional Application 62927547 · Oct 29, 2019
Related Publication 20240243011A1 · Jul 18, 2024
References Cited (25)
US 9478600B2 · Wang et al. · 2016 [cited by applicant]
US 9634007B2 · Pillarisetty et al. · 2017 [cited by applicant]
US 10784106B2 · Huang et al. · 2020 [cited by applicant]
US 10811502B1 · Khemka et al. · 2020 [cited by applicant]
US 11488858B2 · Lin · 2022 [cited by examiner]
US 11942363B2 · Lin · 2024 [cited by examiner]
US 20100123220A1 · Burke et al. · 2010 [cited by applicant]
US 20140154849A1 · Wang et al. · 2014 [cited by applicant]
US 20150037970A1 · Hasebe et al. · 2015 [cited by applicant]
US 20150249086A1 · Divakaruni et al. · 2015 [cited by applicant]
US 20170243941A1 · Yeh et al. · 2017 [cited by applicant]
US 20180366375A1 · Chen · 2018 [cited by examiner]
US 20190006492A1 · Wang et al. · 2019 [cited by applicant]
US 20190109004A1 · Huang et al. · 2019 [cited by applicant]
US 20200044095A1 · Wang et al. · 2020 [cited by applicant]
CN 106252386A · 2016 [cited by applicant]
DE 102018105996A1 · 2019 [cited by applicant]
JP 2003273368A · 2003 [cited by applicant]
KR 20090012583A · 2009 [cited by applicant]
KR 20110108220A · 2011 [cited by applicant]
KR 20150038419A · 2015 [cited by applicant]
KR 20170136961A · 2017 [cited by applicant]
WO 2018039654A1 · 2018 [cited by applicant]
Takenaka, et al., “Anisotropic deposition of copper of H-assisted plasma chemical vapor deposition,” Materials Science in Semiconductor Processing, vol. 5, 2003, pp. 301-304. [cited by applicant]
“What in the world is Engimatics? CVD of Titanium NItride and Other Battier Metals,” Titanium NItride, Apr. 22, 2021, 7 pages. [cited by applicant]