Method of manufacturing a brazing sheet
A brazing-sheet manufacturing method includes superposing a core-material slab on or adjacent to at least one surface of a filler-material slab to form a clad slab, the core-material slab being composed of an aluminum material and the filler-material slab being composed of an Al—Si—Mg series alloy. Then, the clad slab is hot rolled to form a clad sheet having a core material layer composed of the aluminum material of the core-material slab and a filler material layer composed of the Al—Si—Mg series alloy of the filler-material slab. Then, the clad sheet is subjected to one or more passes of cold rolling. Either between cold-rolling passes or after the completion of the cold rolling, a surface of the clad sheet is etched using a liquid etchant that includes one or more inorganic acids. The liquid etchant does not contain fluorine atoms.
1 . A brazing-sheet manufacturing method for brazing an aluminum material in an inert-gas atmosphere without using flux, comprising:
a layering process in which a clad slab is manufactured that comprises: a core-material slab composed of an aluminum material; and a filler-material slab composed of an Al—Si—Mg series alloy and disposed on at least one surface of the core-material slab;
a hot-rolling process in which a clad sheet—which comprises: a core material composed of the core-material slab; and a filler material composed of the filler-material slab and disposed on at least one surface of the core-material slab—is manufactured by performing hot rolling on the clad slab;
a cold-rolling process in which one or more passes of cold rolling are performed on the clad sheet; and
an etching process in which, between cold-rolling passes in the cold-rolling process or after the completion of the cold-rolling process, a surface of the clad sheet is etched using a liquid etchant that includes one or more inorganic acids,
wherein the liquid etchant does not contain fluorine atoms.
2 . The brazing-sheet manufacturing method according to claim 1 , wherein the Al—Si—Mg series alloy that constitutes the filler-material slab contains Si: 3 mass % or more and 13 mass % or less, Mg: 0.1 mass % or more and 2.0 mass % or less, and Bi: 1.0 mass % or less.
3 . The brazing-sheet manufacturing method according to claim 1 , wherein the liquid etchant further contains ferric sulfate.
4 . The brazing-sheet manufacturing method according to claim 3 , wherein the liquid etchant contains sulfuric acid and nitric acid as the inorganic acids.
5 . The brazing-sheet manufacturing method according to claim 4 , wherein, in the liquid etchant, the concentration of sulfuric acid is 0.20 mass % or more and 2.0 mass % or less, the concentration of nitric acid is 0.02 mass % or more and 0.50 mass % or less, and the concentration of ferric sulfate is 0.10 mass % or more and 1.0 mass % or less.
6 . The brazing-sheet manufacturing method according to claim 5 , wherein the Al—Si—Mg series alloy that constitutes the filler-material slab contains Si: 3 mass % or more and 13 mass % or less, Mg: 0.1 mass % or more and 2.0 mass % or less, and Bi: 1.0 mass % or less.
7 . The brazing-sheet manufacturing method according to claim 1 , wherein the aluminum material of the core-material slab contains 0.10 to 4.0 mass % Mg.
8 . The brazing-sheet manufacturing method according to claim 1 , wherein the aluminum material of the core-material slab contains 0.40 to 1.0 mass % Mg.
9 . The brazing-sheet manufacturing method according to claim 7 , wherein the aluminum material of the core-material slab contains:
0.05 to 1.60 mass % Mn;
1.0 mass % or less Si;
1.0 mass % or less Fe;
2.0 mass % or less Cu;
6.5 mass % or less Zn;
0.20 mass % or less Ti;
0.50 mass % or less Cr; and
0.50 mass % or less Zr.
10 . The brazing-sheet manufacturing method according to claim 9 , wherein the Al—Si—Mg series alloy that constitutes the filler-material slab contains:
3-13 mass % Si;
0.1-2.0 mass % Mg; and
1.0 mass % or less Bi.
11 . The brazing-sheet manufacturing method according to claim 1 , wherein the one or more inorganic acids in the liquid etchant are 0.2-3.70 mass % sulfuric acid and 0.5 mass % or less nitric acid.
12 . The brazing-sheet manufacturing method according to claim 1 , wherein the liquid etchant contains 0.05-1.0 mass % ferric sulfate.
13 . The brazing-sheet manufacturing method according to claim 1 , wherein the liquid etchant contains 0.10-1.0 mass % ferric sulfate.
14 . A manufacturing method, comprising:
superposing a core-material slab on or adjacent to at least one surface of a filler-material slab to form a clad slab, the core-material slab being composed of an aluminum material and the filler-material slab being composed of an Al—Si—Mg series alloy;
hot rolling the clad slab to form a clad sheet having a core material layer composed of the aluminum material of the core-material slab and a filler material layer composed of the Al—Si—Mg series alloy of the filler-material slab;
subjecting the clad sheet to one or more passes of cold rolling; and
either between cold-rolling passes or after the completion of the cold rolling, etching a surface of the clad sheet using a liquid etchant that includes one or more inorganic acids,
wherein the liquid etchant does not contain fluorine atoms.
15 . The manufacturing method according to claim 14 , wherein the Al—Si—Mg series alloy contains:
3-13 mass % Si;
0.1-2.0 mass % Mg; and
1.0 mass % or less Bi.
16 . The manufacturing method according to claim 15 , wherein the one or more inorganic acids in the liquid etchant are 0.2-3.70 mass % sulfuric acid and 0.5 mass % or less nitric acid.
17 . The manufacturing method according to claim 15 , wherein the aluminum material of the core-material slab contains:
0.40 to 1.0 mass % Mg;
0.05 to 1.60 mass % Mn;
1.0 mass % or less Si;
1.0 mass % or less Fe;
2.0 mass % or less Cu;
6.5 mass % or less Zn;
0.20 mass % or less Ti;
0.50 mass % or less Cr; and
0.50 mass % or less Zr.
18 . The manufacturing method according to claim 17 , wherein the liquid etchant further contains ferric sulfate.
19 . The manufacturing method according to claim 17 , wherein the liquid etchant contains 0.05-1.0 mass % ferric sulfate.
20 . The manufacturing method according to claim 14 , further comprising, after the clad sheet has been etched, brazing the clad sheet without using flux.
21 . The brazing-sheet manufacturing method according to claim 1 , wherein:
in the hot-rolling process, the filler material is joined to at least one surface of the core material; and
in the etching process, at least an outermost surface of the filler material of the clad sheet is etched.
22 . The brazing-sheet manufacturing method according to claim 21 , wherein:
the Al—Si—Mg series alloy that constitutes the filler-material slab consists of 3-13 mass % Si, 0.1-2.0 mass % Mg, 1.0 mass % or less Bi, 0.30 mass % or less Li, 2.0 mass % or less Cu, 6.5 mass % or less Zn, 0.10 mass % or less Sn, 0.10 mass % or less In, 0.030 mass % or less Sr, 0.030 mass % or less Na and 0.030 mass % or less Sb, the balance being aluminum and unavoidable impurities;
the aluminum material that constitutes the core-material slab comprises 0.10 mass % Mg, and 1.0 mass % or less Si;
the liquid etchant further contains a salt that contains iron ions; and
in the etching step, 0.05-1.0 g/m 2 is removed from the outermost surface of the filler material of the clad sheet.
23 . The brazing-sheet manufacturing method according to claim 22 , wherein the liquid etchant contains:
sulfuric acid and nitric acid as the inorganic acid; and
ferric sulfate as the salt that contains iron ions.