Cosmetic O/W mascara compositions comprising polyurethane resin
According to the present invention there is provided a stable, fluid, tubing mascara composition in the form of an oil-in-water emulsion comprising: (i) at least 9% by weight of the total composition of one or more film-forming aliphatic polyurethane resins; and (ii) one or more waxes; wherein the ratio of total aliphatic polyurethane resin concentration to total wax concentration is between 0.70 and 0.92. The present invention also provides an assembly or kit for packaging and applying a mascara composition for coating eyelashes, comprising: (i) a device for packaging the mascara composition as defined above; and (ii) an applicator for the composition. The present invention also provides a method using the assembly or kit as defined above for building up layers of the mascara composition onto the eyelashes comprising: (i) applying the mascara composition to the applicator; (ii) moving the applicator so that the mascara composition is applied to the eyelashes from the roots of the eyelashes to the tips of the eyelashes; (iii) optionally repeating (ii) in order to apply an even coat of the mascara composition onto the eyelashes; and (iv) optionally repeating steps (i) to (iii), wherein subsequent reapplications of the mascara compositions are carried out whilst the mascara composition present on the eyelashes has not yet dried.
1 . A stable, fluid, tubing mascara composition in the form of an oil-in-water emulsion comprising:
(i) at least 9% by weight of the total composition of one or more film-forming aliphatic polyurethane resins; and
(ii) one or more waxes;
wherein the ratio of total aliphatic polyurethane resin concentration to total wax concentration is between 0.78 and 0.92, and
wherein paraffin wax forms between 7% and 15% of the total wax.
2 . The mascara composition of claim 1 , wherein one or more of the film-forming aliphatic polyurethane resins comprises a polyether-polyurethane resin.
3 . The mascara composition of claim 1 , wherein the total film-forming aliphatic polyurethane resin concentration is at least 10% by weight of the total composition.
4 . The mascara composition of claim 1 , wherein the one or more waxes further comprise one or more waxes chosen from one or more waxes in the group of petrolatum waxes, microcrystalline waxes, waxes of plant or animal origin, mineral waxes, polyethylene waxes, waxes obtained by the Fischer-Tropsch synthesis, a C 20 -C 40 alkyl hydroxystearyloxystearate, waxy copolymers, waxes obtained by catalytic hydrogenation of animal or vegetable oils having linear or branched C 8 -C 32 fatty chains, waxes obtained by hydrogenation of olive oil esterified with stearyl alcohol, waxes obtained by hydrogenation of castor oil esterified with cetyl alcohol, silicone waxes, and fluoro waxes.
5 . The mascara composition of claim 4 wherein the one or more waxes further comprise carnauba wax, candelilla wax, beeswax or combinations thereof.
6 . The mascara composition of claim 1 wherein the total wax concentration is at least 14% by weight of the total composition.
7 . The mascara composition of claim 1 , wherein the composition further comprises one or more emulsifiers.
8 . The mascara composition of claim 7 , wherein the total emulsifier concentration is less than 6%, by weight of the total composition.
9 . The mascara composition of claim 1 , wherein the mascara composition further comprises one or more volumising powders or fillers.
10 . The mascara composition of claim 9 , wherein the total volumising powder/filler concentration is between 2% and 20%, by weight of the total composition.
11 . The mascara composition of claim 1 , wherein the ratio of total aliphatic polyurethane resin concentration to total wax concentration is between 0.79 and 0.92.
12 . The mascara composition of claim 1 , wherein the mascara composition further comprises a water-soluble polymer.
13 . The mascara composition of claim 2 , wherein the polyether-polyurethane resin comprises a PPG-17/IPDI/DMPA copolymer.
14 . The mascara composition of claim 9 , wherein the volumising powders or fillers are chosen from one or more volumising powders or fillers in the group of HDI/trimethylol hexyllactone crosspolymer, polyamide powders, nylon powders, rayon, silica, treated silica, zinc stearate, mica, kaolin, polyethylene powder, PTFE powders, starch, boron nitride, copolymer microspheres, silicone resin microbeads, talc, mica, synthetic fluorphlogopite and combinations thereof.
15 . The mascara composition of claim 9 , wherein the total volumising powder/filler concentration is between 8% and 12%, by weight of the total composition.
16 . The mascara composition of claim 1 , wherein the ratio of total aliphatic polyurethane resin concentration to total wax concentration is between 0.78 and 0.82.
17 . The mascara composition of claim 12 , wherein the water-soluble polymer is chosen from one or more water-soluble polymers in the group of gums, dextrin, starch, proteins, hydroxyethylcellulose, methylcellulose, ethylcellulose, carboxymethyl cellulose, methyl starch, carboxymethyl starch, soluble starch, polyvinyl alcohol, polyvinylmethylether, sodium polyacrylate, polyacrylate crosspolymer, polyacrylic acid, bentonite, laponite, non-dispersed silicon, and magnesium aluminium silicate.