Structuring premixes and liquid compositions comprising them
A structuring premix having a non-polymeric, crystalline, hydroxyl-containing structuring agent and at least two nonionic surfactants having a low HLB and a high HLB. A liquid fabric care composition that includes such a structuring premix. A process for making a structured liquid fabric care composition.
1 . A structuring premix comprising:
a) about 1.0% to about 16% by weight of a non-polymeric, crystalline, hydroxyl-containing structuring agent comprising crystallizable glyceride;
b) about 4.0% to about 20% of at least two nonionic surfactants, wherein the at least two nonionic surfactants comprise:
(i) at least one low HLB nonionic surfactant, wherein the at least one low HLB nonionic surfactant has an HLB of about 5.0 to about 9.5, and wherein the structuring premix comprises about 0.5% to about 8.0% by weight of the low HLB nonionic surfactant;
(ii) at least one high HLB nonionic surfactant, wherein the at least one high HLB nonionic surfactant has an HLB of about 10.5 to about 16.0, and wherein the structuring premix comprises about 1.5% to about 16% by weight of the high HLB nonionic surfactant;
wherein the average HLB of the at least two nonionic surfactants is about 11 to about 12.5, and the nonionic surfactants for both the low HLB nonionic surfactant and high HLB nonionic surfactant are selected from alkoxylated alcohol nonionic surfactants, alkyl polyglucoside nonionic surfactants, and mixtures thereof,
wherein the average HLB is the weight average of the HLBs of the individual surfactants; and
c) from 45% to 97% by weight of the premix of water, wherein the premix comprises no additional surfactant beyond the nonionic surfactant and anionic surfactant, and the premix comprises less than 5% by weight of the anionic surfactant.
2 . The structuring premix according to claim 1 , wherein the structuring premix comprises about 1.0% to about 10% by weight of the non-polymeric, crystalline, hydroxyl-containing structuring agent.
3 . The structuring premix according to claim 2 , wherein the structuring premix comprises about 2.0% to about 6.0% by weight of the non-polymeric, crystalline, hydroxyl-containing structuring agent.
4 . The structuring premix according to claim 1 , wherein:
a) the at least one low HLB nonionic surfactant has an HLB of about 7.5 to about 9.0;
b) the at least one high HLB nonionic surfactant has an HLB of about 12.0 to about 14.5; and
wherein the average HLB of the at least two nonionic surfactants is about 11.0 to about 12.0.
5 . The structuring premix according to claim 1 , wherein the structuring premix comprises about 10% to about 16% by weight of nonionic surfactant.
6 . The structuring premix according to claim 1 , wherein the structuring premix comprises:
a) about 2.0% to about 6.0% by weight of the low HLB nonionic surfactant; and
b) about 6.0% to about 8.0% by weight of the high HLB nonionic surfactant.
7 . The structuring premix according to claim 1 , wherein the premix comprises 0.25% to 1.0% by weight of anionic surfactant.
8 . The structuring premix according to claim 1 , wherein, if present, the anionic surfactant is selected from the group consisting of alkyl sulphate surfactant, alkyl alkoxy sulphate surfactant, linear alkyl benzene sulphonate surfactant, and mixtures thereof.
9 . The structuring premix according to claim 8 , wherein, if present, the anionic surfactant is linear alkyl benzene sulphonate surfactant.
10 . The structuring premix according to claim 1 , wherein the crystallisable glyceride comprises hydrogenated castor oil.
11 . The structuring premix according to claim 1 , wherein the structuring premix has a viscosity of about 10 to about 10,000 Pa·s, at a steady state shear rate of about 0.01 s −1 , at about 25° C.
12 . The structuring premix according to claim 1 , wherein the structuring premix further comprises at least one suspended particulate or droplet.
13 . A process for making a structured liquid fabric care composition, comprising the steps of:
a) providing a structuring premix according to claim 1 ;
b) combining the structuring premix with a liquid fabric care composition.
14 . A liquid fabric care composition comprising a structuring premix according to claim 1 , wherein the liquid fabric care composition comprises less than about 7.5% of anionic surfactant.
15 . The liquid fabric care composition according to claim 14 , wherein the fabric care composition comprises particulates, wherein the particulates are selected from the group consisting of encapsulates, oils, pearlescent agents, non-water-soluble polymers, and mixtures thereof.
16 . The liquid fabric care composition according to claim 14 , wherein the fabric care composition comprises a cationic ingredient, wherein the cationic ingredient is selected from the group consisting of: quaternary ammonium ester softening actives, cationic antimicrobial agents, cationic polymeric deposition aids, cationically coated encapsulated perfumes, and mixtures thereof.
17 . The structuring premix according to claim 1 , wherein the structuring premix exhibits a yield point of greater than 20, according to the Rheology method.