Multilayer coil component
A multilayer coil component includes a multilayer body in which a plurality of insulating layers are stacked in a stacking direction and a coil inside, and outer electrodes on surfaces of the multilayer body and electrically connected to the coil. The insulating layers have a magnetic phase having spinel structure containing at least Fe, Ni, Zn, and Cu and a non-magnetic phase containing at least Si. When grain sizes D50 and D90 of crystal grains constituting the magnetic phase are respectively defined as equivalent-area circle diameters of 50% and 90% on a cumulative sum basis in a cumulative distribution of equivalent-area circle diameters of the crystal grains, the grain size D50 is from 50 nm to 750 nm, and the grain size D90 is from 200 nm to 1500 nm.
1 . A multilayer coil component comprising:
a multilayer body in which a plurality of insulating layers are stacked in a stacking direction, and a coil inside the multilayer body; and
outer electrodes that are on surfaces of the multilayer body and are electrically connected to the coil,
wherein
the multilayer body has a first end surface and a second end surface, which face each other in a length direction, a first main surface and a second main surface, which face each other in a height direction perpendicular to the length direction, and a first side surface and a second side surface, which face each other in a width direction perpendicular to the length direction and the height direction,
the outer electrodes include a first outer electrode that extends from at least part of the first end surface of the multilayer body across part of the first main surface, and a second outer electrode that extends from at least part of the second end surface of the multilayer body across part of the first main surface,
a stacking direction of the plurality of insulating layers in the multilayer body and a coil axis direction of the coil are parallel to the first main surface,
the insulating layers have a magnetic phase having a spinel structure containing at least Fe, Ni, Zn, and Cu and a non-magnetic phase containing at least Si,
when grain sizes D50 and D90 of crystal grains constituting the magnetic phase are respectively defined as equivalent-area circle diameters of 50% and 90% on a cumulative sum basis in a cumulative distribution of equivalent-area circle diameters of the crystal grains,
the grain size D50 is from 50 nm to 750 nm, and
the grain size D90 is from 200 nm to 1500 nm,
wherein a full width at half maximum of a diffraction peak originating from a (642) plane of the magnetic phase at 20=86 to 87° obtained though X-ray diffraction using a Cu-Kα1 line is from 0.2° to 0.5°.
2 . The multilayer coil component according to claim 1 , wherein
the insulating layers contain
B at from 2 wt % to 11 wt % in terms of B 2 O 3 ,
Si at from 18 wt % to 66 wt % in terms of SiO 2 ,
Fe at from 13 wt % to 52 wt % in terms of Fe 2 O 3 ,
Ni at from 1 wt % to 7 wt % in terms of NiO,
Zn at from 4 wt % to 16 wt % in terms of ZnO, and
Cu at from 1 wt % to 5 wt % in terms of CuO.
3 . A multilayer coil component comprising:
a multilayer body in which a plurality of insulating layers are stacked in a stacking direction, and a coil inside the multilayer body; and
outer electrodes that are on surfaces of the multilayer body and are electrically connected to the coil,
wherein
the multilayer body has a first end surface and a second end surface, which face each other in a length direction, a first main surface and a second main surface, which face each other in a height direction perpendicular to the length direction, and a first side surface and a second side surface, which face each other in a width direction perpendicular to the length direction and the height direction,
the outer electrodes include a first outer electrode that extends from at least part of the first end surface of the multilayer body across part of the first main surface, and a second outer electrode that extends from at least part of the second end surface of the multilayer body across part of the first main surface,
a stacking direction of the plurality of insulating layers in the multilayer body and a coil axis direction of the coil are parallel to the first main surface,
the insulating layers have a magnetic phase having a spinel structure containing at least Fe, Ni, Zn, and Cu and a non-magnetic phase containing at least Si,
when grain sizes D50 and D90 of crystal grains constituting the magnetic phase are respectively defined as equivalent-area circle diameters of 50% and 90% on a cumulative sum basis in a cumulative distribution of equivalent-area circle diameters of the crystal grains,
the grain size D50 is from 50 nm to 750 nm, and
the grain size D90 is from 200 nm to 1500 nm,
wherein the insulating layers contain
B at from 2 wt % to 11 wt % in terms of B 2 O 3 ,
Si at from 18 wt % to 66 wt % in terms of SiO 2 ,
Fe at from 13 wt % to 52 wt % in terms of Fe 2 O 3 ,
Ni at from 1 wt % to 7 wt % in terms of NiO,
Zn at from 4 wt % to 16 wt % in terms of ZnO, and
Cu at from 1 wt % to 5 wt % in terms of CuO.