Granted Patent B2

US 12,486,411 · App. 17/660,850 · Granted Dec 2, 2025

Inventors: Shih-Wa Wang (Glen Mills, PA); Michael S. Wolfe (Wilmington, DE); John R. Moore (Lansdale, PA); Petra Stoffel (Cologne, DE)

Assignee: AXALTA COATING SYSTEMS IP CO., LLC

C09D11/023C09D11/03C09D11/102C09D11/107C09D11/38

Abstract

Claims (64)

1 . A method of applying a one-component waterborne coating composition to a substrate utilizing a high transfer efficiency applicator to form a coating layer disposed on the substrate, the method comprising the steps of:

providing the coating composition to the high transfer efficiency applicator; and

applying the coating composition to the substrate through the high transfer efficiency applicator to form the coating layer on the substrate wherein a loss of volatiles after application through the high transfer efficiency applicator is less than about 0.5 weight percent actives based on a total weight of the coating composition,

wherein the coating composition has a pH of greater than about 7 and comprises:

A. a resin dispersion comprising a latex, a polyurethane, or combinations thereof;

B. an optional cross-linker;

C. an optional pigment;

D. water;

E. a water-soluble solvent; and

F. at least one rheology control agent chosen from an alkali swellable emulsion, a layered silicate, and combinations thereof;

wherein the coating composition has a viscosity of about 20 to about 100 mPa·s as determined using ASTM 7867-13 with cone-and-plate or parallel plates at a shear rate of 1000 sec-1,

wherein the coating composition has a viscosity of from about 2000 to about 6500 mPa·s as determined using ASTMD7867 at a shear rate of 0.1 sec-1,

wherein the coating composition has a wet film thickness of at least 20 microns measured at about 45 degrees without visible sag, and

wherein the coating composition has a wet film thickness of at least 71 microns measured at about 45 degrees without fat edge.

2 . The method of claim 1 wherein:

A. the resin dispersion is present in an amount of from about 10 to about 35 weight percent actives based on a total weight of the composition;

B. the cross-linker is melamine and is present in an amount of from about 2 to about 8 weight percent actives based on a total weight of the composition;

C. the pigment is present in an amount of from about 0.1 to about 20 weight percent actives based on a total weight of the composition;

D. the water is present in an amount of from about 15 to about 80 weight percent actives based on a total weight of the composition;

E. the water soluble solvent is present in a total amount of from about 5 to about 25 weight percent actives based on a total weight of the composition; and

F. the at least one rheology control agent is present in an amount of from about 0.01 to about 7 weight percent actives based on a total weight of the composition;

wherein the coating composition has a viscosity of about 35 to about 95 cPs as determined using ASTM 7867-13 with cone-and-plate or parallel plates at a shear rate of 1000 sec-1, and

wherein the coating composition has a wet film thickness of at least about 20 microns measured at about 45 degrees without visible sag as determined using ASTM D4400-18.

3 . The method of claim 1 wherein:

A. the resin dispersion is present in an amount of from about 12 to about 20 weight percent actives based on a total weight of the composition and comprises:

an acrylic latex dispersion present in an amount of from about 3 to about 5 weight percent actives based on a total weight of the composition and that is a polyester-modified acrylic dispersion containing epoxy groups;

a first polyurethane dispersion present in an amount of about 1.5 to about 2.5 weight percent actives based on a total weight of the composition and that is formed from a branched polyester polyol and hexamethylene diisocyanate;

a second polyurethane dispersion present in an amount of from about 1 to about 2 weight percent actives based on a total weight of the composition and that is formed from a linear polyester diol resin and isophorone diisocyanate wherein the linear polyester diol is the reaction product of 1,6-hexanediol, adipic acid, and isophthalic acid; and

a third polyurethane dispersion present in an amount of from about 0.5 to about 1.5 weight percent actives based on a total weight of the composition and that is formed from a linear polycarbonate-polyester polyol and isophorone diisocyanate;

B. the cross-linker is melamine and is present in an amount of from about 3 to about 4 weight percent actives based on a total weight of the composition;

C. the pigment dispersion is present in an amount of from about 0.5 to about 4.5 weight percent actives based on a total weight of the composition;

D. the water is present in an amount of from about 55 to about 70 weight percent actives based on a total weight of the composition;

E. the water soluble solvent is butanol and is present in an amount of from about 10 to about 20 weight percent actives based on a total weight of the composition; and

F. the at least one rheology control agent is the alkali swellable emulsion that is an acrylic copolymer emulsion and that is present in an amount of from about 0.1 to about 2 weight percent actives based on a total weight of the composition;

wherein the coating composition has a viscosity of about 35 to about 70 cps as determined using ASTM 7867-13 with cone-and-plate or parallel plates at a shear rate of 1000 sec-1, and

wherein the coating composition has a wet film thickness of at least about 20 microns measured at about 45 degrees without visible sag as determined using ASTM D4400-18.

4 . The method of claim 1 wherein the coating composition consists essentially of (A)-(F) wherein:

A. the resin dispersion is present in an amount of from about 10 to about 35 weight percent actives based on a total weight of the composition;

B. the cross-linker is melamine and is present in an amount of from about 2 to about 8 weight percent actives based on a total weight of the composition;

C. the pigment is present in an amount of from about 0.1 to about 20 weight percent actives based on a total weight of the composition;

D. the water is present in an amount of from about 15 to about 70 weight percent actives based on a total weight of the composition;

E. the water soluble solvent is present in a total amount of from about 5 to about 25 weight percent actives based on a total weight of the composition;

the coating composition has a viscosity of about 35 to about 95 cPs as determined using ASTM 7867-13 with cone-and-plate or parallel plates at a shear rate of 1000 sec-1;

the coating composition has a wet film thickness of at least about 20 microns measured at about 45 degrees without visible sag as determined using ASTM D4400-18;

the latex is present and is chosen from a polyester-modified acrylic dispersion containing epoxy groups, a styrene-acrylic latex dispersion, and combinations thereof;

the polyurethane is present and is chosen from one formed from a branched polyester polyol and hexamethylene diisocyanate; formed from a linear polyester diol resin and isophorone diisocyanate wherein the linear polyester diol is the reaction product of 1,6-hexanediol, adipic acid, and isophthalic acid; formed from a linear polycarbonate-polyester polyol and isophorone diisocyanate; a polyester-polyurethane polymer; and combinations thereof;

the alkali swellable emulsion is present, is an acrylic copolymer emulsion, and is present in an amount of from about 0.1 to about 2 weight percent actives based on a total weight of the composition; and

the layered silicate is optionally present in an amount of from 0 to about 0.3 weight percent actives based on a total weight of the composition and is a synthetic phyllosilicate.

5 . The method of claim 1 wherein the resin dispersion is present in an amount of from about 10 to about 35 weight percent actives based on a total weight of the composition; the cross-linker is melamine and is present in an amount of from about 2 to about 8 weight percent actives based on a total weight of the composition; the pigment is present in an amount of from about 0.1 to about 20 weight percent actives based on a total weight of the composition; the water is present in an amount of from about 15 to about 70 weight percent actives based on a total weight of the composition; the water soluble solvent is present in a total amount of from about 5 to about 25 weight percent actives based on a total weight of the composition; and the at least one rheology control agent is present in an amount of from about 0.01 to about 7 weight percent actives based on a total weight of the composition; wherein the coating composition has a viscosity of about 35 to about 95 cPs as determined using ASTM 7867-13 with cone-and-plate or parallel plates at a shear rate of 1000 sec-1, and wherein the coating composition has a wet film thickness of at least about 20 microns measured at about 45 degrees without visible sag as determined using ASTM D4400-18.

6 . The method of claim 1 wherein the resin dispersion is present in an amount of from about 12 to about 20 weight percent actives based on a total weight of the composition and comprises: an acrylic latex dispersion present in an amount of from about 3 to about 5 weight percent actives based on a total weight of the composition and that is a polyester-modified acrylic dispersion containing epoxy groups; a first polyurethane dispersion present in an amount of about 1.5 to about 2.5 weight percent actives based on a total weight of the composition and that is formed from a branched polyester polyol and hexamethylene diisocyanate; a second polyurethane dispersion present in an amount of from about 1 to about 2 weight percent actives based on a total weight of the composition and that is formed from a linear polyester diol resin and isophorone diisocyanate wherein the linear polyester diol is the reaction product of 1,6-hexanediol, adipic acid, and isophthalic acid; and a third polyurethane dispersion present in an amount of from about 0.5 to about 1.5 weight percent actives based on a total weight of the composition and that is formed from a linear polycarbonate-polyester polyol and isophorone diisocyanate; the cross-linker is melamine and is present in an amount of from about 3 to about 4 weight percent actives based on a total weight of the composition; the pigment dispersion is carbon black and is present in an amount of from about 0.5 to about 4.5 weight percent actives based on a total weight of the composition; the water is present in an amount of from about 55 to about 70 weight percent actives based on a total weight of the composition; the water soluble solvent is butanol and is present in an amount of from about 10 to about 20 weight percent actives based on a total weight of the composition; and the at least one rheology control agent is the alkali swellable emulsion that is an acrylic copolymer emulsion and that is present in an amount of from about 0.1 to about 2 weight percent actives based on a total weight of the composition; wherein the coating composition has a viscosity of about 35 to about 70 cps as determined using ASTM 7867-13 with cone-and-plate or parallel plates at a shear rate of 1000 sec-1, and wherein the coating composition has a wet film thickness of at least about 20 microns measured at about 45 degrees without visible sag as determined using ASTM D4400-18.

7 . The method of claim 1 wherein the alkali swellable emulsion is present and is an acrylic copolymer emulsion and the layered silicate is present and is a synthetic phyllosilicate.

8 . The method of claim 1 wherein:

the latex is chosen from a polyester-modified acrylic dispersion containing epoxy groups, a styrene-acrylic latex dispersion, and combinations thereof; and

the polyurethane is chosen from one formed from a branched polyester polyol and hexamethylene diisocyanate; formed from a linear polyester diol resin and isophorone diisocyanate wherein the linear polyester diol is the reaction product of 1,6-hexanediol, adipic acid, and isophthalic acid; formed from a linear polycarbonate-polyester polyol and isophorone diisocyanate; a polyester-polyurethane polymer; and combinations thereof.

9 . The method of claim 8 wherein the latex is the polyester-modified acrylic dispersion containing epoxy groups.

10 . The method of claim 9 wherein the polyurethane is formed from a branched polyester polyol and hexamethylene diisocyanate.

11 . The method of claim 9 wherein the polyurethane is formed from a linear polyester diol resin and isophorone diisocyanate wherein the linear polyester diol is the reaction product of 1,6-hexanediol, adipic acid, and isophthalic acid.

12 . The method of claim 9 wherein the polyurethane is formed from a linear polycarbonate-polyester polyol and isophorone diisocyanate.

13 . The method of claim 9 wherein the polyurethane is a polyester-polyurethane polymer.

14 . The method of claim 8 wherein the latex is the styrene-acrylic latex dispersion.

15 . The method of claim 14 wherein the polyurethane is formed from a branched polyester polyol and hexamethylene diisocyanate.

16 . The method of claim 14 wherein the polyurethane is formed from a linear polyester diol resin and isophorone diisocyanate wherein the linear polyester diol is the reaction product of 1,6-hexanediol, adipic acid, and isophthalic acid.

17 . The method of claim 14 wherein the polyurethane is formed from a linear polycarbonate-polyester polyol and isophorone diisocyanate.

18 . The method of claim 14 wherein the polyurethane is a polyester-polyurethane polymer.

Assignments (1)

Continuity (2)

References Cited (18)