Organic electroluminescence device and electronic apparatus provided with the same
An organic electroluminescence device induing a cathode, an anode, and an emitting layer disposed between the cathode and the anode, wherein the emitting layer contains a compound represented by the following formula (1) and one or more compounds selected from the group consisting of a compound represented by formula (11), a compound represented by formula (21), a compound represented by formula (31), a compound represented by formula (41), a compound represented by formula (51), a compound represented by formula (61), a compound represented by formula (71) and a compound represented by formula (81). In the formula (1), at east one of R 1 to R 8 is a deuterium atom.
1 . An organic electroluminescence device comprising:
a cathode,
an anode, and
an emitting layer disposed between the cathode and the anode, wherein
the emitting layer comprises a compound represented by the following formula (1) and one or more compounds selected from the group consisting of a compound represented by formula (11), a compound represented by formula (21), a compound represented by formula (31), a compound represented by formula (41), a compound represented by formula (51), a compound represented by formula (61), a compound represented by formula (71) and a compound represented by formula (81):
wherein in the formula (1), each of R 1 to R 8 is a deuterium atom,
L 1 and L 2 are independently
a single bond,
a substituted or unsubstituted phenylene group,
a substituted or unsubstituted naphthylene group,
a substituted or unsubstituted biphenylene group,
a substituted or unsubstituted terphenylene group,
a substituted or unsubstituted anthrylene group, or
a substituted or unsubstituted phenanthrylene group;
Ar 1 and Ar 2 are independently
a substituted or unsubstituted phenyl group,
a substituted or unsubstituted naphthyl group,
a substituted or unsubstituted biphenyl group,
a substituted or unsubstituted terphenyl group,
a substituted or unsubstituted anthryl group, or
a substituted or unsubstituted phenanthryl group;
when L 1 , L 2 , Ar 1 and Ar 2 have a substituent, the substituent is an alkyl group having 1 to 50 carbon atoms,
an alkenyl group having 2 to 50 carbon atoms,
an alkynyl group having 2 to 50 carbon atoms,
a cycloalkyl group having 3 to 50 ring carbon atoms,
an alkylsilyl group having 1 to 50 carbon atoms,
a halogen atom, or
a cyano group;
wherein, in the formula (11),
one or more pairs of two or more adjacent groups of R 101 to R 110 are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring;
at least one of R 101 to R 110 is a monovalent group represented by the formula (12);
R 101 to R 110 that do not form the substituted or unsubstituted, saturated or unsaturated ring and that are not a monovalent group represented by the following formula (12) are independently
a hydrogen atom,
a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms,
a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms,
a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms,
a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms,
—Si(R 901 )(R 902 )(R 903 ),
—O—(R 904 ),
—S—(R 905 ),
N(R 906 )(R 907 ),
a halogen atom, a cyano group, a nitro group,
a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or
a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;
R 901 to R 907 are as defined in the formula (1);
wherein, in the formula (12), Ar 101 and Ar 102 are independently
a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or
a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;
L 101 to L 103 are independently
a single bonded,
a substituted or unsubstituted arylene group having 6 to 30 ring carbon atoms, or
a substituted or unsubstituted divalent heterocyclic group having 5 to 30 ring atoms;
wherein, in the formula (21),
Zs are independently CR a or N;
A1 ring and A2 ring are independently a substituted or unsubstituted aromatic hydrocarbon ring having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heterocyclic ring having 5 to 50 ring atoms;
when a plurality of R a s exist, two or more adjacent groups of R a are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring;
when a plurality of R b s exist, two or more adjacent groups of R b are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring;
when a plurality of R c s exist, one or more pairs of two or more adjacent groups of R c are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring;
n21 and n22 are independently an integer of 0 to 4;
R a to R c that do not form the substituted or unsubstituted, saturated or unsaturated ring are independently
a hydrogen atom,
a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms,
a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms,
a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms,
a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms,
—Si(R 901 )(R 902 )(R 903 ),
—O—(R 904 ),
—S—(R 905 ),
—N(R 906 )(R 907 ),
a halogen atom, a cyano group, a nitro group,
a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or
a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;
R 901 to R 907 are as defined in the formula (1);
wherein, in the formula (31),
one or more pairs of two or more adjacent groups of R 301 to R 307 and R 311 to R 317 form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted saturated or unsaturated ring;
R 301 to R 307 and R 311 to R 317 that do not form the substituted or unsubstituted, saturated or unsaturated ring are independently
a hydrogen atom,
a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms,
a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms,
a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms,
a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms,
—Si(R 901 )(R 902 )(R 903 ),
—O—(R 904 ),
—S—(R 905 ),
—N(R 906 )(R 907 ),
a halogen atom, a cyano group, a nitro group,
a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or
a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;
R 321 and R 322 are independently
a hydrogen atom,
a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms,
a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms,
a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms,
a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms,
—Si(R 901 )(R 902 )(R 903 ),
—O—(R 904 ),
—S—(R 905 ),
—N(R 906 )(R 907 ),
a halogen atom, a cyano group, a nitro group,
a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or
a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;
R 901 to R 907 are as defined in the formula (1);
wherein, in the formula (41),
a ring, b ring and c ring are independently
a substituted or unsubstituted aromatic hydrocarbon ring having 6 to 50 ring carbon atoms, or
a substituted or unsubstituted heterocyclic ring having 5 to 50 ring atoms;
R 401 and R 402 are independently bonded to the a ring, the b ring or the c ring to form a substituted or unsubstituted heterocyclic ring or do not form a substituted or unsubstituted heterocyclic ring;
R 401 and R 402 that do not form the substituted or unsubstituted heterocyclic ring are independently
a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms,
a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms,
a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms,
a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms,
a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or
a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;
wherein, in the formula (51),
r ring is a ring represented by the formula (52) or formula (53) which is fused to an adjacent ring at an arbitrary position;
q ring and s ring are independently a ring represented by the formula (54) which is fused to an adjacent ring at an arbitrary position;
p ring and t ring are independently a ring represented by the formula (55) or the formula (56) which is fused to an adjacent ring at an arbitrary position;
when a plurality of R 501 s exist, adjacent R 501 s are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring;
X 501 is an oxygen atom, a sulfur atom, or NR 502 ;
R 501 and R 502 that do not form the substituted or unsubstituted saturated or unsaturated ring are
a hydrogen atom,
a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms,
a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms,
a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms,
a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms,
—Si(R 901 )(R 902 )(R 903 ),
—O—(R 904 ),
—S—(R 905 ),
—N(R 906 )(R 907 ),
a halogen atom, a cyano group, a nitro group,
a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or
a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;
R 901 to R 907 are as defined in the formula (1);
Ar 501 and Ar 502 are independently
a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms,
a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms,
a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms,
a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms,
a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or
a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;
L 501 is
a substituted or unsubstituted alkylene group having 1 to 50 carbon atoms,
a substituted or unsubstituted alkenylene group having 2 to 50 carbon atoms,
a substituted or unsubstituted alkynylene group having 2 to 50 carbon atoms,
a substituted or unsubstituted cycloalkylene group having 3 to 50 ring carbon atoms,
a substituted or unsubstituted arylene group having 6 to 50 ring carbon atoms, or
a substituted or unsubstituted divalent heterocyclic group having 5 to 50 ring atoms;
m1 is an integer of 0 to 2, m2 is an integer of 0 to 4, m3s are independently an integer of 0 to 3, and m4s are independently an integer of 0 to 5; when a plurality of R 501 s exist, R 501 s may be the same or different;
wherein, in the formula (61),
at least one pair of R 601 and R 602 , R 602 and R 603 , and R 603 and R 604 are bonded with each other to form a divalent group represented by the formula (62);
at least one pair of R 605 and R 606 , R 606 and R 607 , and R 607 and R 608 are bonded with each other to form a divalent group represented by formula (63);
at least one of R 601 to R 604 that does not form the divalent group represented by the formula (62), and R 611 to R 614 is a monovalent group represented by the following formula (64);
at least one of R 605 to R 608 that do not form the divalent group represented by the formula (63), and R 621 to R 624 is a monovalent group represented by the following formula (64);
X 601 is an oxygen atom, a sulfur atom, or NR 609 ;
R 601 to R 608 that do not form the divalent group represented by the formulas (62) and (63) and that is not the monovalent group represented by the formula (64), R 611 to R 614 and R 621 to R 624 that are not the monovalent group represented by the formula (64), and R 609 are independently
a hydrogen atom,
a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms,
a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms,
a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms,
a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms,
—Si(R 901 )(R 902 )(R 903 ),
—O—(R 904 ),
—S—(R 905 ),
—N(R 906 )(R 907 ),
a halogen atom, a cyano group, a nitro group,
a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or
a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;
R 901 to R 907 are as defined in the formula (1);
wherein, in the formula (64), Ar 601 and Ar 602 are independently
a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or
a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;
L 601 to L 603 are independently
a single bonded,
a substituted or unsubstituted arylene group having 6 to 30 ring carbon atoms,
a substituted or unsubstituted divalent heterocyclic group having 5 to 30 ring atoms, or
a divalent linking group formed by bonding 2 to 4 of a substituted or unsubstituted arylene group having 6 to 30 ring carbon atoms, and a substituted or unsubstituted divalent heterocyclic group having 5 to 30 ring atoms;
wherein, in the formula (71),
A 701 ring and A 702 ring are independently
a substituted or unsubstituted aromatic hydrocarbon ring having 6 to 50 ring carbon atoms, or
a substituted or unsubstituted heterocyclic ring having 5 to 50 ring atoms;
One or more rings selected from the group consisting of A 701 ring and A 702 ring are bonded to the bond * of the structure represented by the following formula (72);
wherein, in the formula (72),
A 703 rings are independently
a substituted or unsubstituted aromatic hydrocarbon ring having 6 to 50 ring carbon atoms, or
a substituted or unsubstituted heterocyclic ring having 5 to 50 ring atoms;
X 701 is NR 703 , C(R 704 )(R 705 ), Si(R 706 ) (R 707 ), Ge(R 708 ) (R 709 ), O, S or Se;
R 701 and R 702 are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring or do not form a substituted or unsubstituted saturated or unsaturated ring;
R 701 and R 702 that do not form the substituted or unsubstituted, saturated or unsaturated ring, and R 703 to R 709 are independently
a hydrogen atom,
a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms,
a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms,
a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms,
a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms,
—Si(R 901 )(R 902 )(R 903 ),
—O—(R 904 ),
—S—(R 905 ),
—N(R 906 )(R 907 ),
a halogen atom, a cyano group, a nitro group,
a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or
a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;
R 901 to R 907 are as defined in the formula (1);
wherein, in the formula (81),
A 801 ring is a ring represented by the formula (82) which is fused to an adjacent ring at an arbitrary position;
A 802 ring is a ring represented by the formula (83) which is fused to an adjacent ring at an arbitrary position;
two bonds * bond to A 803 ring at an arbitrary position;
X 801 and X 802 are independently C(R 803 )(R 804 ), Si(R 85 )(R 806 ), an oxygen atom, or a sulfur atom;
A 803 ring is a substituted or unsubstituted aromatic hydrocarbon ring having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heterocyclic ring having 5 to 50 ring atoms;
Ar 801 is a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;
R 801 to R 806 are independently
a hydrogen atom,
a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms,
a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms,
a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms,
a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms,
—Si(R 901 )(R 902 )(R 903 ),
—O—(R 904 ),
—S—(R 905 ),
—N(R 906 )(R 907 ),
a halogen atom, a cyano group, a nitro group,
a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or
a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;
R 901 to R 907 are as defined in the formula (1);
m801 and m802 are independently an integer of 0 to 2; when m801 is 2, R 801 's may be the same as or different from each other, and when m802 is 2, R 802 's may be the same as or different from each other;
a801 is an integer of 0 to 2; when a801 is 0 or 1, the structure in the parentheses indicated by “3-a801” may be the same or different from each other; when a801 is 2, Ar 801 s may be the same or different from each other, wherein
the emitting layer comprises
the compound represented by the formula (1), and
a non-deuterated compound having the structure same as the compound represented by the formula (1) except for containing only protium atoms as hydrogen atoms, and
a content of the compound represented by the formula (1) is from 30 mass % to 99 mass % based on a combined amount of the compound represented by the formula (1) and the non-deuterated compound.
2 . The organic electroluminescence device according to claim 1 , wherein in the formula (1), at least one hydrogen atom possessed in one or more selected from the group consisting of L 1 and L 2 is a deuterium atom.
3 . The organic electroluminescence device according to claim 1 , wherein in the formula (1), L 1 and L 2 are independently a single bond, a substituted or unsubstituted phenylene group, or a substituted or unsubstituted naphthylene group.
4 . The organic electroluminescence device according to claim 1 , wherein in the formula (1), at least one hydrogen atom possessed in one or more selected from the group consisting of Ar 1 and Ar 2 is a deuterium atom.
5 . The organic electroluminescence device according to claim 1 , wherein in the formula (1), Ar 1 and Ar 2 are independently a substituted or unsubstituted phenyl group, a substituted or unsubstituted naphthyl group, or a substituted or unsubstituted phenanthryl group.
6 . The organic electroluminescence device according to claim 1 , wherein in the formula (11), two of R 101 to R 110 are the groups represented by the formula (12).
7 . The organic electroluminescence device according to claim 1 , wherein the compound represented by the formula (11) is a compound represented by the following formula (13):
wherein in the formula (13), R 111 to R 118 are the same as R 101 to R 110 in the formula (11) that are not a monovalent group represented by the formula (12); and Ar 101 , Ar 102 , L 101 , L 102 and L 103 are as defined in the formula (12).
8 . The organic electroluminescence device according to claim 7 , wherein the compound represented by the formula (13) is a compound represented by the following formula (14):
wherein in the formula (14), R 111 to R 118 are as defined in the formula (13), and Ar 101 , Ar 102 , L 102 and L 103 are as defined in the formula (12).
9 . The organic electroluminescence device according to claim 7 , wherein the compound represented by the formula (13) is a compound represented by the following formula (15):
wherein in the formula (15), R 111 to R 118 are as defined in the formula (13), and Ar 101 and Ar 102 are as defined in the formula (12).
10 . The organic electroluminescence device according to claim 7 , wherein the compound represented by the formula (13) is a compound represented by the following formula (17):
wherein in the formula (17), R 111 to R 118 are as defined in the formula (13);
one or more sets of adjacent two or more of R 121 to R 127 are form a substituted or unsubstituted, saturated or unsaturated ring by bonding with each other, or do not form a substituted or unsubstituted, saturated or unsaturated ring;
R 121 to R 127 that do not form the substituted or unsubstituted, saturated or unsaturated ring are independently
a hydrogen atom,
a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms,
a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms,
a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms,
a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms,
—Si(R 901 )(R 902 )(R 903 ),
—O—(R 904 ),
—S—(R 905 ),
—N(R 906 )(R 907 ),
a halogen atom, a cyano group, a nitro group,
a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or
a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;
R 901 to R 907 are as defined in the formula (1);
R 131 to R 135 are independently
a hydrogen atom,
a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms,
a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms,
a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms,
a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms,
—Si(R 901 )(R 902 )(R 903 ),
—O—(R 904 ),
—S—(R 905 ),
—N(R 906 )(R 907 ),
a halogen atom, a cyano group, a nitro group,
a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or
a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; and
R 901 to R 907 are as defined in the formula (1).
11 . The organic electroluminescence device according to claim 1 , wherein in the formula (41), the a ring, the b ring and the c ring are independently a substituted or unsubstituted aromatic hydrocarbon ring having 6 to 50 ring carbon atoms.
12 . The organic electroluminescence device according to claim 1 , wherein in the formula (41), R 401 and R 402 are independently a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms.
13 . The organic electroluminescence device according to claim 1 , wherein in the formula (41), R 401 and R 402 are independently a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms.
14 . The organic electroluminescence device according to claim 1 , wherein the compound represented by the formula (41) is a compound represented by the following formula (42):
wherein in the formula (42),
R 401A forms a substituted or unsubstituted heterocyclic ring by bonding with one or more selected from the group consisting of R 411 and R 421 , or does not form a substituted or unsubstituted heterocyclic ring, and R 402A forms a substituted or unsubstituted heterocyclic ring by bonding with one or more selected from the group consisting of R 413 and R 414 , or does not form a substituted or unsubstituted heterocyclic ring;
R 401A and R 402A that do not form the substituted or unsubstituted heterocyclic ring are independently
a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms,
a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms,
a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms,
a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms,
a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or
a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;
at least one pair of adjacent two or more of R 411 to R 421 forms a substituted or unsubstituted, saturated or unsaturated ring by bonding with each other, or do not form a substituted or unsubstituted, saturated or unsaturated ring;
R 411 to R 421 that do not form the substituted or unsubstituted heterocyclic ring or the substituted or unsubstituted, saturated or unsaturated ring are independently
a hydrogen atom,
a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms,
a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms,
a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms,
a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms,
—Si(R 901 )(R 902 )(R 903 ),
—O—(R 904 ),
—S—(R 905 ),
—N(R 906 )(R 907 ),
a halogen atom, a cyano group, a nitro group,
a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or
a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; and
R 901 to R 907 are as defined in the formula (1).
15 . The organic electroluminescence device according to claim 1 , wherein the compound represented by the formula (41) is a compound represented by the following formula (43):
wherein in the formula (43),
R 431 forms a substituted or unsubstituted heterocyclic ring by bonding with R 446 , or does not form a substituted or unsubstituted heterocyclic ring, R 433 forms a substituted or unsubstituted heterocyclic ring by bonding with R 447 , or does not form a substituted or unsubstituted heterocyclic ring, R 434 forms a substituted or unsubstituted heterocyclic ring by bonding with R 451 , or does not form a substituted or unsubstituted heterocyclic ring, and R 441 forms a substituted or unsubstituted heterocyclic ring by bonding with R 442 , or does not form a substituted or unsubstituted heterocyclic ring;
at least one pair of adjacent two or more of R 431 to R 451 forms a substituted or unsubstituted, saturated or unsaturated ring by bonding with each other, or does not form a substituted or unsubstituted, saturated or unsaturated ring;
R 431 to R 451 that do not form the substituted or unsubstituted heterocyclic ring, or the substituted or unsubstituted, saturated or unsaturated ring are independently
a hydrogen atom,
a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms,
a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms,
a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms,
a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms,
—Si(R 901 )(R 902 )(R 903 ),
—O—(R 904 ),
—S—(R 905 ),
—N(R 906 )(R 907 ),
a halogen atom, a cyano group, a nitro group,
a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or
a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; and
R 901 to R 907 are as defined in the formula (1).
16 . The organic electroluminescence device according to claim 1 , which further comprises a hole-transporting layer between the anode and the emitting layer.
17 . The organic electroluminescence device according to claim 1 , which further comprises an electron-transporting layer between the cathode and the emitting layer.
18 . An electronic appliance wherein the organic electroluminescence device according to claim 1 is provided.