IP Library › Granted Patent US 12,492,149
Granted Patent B2
US 12,492,149 · App. 19/013,139 · Granted Dec 9, 2025

Ceramic sintered body and plasma-generating electrode

Inventors: Tsuneyuki Ito (Nagoya, JP); Shinji Ban (Nagoya, JP); Osamu Yoshimoto (Nagoya, JP); Tomoo Tanaka (Nagoya, JP)
Assignee: Niterra Co., Ltd.
C04B35/5626C04B35/5607C04B35/5622H01B1/04H01J37/3255C04B2235/3217C04B2235/3246C04B2235/3839C04B2235/3843C04B2235/3847C04B2235/80
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Quick Facts
Patent No.
US 12,492,149
App. No.
19/013,139
Granted
Dec 9, 2025
Kind
B2
Abstract

A ceramic sintered body contains a first particular element consisting of five or six elements selected from among titanium (Ti), vanadium (V), zirconium (Zr), niobium (Nb), molybdenum (Mo), hafnium (Hf), tantalum (Ta), and tungsten (W); a second particular element consisting of one element selected from yttrium (Y) and aluminum (Al); and elemental carbon (C). The total amount of the first particular element, the second particular element, and elemental carbon is 98 at % or more. The ceramic sintered body has a plurality of microstructures having respective compositions different from one another. One of the plurality of microstructures includes a solid solution containing at least three members of the first particular element.

Claims (29)

1 . A ceramic sintered body, which comprises

a first particular element consisting of five or six elements selected from among the group consisting of titanium (Ti), vanadium (V), zirconium (Zr), niobium (Nb), molybdenum (Mo), hafnium (Hf), tantalum (Ta), and tungsten (W);

a second particular element consisting of one element selected from the group consisting of yttrium (Y) and aluminum (Al); and

elemental carbon (C), wherein

a total amount of the first particular element, the second particular element, and elemental carbon is 98 at % or more;

the ceramic sintered body has a plurality of microstructures having respective compositions different from one another;

one of the plurality of microstructures includes a solid solution containing at least three members of the first particular element.

2 . The ceramic sintered body according to claim 1 ,

wherein another one of the plurality of microstructures has undergone spinodal decomposition.

3 . The ceramic sintered body according to claim 2 ,

wherein another one of the plurality of microstructures includes a solid solution containing at least two members of the first particular element.

4 . The ceramic sintered body according to claim 2 ,

which contains the second particular element in an amount of 3,000 at. ppm or less.

5 . The ceramic sintered body according to claim 2 ,

which contains elemental carbon in an amount of 45 at % or more and 55 at % or less.

6 . The ceramic sintered body according to claim 2 ,

which contains elemental iron (Fe) in an amount of 800 at. ppm or less.

7 . A plasma-generating electrode, comprising:

a ceramic sintered body as recited in claim 2 .

8 . The ceramic sintered body according to claim 1 ,

wherein another one of the plurality of microstructures includes a solid solution containing at least two members of the first particular element.

9 . The ceramic sintered body according to claim 1 ,

which contains the second particular element in an amount of 3,000 at. ppm or less.

10 . The ceramic sintered body according to claim 1 ,

which contains elemental carbon in an amount of 45 at % or more and 55 at % or less.

11 . The ceramic sintered body according to claim 1 ,

which contains elemental iron (Fe) in an amount of 800 at. ppm or less.

12 . A plasma-generating electrode, comprising:

a ceramic sintered body as recited in claim 1 .

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 8, 2025
From: ITO, TSUNEYUKI; BAN, SHINJI; YOSHIMOTO, OSAMU; TANAKA, TOMOO
To: NITERRA CO., LTD.
Reel/Frame 069782/0589 →
Priority Claims (1)
JP 2024-003706 · Jan 15, 2024 · national
Continuity (1)
Related Publication 20250230102A1 · Jul 17, 2025
References Cited (6)
US 10087517B2 · Miyanaga · 2018 [cited by examiner]
US 11230502B2 · Yagi · 2022 [cited by examiner]
US 11434174B2 · Ikeda · 2022 [cited by examiner]
JP 6929755B2 · 2021 [cited by applicant]
Liu et al “Formation of solid solution structures in (Ti,W, Ta, Mo)(C, N) cermet via spark plasma sintering”, International Journal of Refractory Metals and Hard Materials 113 (2023) 10621. [cited by examiner]
Monteverde et al “Compositional disorder and sintering of entropy stabilized (Hf, Nb, Ta, Ti, Zr) B2 solid solution powders”, Journal of the European Ceramic Society 40 (2020) 3807-3814. [cited by examiner]