Inkjet primer compositions containing nanocellulose
Inkjet primer compositions are provided, including those comprising water, a co-medium, one or more types of nanocellulose, and resin particles, wherein the resin particles comprise a polymerization product of reactants comprising one or more types of monomers. Inkjet sets for inkjet printing systems are also provided, including those comprising such an inkjet primer composition; and an aqueous inkjet ink composition for printing on an ink-receiving layer, the ink-receiving layer comprising the resin particles of the inkjet primer composition, the aqueous inkjet ink composition comprising water, a colorant, and additional resin particles.
1 . An inkjet primer composition comprising water, a co-medium, one or more types of nanocellulose, and resin particles, wherein the resin particles comprise a polymerization product of reactants comprising one or more types of metal chelating monomers, wherein the one or more types of metal chelating monomers comprise one or more types of phosphoric acid monomers; one or more types of sulfonic acid monomers; or both one or more types of phosphoric acid and one or more types of sulfonic acid monomers,
wherein the reactants further comprise one or more types of acidic monomers comprising (meth)acrylic acid monomers,
wherein a total amount of polymerized metal chelating monomers and polymerized (meth)acrylic acid monomers in the resin particles is at least about 8 weight % and a total amount of polymerized metal chelating monomers in the resin particles is at least about 4 weight %,
wherein a weight ratio of a total amount of polymerized metal chelating monomers in the resin particles to a total amount of polymerized (meth)acrylic acid monomers in the resin particles is less than about 0.5, and
further wherein the inkjet primer composition is free of a colorant.
2 . The inkjet primer composition of claim 1 , wherein the one or more types of nanocellulose comprise cellulose nanocrystals.
3 . The inkjet primer composition of claim 1 , wherein the reactants do not comprise 4-methylstyrene, cyclohexyl acrylate, isobornyl methacrylate, isobornyl acrylate, or combinations thereof.
4 . The inkjet primer composition of claim 1 , wherein the one or more types of phosphoric acid monomers are present and comprise those having formula P(O)(OR) 3 , wherein each R is independently selected from hydrogen and ethyl(meth)acrylate and at least one R is the ethyl(meth)acrylate.
5 . The inkjet primer composition of claim 1 ,
wherein the one or more types of phosphoric acid monomers comprise those having formula P(O)(OR) 3 , wherein each R is independently selected from hydrogen and ethyl(meth)acrylate and at least one R is the ethyl(meth)acrylate;
the reactants further comprise one or more types of hydrophobic monomers comprising styrene and an alkyl(meth)acrylate; and
the reactants further comprise a reactive surfactant.
6 . The inkjet primer composition of claim 5 , wherein the one or more types of nanocellulose comprise cellulose nanocrystals.
7 . The inkjet primer composition of claim 1 , wherein the polymerization product comprises poly[(styrene)-ran-(butyl acrylate)-ran-(phosphoric acid 2-hydroxyethyl methacrylate ester)-ran-(bis[2-(methacryloyloxy)ethyl]phosphate)-ran-(methacrylic acid)-ran-(anionic ether sulfate).
8 . The inkjet primer composition of claim 7 , wherein a total amount of polymerized phosphoric acid 2-hydroxyethyl methacrylate ester, polymerized bis[2-(methacryloyloxy)ethyl]phosphate, and polymerized methacrylic acid in the resin particles is at least about 8 weight %; a total amount of polymerized phosphoric acid 2-hydroxyethyl methacrylate ester and polymerized bis[2-(methacryloyloxy)ethyl] phosphate in the resin particles is at least about 4 weight %; and a weight ratio of a total amount of polymerized phosphoric acid 2-hydroxyethyl methacrylate ester and polymerized bis[2-(methacryloyloxy)ethyl] phosphate in the resin particles to a total amount of polymerized methacrylic acid in the resin particles is less than about 0.5.
9 . The inkjet primer composition of claim 7 , consisting of the water, the co-medium, the one or more types of nanocellulose, the resin particles, and optionally, one or more of a surfactant, a wetting agent, and a defoamer.
10 . The inkjet primer composition of claim 1 , wherein the inkjet primer composition is free of a non-polymerized acid and the inkjet primer composition has a pH of from 7.5 to 9.
11 . The inkjet primer composition of claim 1 , consisting of the water, the co-medium, the one or more types of nanocellulose, the resin particles, and optionally, one or more of a surfactant, a wetting agent, and a defoamer.
12 . An inkjet set for an inkjet printing system, the inkjet set comprising:
an inkjet primer composition comprising water, a co-medium, one or more types of nanocellulose, and resin particles, wherein the resin particles comprise a polymerization product of reactants comprising one or more types of metal chelating monomers; and
and an aqueous inkjet ink composition for printing on an ink-receiving layer, the ink-receiving layer comprising the resin particles of the inkjet primer composition, the aqueous inkjet ink composition comprising water, a colorant, and additional resin particles,
wherein in the inkjet primer composition, the one or more types of metal chelating monomers comprise one or more types of phosphoric acid monomers; one or more types of sulfonic acid monomers; or both one or more types of phosphoric acid monomers and one or more types of sulfonic acid monomers,
wherein the reactants further comprise one or more types of acidic monomers comprising (meth)acrylic acid monomers,
wherein a total amount of polymerized metal chelating monomers and polymerized (meth)acrylic acid monomers in the resin particles is at least about 8 weight % and a total amount of polymerized metal chelating monomers in the resin particles is at least about 4 weight %,
wherein a weight ratio of a total amount of polymerized metal chelating monomers in the resin particles to a total amount of polymerized (meth)acrylic acid monomers in the resin particles is less than about 0.5, and
further wherein the inkjet primer composition is free of a colorant.
13 . The inkjet set of claim 12 , wherein the resin particles of the inkjet primer composition are negatively charged in the inkjet primer composition and the additional resin particles of the aqueous inkjet ink composition are negatively charged in the aqueous inkjet ink composition.
14 . The inkjet set of claim 12 , wherein the additional resin particles of the aqueous inkjet ink composition are the same as the resin particles of the inkjet primer composition.
15 . The inkjet set of claim 12 , wherein the aqueous inkjet ink composition printed onto the ink-receiving layer exhibits a gloss differential value of less than about 1 unit; wherein an about 9 ng drop of the aqueous inkjet ink composition printed onto the ink-receiving layer exhibits a wet rub resistance of at least about 20; or both.
16 . The inkjet set of claim 12 , wherein the inkjet primer composition is free of a non-polymerized acid and the inkjet primer composition has a pH of from 7.5 to 9.
17 . The inkjet set of claim 12 , wherein the inkjet primer composition consists of the water, the co-medium, the one or more types of nanocellulose, the resin particles, and optionally, one or more of a surfactant, a wetting agent, and a defoamer.
18 . The inkjet set of claim 12 , wherein the polymerization product of the resin particles comprises poly[(styrene)-ran-(butyl acrylate)-ran-(phosphoric acid 2-hydroxyethyl methacrylate ester)-ran-(bis[2-(methacryloyloxy)ethyl]phosphate)-ran-(methacrylic acid)-ran-(anionic ether sulfate).
19 . The inkjet set of claim 18 , wherein the inkjet primer composition consists of the water, the co-medium, the one or more types of nanocellulose, the resin particles, and optionally, one or more of a surfactant, a wetting agent, and a defoamer.