Versatile method for purifying glyceridic materials
The invention provides a method for the purifying of low-quality glyceridic material usually unfit for use as feed or food. The method includes a thermal treatment of the low-quality glyceridic material and chemical treatments. The purified oils and fat are suitable feed-stock or suitable components thereof for a hydrogenation processes yielding to high quality renewable diesel. The process thus permits the recycling of waste material that is usually discarded, into a valuable high-quality fuel.
1 . A method for the purification of low-quality glyceridic material to yield a purified glyceridic material, said low-quality glyceridic material containing triglycerides, partial glycerides, free fatty acids and P, Na, K, Mg, Ca and Fe, said purification process including:
(a) a thermal treatment of the low-quality glyceridic material at a temperature of at least 160° C., to yield a thermally treated low-quality glyceridic material,
(b) allowing to cool the thermally treated low-quality glyceridic material of step a) at a temperature of 120° C. or lower to yield a cooled thermally treated low-quality glyceridic material, and
(c) applying one or more standard refining technique(s) to said cooled thermally treated low-quality glyceridic material of step b),
wherein said low-quality glyceridic material contain at least 500 ppm of alkalinity,
wherein prior to the thermal treatment, the method further comprises a pre-treatment that does not decrease the natural alkalinity of the low-quality glyceridic feedstock below an alkalinity of 500 ppm,
wherein said method is devoid of an FFA stripping step,
wherein said one or more standard refining technique(s) include water washing, acidulated water washing, water degumming, acid degumming, bleaching realized with bleaching agent(s),
wherein said thermal treatment of the low-quality glyceridic material is realized in a hermitical vessel under pressure ranging from 100 mbar to 10 bar.
2 . The method according to claim 1 , wherein said method removes at least 90% of the phosphorus and at least 95% of the sum of elements Na, K, Mg, Ca and Fe from said low-quality glyceridic material.
3 . The method according to claim 1 , wherein said thermal treatment of the low-quality glyceridic material is occurring in absence of any solvent and further in absence of any reactant.
4 . The method according to claim 1 , wherein said thermal treatment includes heating the low-quality glyceridic material at a temperature ranging from 160° C. to 300° C.
5 . The method according to claim 1 , wherein said thermal treatment of the low-quality glyceridic material is realized during a period of time ranging from 5 minutes to 120 minutes.
6 . The method according to claim 1 , wherein said thermal treatment of the low-quality glyceridic material is realized in the hermitical vessel under a pressure ranging from 200 mbar to 8 bar.
7 . The method according to claim 1 , wherein said thermal treatment of the low-quality glyceridic material is realized under a rotating mechanical agitation having a frequency ranging from 0.01 to 100 hertz.
8 . The method according to claim 1 , wherein the low-quality glyceridic material is at least partially water washed prior said thermal treatment.
9 . The method according to claim 1 , wherein the low-quality glyceridic material is at least partially washed with an aqueous acidic solution prior said thermal treatment.
10 . The method according to claim 1 , wherein the low-quality glyceridic material is at least partially degummed prior to said thermal treatment.
11 . The method according to claim 1 , wherein said low-quality glyceridic material contain at least 5% of FFA.
12 . The method according to claim 1 , wherein said low-quality glyceridic material contain at least 500 ppm of alkalinity, said alkalinity being defined at the sum of Na, K, Mg, Ca and Fe.
13 . The method according to claim 1 , wherein said method further includes a filtration step, said filtration step removing solid particles.
14 . The method according to claim 13 , wherein said filtration step includes using a filter aid.
15 . The method according to claim 1 , wherein said low-quality glyceridic materials include waste oils or fats of vegetable or animal origins, recycled oils or fats of vegetable or animal origins, rendered animal fats, acid oils.