Fluorine-containing alcohol composite
View Patent ↗A fluorine-containing alcohol composite comprising a condensate of a fluorine-containing alcohol represented by the general formula: HO-A-R F -A-OH [I] (wherein R F is a group containing a perfluoroalkylene group or a polyfluoroalkylene group having 6 or less carbon atoms and an ether bond, and A is an alkylene group having 1 to 3 carbon atoms), a hydroxyl group-containing polymer, and a zirconium compound. The fluorine-containing alcohol composite, using a fluorine-containing alcohol, does not produce perfluorooctanoic acid and the like when released into the environment and that has a unit easily decomposed into short chain compounds. And also, it exhibits hydrophilic oil repellency.
1 . A fluorine-containing alcohol composite comprising a condensate of:
a fluorine-containing alcohol represented by the general formula:
HO-A-R F -A-OH [I]
wherein R F is a group containing a perfluoroalkylene group or a polyfluoroalkylene group having 6 or less carbon atoms, and an ether bond, and A is an alkylene group having 1 to 3 carbon atoms,
a hydroxyl group-containing polymer, and
a zirconium compound; wherein
the fluorine-containing alcohol, the hydroxyl group-containing polymer, and the zirconium compound are subjected to a condensation reaction in the presence of a basic or acidic catalyst to form the fluorine-containing alcohol composite.
2 . The fluorine-containing alcohol composite according to claim 1 , wherein organic silicon compound is further comprised.
3 . The fluorine-containing alcohol composite according to claim 1 , wherein as the fluorine-containing alcohol represented by the general formula [I], a perfluoroalkylene ether diols represented by the general formula:
HO(CH 2 ) a CF(CF 3 )[OCF 2 CF(CF 3 )] b O(CF 2 ) c O[CF(CF 3 )CF 2 O] d CF(CF 3 )(CH 2 ) a OH [III]
wherein a is an integer of 1 to 3, b+d is an integer of 0 to 50, and c is an integer of 1 to 6 is used.
4 . The fluorine-containing alcohol composite according to claim 1 , wherein the hydroxyl group-containing polymer is polyvinyl alcohol.
5 . The fluorine-containing alcohol composite according to claim 1 , wherein the zirconium compound is zirconium oxychloride.
6 . The fluorine-containing alcohol composite according to claim 2 ,
wherein the organic silicon compound is tetra lower alkyl orthosilicate.
7 . The method for producing a condensate according to claim 1 , wherein the hydroxyl group-containing polymer is used at a 0.5 to 10 times ratio, and the zirconium compound is used at a 5 times or less ratio, based on the fluorine-containing alcohol.
8 . The method for producing a condensate according to claim 1 , wherein the organic silicon compound is used at a 5 times or less ratio, based on the fluorine-containing alcohol.
9 . The method for producing a condensate according to claim 1 , wherein the basic catalyst is an ammonia aqueous solution.
10 . The method for producing a condensate according to claim 1 , wherein the acidic catalyst is an inorganic acid.
11 . A surface treatment agent, comprising the fluorine-containing alcohol composite according to claim 1 , as an active ingredient.
12 . The surface treatment agent according to claim 11 , which exhibits hydrophilic oil repellency.
13 . A substrate with a coating film formed from the surface treatment agent according to claim 11 .