Method for manufacturing a high strength steel product and steel product thereby obtained
A method for manufacturing a steel product includes providing a heated steel starting product at a temperature between 380° C. and 700° C., with a composition comprising, in percent by weight: 0.15%≤C≤0.40%, 1.5%≤Mn≤4.0%, 0.5%≤Si≤2.5%, 0.005%≤Al≤1.5%, with 0.8%≤Si+Al≤2.5%, S≤0.05%, P≤0.1%, at least one element chosen among Cr and Mo; subjecting the starting product to a hot forming step at a temperature between 700° C. and 380° C., to obtain a fully austenitic product; then quenching the product by cooling it down, to a quenching temperature QT lower than Ms in order to obtain a structure containing between 40% and 90% of martensite; then maintaining or reheating the product to a holding temperature PT between QT and 470° C. and holding the temperature PT for a duration Pt between 5 s and 600 s.
1 . A steel product having a composition consisting of, in percent by weight:
0.15%≤C≤0.40%,
1.5%≤Mn≤4.0%,
0.5%≤Si≤2.5%,
0.005%≤Al≤1.5%,
with 0.8%≤Si+Al≤2.5%,
S≤0.05%,
P≤0.1%,
Nb≤0.1%,
Ti≤0.1%,
Ni≤3.0%,
0.0005%≤B≤0.005%,
0.0005%≤Ca≤0.005%
at least one element chosen among Cr and Mo, such that:
0%≤Cr≤4.0%,
0%≤Mo≤0.5%,
and
2.7%≤Mn+Cr+3 Mo≤5.7%,
a balance of the composition consisting of iron and unavoidable impurities resulting from smelting,
a structure of at least one location of the steel product consisting of:
tempered martensite or laths of martensite without carbides, with an area percentage of at least 40%, the martensite laths having an average size less than 1 μm, said martensite laths having an aspect ratio comprised between 2 and 5, said tempered martensite and the martensite laths comprising, in area percentage, less than 0.5% of carbides, as compared to a surface of said tempered martensite and martensite laths,
fresh martensite, the fresh martensite having a shape of islands or films, an area percentage of said fresh martensite being between 5% and 30%, and
austenite, with an area percentage of 5% to 35%.
2 . The steel product according to claim 1 , wherein a product of a tensile strength TS of the steel by a uniform elongation UE of the steel is greater than or equal to 13000 MPa %.
3 . The steel product according to claim 1 , wherein the islands of fresh martensite having an aspect ratio lower than 3 have a maximal size lower than 3 μm.
4 . The steel product according to claim 1 , wherein the structure has an average prior austenitic grain size lower than 30 μm.
5 . The steel product according to claim 1 , wherein the structure has a prior austenitic grain aspect ratio higher than 1.3.
6 . The steel product according to claim 1 , wherein said austenite is in a shape of films or islands, a smallest dimension of said films or islands being lower than 0.3 μm, a largest dimension of said films or islands being lower than 2 μm on average.
7 . The steel product according to claim 1 , wherein said carbides have an average size lower than 50 nm.
8 . The steel product according to claim 1 , wherein said steel product is a steel sheet, and the whole of the steel sheet has a structure consisting of:
tempered martensite or laths of martensite without carbides, with an area percentage of at least 40%,
fresh martensite, the fresh martensite having a shape of islands or films, an area percentage of said fresh martensite being comprised between 5% and 30%, and
austenite, with an area percentage from 5% to 35%.
9 . The steel product according to claim 1 , wherein said steel product is a hot stamped steel part, and a structure of at least 20% of a volume of said hot-stamped steel part consists of:
tempered martensite or laths of martensite without carbides, with an area percentage of at least 40%,
fresh martensite, the fresh martensite having a shape of islands or films, an area percentage of said fresh martensite being comprised between 5% and 30%, and
austenite, with an area percentage from 5% to 35%.
10 . The steel product according to claim 9 , wherein said steel product comprises at least one coating layer.
11 . The steel product according to claim 10 , wherein said coating layer is zinc or zinc-based alloy, or aluminum or aluminum based alloy.
12 . The steel product according to claim 11 , wherein said coating layer is applied before hot stamping.