Frictional transmission belt and production method therefor
A frictional power transmission belt includes a compression rubber layer having a frictional power transmission surface that is covered with a fabric. The compression rubber layer includes an inner rubber layer in contact with the fabric and an outer rubber layer on an outer peripheral side of the inner rubber layer. The inner rubber layer is formed of a cured product of a rubber composition including a surfactant as a hydrophilic plasticizer, an unsaturated carboxylic acid metal salt, and polyolefin particles.
1 . A frictional power transmission belt comprising a compression rubber layer having a frictional power transmission surface that is covered with a fabric, the compression rubber layer comprising an inner rubber layer in contact with the fabric and an outer rubber layer on an outer peripheral side of the inner rubber layer,
wherein the inner rubber layer is formed of a cured product of a rubber composition comprising a surfactant as a hydrophilic plasticizer, an unsaturated carboxylic acid metal salt, and polyolefin particles, and
a proportion of the unsaturated carboxylic acid metal salt is 2 to 10 parts by mass with respect to 100 parts by mass of a rubber component forming the inner rubber layer, and
wherein the inner rubber layer further comprises a metal oxide and a content of the surfactant is 20-200 parts by mass per 100 parts by mass of the metal oxide.
2 . The frictional power transmission belt according to claim 1 , wherein the fabric comprises a cellulose-based fiber.
3 . The frictional power transmission belt according to claim 1 , wherein the polyolefin particles comprise ultra-high molecular weight polyethylene particles.
4 . The frictional power transmission belt according to claim 1 , wherein a thickness ratio of the inner rubber layer to the entire compression rubber layer is 1% to 50%.
5 . The frictional power transmission belt according to claim 1 , further comprising a cord extending in a longitudinal direction of a belt body, wherein a tensile elastic modulus of fibers constituting the cord is 50 GPa or more.
6 . The frictional power transmission belt according to claim 5 , wherein the cord is formed of at least one of an aramid fiber and a carbon fiber.
7 . The frictional power transmission belt according to claim 1 , wherein the outer rubber layer does not comprise polyolefin particles.
8 . The frictional power transmission belt according to claim 1 , which is a V-ribbed belt.
9 . The frictional power transmission belt according to claim 1 , wherein a proportion of the polyolefin particles is 2 to 35 parts by mass with respect to 100 parts by mass of a rubber component forming the inner rubber layer.
10 . The frictional power transmission belt according to claim 1 , wherein a proportion of the hydrophilic plasticizer is 1 to 10 parts by mass with respect to 100 parts by mass of a rubber component forming the inner rubber layer.
11 . The frictional power transmission belt according to claim 1 , wherein the rubber component forming the inner rubber layer is an ethylene-α-olefin elastomer.
12 . The frictional power transmission belt according to claim 1 , wherein the fabric is impregnated with a resorcin-formalin-latex liquid.
13 . The frictional power transmission belt according to claim 1 , wherein the inner rubber layer has a thickness of 0.1 mm to 0.25 mm.
14 . A method for producing a frictional power transmission belt, the method comprising:
disposing, on a cylindrical inner mold disposed in a hollow cylindrical outer mold, an unvulcanized laminate including an unvulcanized rubber sheet for a compression rubber layer and a fabric laminated on the unvulcanized rubber sheet so that the fabric is directed toward the outer mold;
pressurizing the unvulcanized laminate at least toward the outer mold to vulcanize the unvulcanized laminate; and
demolding a molded body of the vulcanized rubber sheet and the fabric to produce a frictional power transmission belt having a predetermined form,
wherein the unvulcanized rubber sheet is formed of an unvulcanized rubber sheet for an inner rubber layer in contact with the fabric and an unvulcanized rubber sheet for an outer rubber layer on an outer peripheral side of the unvulcanized rubber sheet for the inner rubber layer,
the unvulcanized rubber sheet for the inner rubber layer is formed of a rubber composition comprising a surfactant as a hydrophilic plasticizer, an unsaturated carboxylic acid metal salt, and polyolefin particles,
a proportion of the unsaturated carboxylic acid metal salt is 2 to 10 parts by mass with respect to 100 parts by mass of a rubber component forming the inner rubber layer, and
wherein the inner rubber layer further comprises a metal oxide and a content of the surfactant is 20-200 parts by mass per 100 parts by mass of the metal oxide.
15 . The production method according to claim 14 , wherein the unvulcanized laminate is pressurized and vulcanized at a pressure of 1.2 MPa or more.
16 . The production method according to claim 14 , wherein the unvulcanized rubber sheet for the compression rubber layer is prepared by rolling an unvulcanized rubber sheet with a calender roll to form the unvulcanized rubber sheet for the inner rubber layer to be in contact with the fabric, and laminating the unvulcanized rubber sheet for the inner rubber layer with the unvulcanized rubber sheet for the outer rubber layer on the calender roll.
17 . The production method according to claim 14 , comprising:
disposing the unvulcanized laminate which is a hollow cylindrical or sleeve-shaped unvulcanized laminate comprising:
an unvulcanized rubber laminated sheet for forming a belt body at least including the unvulcanized rubber sheet for the compression rubber layer and an unvulcanized rubber sheet for a tension rubber layer laminated or disposed on one surface of the unvulcanized rubber sheet for the compression rubber layer;
a cord embedded in a longitudinal direction of the unvulcanized rubber laminated sheet; and
the fabric which is a knitted fabric laminated or disposed on the other surface of the unvulcanized rubber sheet for the compression rubber layer, so that the knitted fabric is directed toward a rib mold of the outer mold; and
pressurizing and vulcanizing the unvulcanized laminate with an expansion pressure of a flexible jacket that is mounted on the inner mold and is expandable and contractable.
18 . The production method according to claim 14 , wherein the fabric is impregnated with a resorcin-formalin-latex liquid.
19 . The production method according to claim 14 , wherein the inner rubber layer has a thickness of 0.1 mm to 0.25 mm.