Flux and method for producing electronic component
Provided is a flux that can suppress the generation of voids when an indium alloy sheet is used to perform a continuous reflow under different temperature conditions. The present invention employs a flux that contains a rosin ester, an organic acid (A), and a solvent (S). The organic acid (A) includes a dimer acid (A1) that demonstrates a weight reduction rate of not more than 1 mass % in a thermogravimetric analysis in which the dimer acid is heated up to 260° C. at a temperature rising rate of 10° C./min. The solvent (S) includes a solvent (S1) that demonstrates the weight reduction rate of at least 99 mass % in a thermogravimetric analysis in which the solvent (S1) is heated up to 150° C. at a temperature rising rate of 6° C./min.
1 . A flux comprising:
a rosin ester;
an organic acid (A); and
a solvent(S),
wherein the organic acid (A) comprises a dimer acid (A1) having a weight reduction rate of 1% by mass or less when heated to 260° C. at a temperature rising rate of 10° C./min in thermogravimetric measurement, and
the solvent(S) comprises a solvent (S1) having a weight reduction rate of 99% by mass or greater when heated to 150° C. at a temperature rising rate of 6° C./min in the thermogravimetric measurement,
a content of the dimer acid (A1) is 5% by mass or greater and 70% by mass or less with respect to a total mass, 100% by mass, of the flux,
a content of the dimer acid (A1) is 75% by mass or greater with respect to a total mass of the organic acid (A),
a content of the solvent (S1) is 10% by mass or greater and 90% by mass or less with respect to the total mass, 100% by mass, of the flux, and
a content of the solvent (S1) is 70% by mass or greater with respect to a total mass of the solvent(S).
2 . The flux according to claim 1 ,
wherein the content of the solvent (S1) is 80% by mass or greater with respect to the total mass of the solvent(S).
3 . The flux according to claim 1 ,
wherein the dimer acid (A1) is at least one selected from the group consisting of dimers to which unsaturated fatty acids having 18 carbon atoms are bonded.
4 . The flux according to claim 1 ,
wherein the solvent (S1) has a boiling point of 200° C. or lower.
5 . The flux according to claim 1 , further comprising an azole.
6 . The flux according to claim 1 ,
wherein the content of the solvent (S1) is 10% by mass or greater and 75% by mass or less with respect to the total mass, 100% by mass, of the flux, and
the content of the dimer acid (A1) is 10% by mass or greater and 60% by mass or less with respect to the total mass of the flux.
7 . The flux according to claim 1 ,
wherein the content of the solvent (S1) is 10% by mass or greater and 75% by mass or less with respect to the total mass, 100% by mass, of the flux, and
a content of the rosin ester is 15% by mass or greater and 60% by mass or less with respect to a total mass of the flux.
8 . A method for producing an electronic component comprising a semiconductor package, the method comprising:
a step (i) of obtaining a semiconductor package including a bonded object in which a die and a lid are bonded to each other through a thermal interface material (TIM); and
a step (ii) of bonding a solder ball to a rear surface of the semiconductor package to obtain an electronic component,
wherein the TIM is a sheet made of an alloy consisting of indium and silver,
the step (i) comprises a heating operation (1) of bonding the die and the lid to each other by a reflow method with a flux of claim 1 being interposed on at least one side of between the TIM and the die and between the TIM and the lid, and
the step (ii) comprises a heating operation (2) of bonding the solder ball and the semiconductor package to each other by the reflow method.
9 . The method for producing an electronic component according to claim 8 ,
wherein the heating operation (1) is carried out under a temperature condition of 150° C. to 250° C., and
the heating operation (2) is carried out under a temperature condition of 200° C. to 280° C.