IP Library › Granted Patent US 12,528,699
Granted Patent B2
US 12,528,699 · App. 18/405,799 · Granted Jan 20, 2026

Systems and methods for local generation and/or consumption of hydrogen gas

Inventors: Justin B. Ashton (Palo Alto, CA); Roelof E. Groenewald (Bothell, WA); Kevin J. Hughes (Knoxville, TN); Arvind Kannan (Kirkland, WA); William Kokonaski (Edmonds, WA); Max N. Mankin (Seattle, WA); Tony S. Pan (Bothell, WA); Lowell L Wood (Bellevue, WA); John J. Lorr (Redmond, WA); Amit Goyal (Hoover, AL); Guido Radaelli (Pleasant Hill, CA); Vikram Seshadri (Redmond, WA)
Assignee: Modern Hydrogen, Inc.
C01B3/24B01J6/008B01J19/0013B01J19/2425B01J2219/00065B01J2219/00157C01B2203/0272C01B2203/1235
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 12,528,699
App. No.
18/405,799
Granted
Jan 20, 2026
Kind
B2
Abstract

Systems for producing hydrogen gas for local distribution, consumption, and/or storage, and related devices and methods are disclosed herein. A representative system includes a pyrolysis reactor that can be coupled to a supply of reaction material that includes a hydrocarbon. The reactor includes one or more flow channels positioned to transfer heat to the reaction material to convert the hydrocarbon into an output that includes hydrogen gas and carbon particulates. The system also includes a carbon separation system operably coupled to the pyrolysis reactor to separate the hydrogen gas the carbon particulates in the output. In various embodiments, the system also includes components to locally consume the filtered hydrogen gas.

Claims (50)

1 . A system for producing hydrogen gas for local distribution, consumption, and/or storage, the system comprising:

a pyrolysis reactor comprising:

an input couplable to a supply of reaction material that includes a hydrocarbon;

one or more reaction channels coupled to the input, wherein the one or more reaction channels are positioned to transfer heat to the reaction material to convert the hydrocarbon into an output flow that includes hydrogen gas and carbon particulates; and

an output thermally coupled to the input, wherein the output is positioned to transfer heat from the output flow to the reaction material in the input to preheat the reaction material in the input during operation;

a carbon separation system operably coupled to the output of the pyrolysis reactor to separate the hydrogen gas from the carbon particulates in the output flow; and

a burner couplable to the output of the pyrolysis reactor, wherein the burner is positioned to receive and combust at least a portion of the output flow.

2 . The system of claim 1 wherein the burner is thermally coupled to the one or more reaction channels and positioned to provide the heat transferred to the reaction material in the one or more reaction channels.

3 . The system of claim 1 wherein the pyrolysis reactor is sized to consume the reaction material at a consumption rate between 18 and 135,000 British thermal units per minute.

4 . The system of claim 1 wherein the pyrolysis reactor is sized to reaction material at a consumption rate between 10 and 3,350,000 million British thermal units per year.

5 . The system of claim 1 , further comprising a heating component, wherein the output is operably coupled to the heating component downstream from the carbon separation system, and wherein the heating component includes at least one of: a furnace, a forced air distribution system, a boiler, a radiator distribution system, a heat pump, a hybrid heating system, or a hydronic heating system.

6 . The system of claim 1 wherein the burner is a first burner, wherein the output is operably coupled to a second burner downstream from the carbon separation system, and wherein the second burner is a part of a heating component including at least one of: a furnace, a forced air distribution system, a boiler, a radiator distribution system, a heat pump, a hybrid heating system, or a hydronic heating system.

7 . The system of claim 1 wherein the input includes one or more coils around the output.

8 . The system of claim 1 wherein the pyrolysis reactor further comprises a carbon removal component positioned to remove carbon from the one or more reaction channels.

9 . The system of claim 8 , wherein the carbon removal component comprises one or more of:

mechanical scraping component;

a fluid scraping component;

a sloped surface of the one or more reaction channels; or

a precipitation component.

10 . The system of claim 1 wherein the pyrolysis reactor further comprises a chamber at least partially surrounding the one or more reaction channels, wherein the chamber is configured to hold a vacuum.

11 . A pyrolysis reactor for producing hydrogen gas for local distribution, consumption, and/or storage, the pyrolysis reactor comprising:

an input couplable to a supply of reaction material that includes a hydrocarbon;

a reaction chamber coupled to the input, the reaction chamber having one or more flow channels positioned to provide an input heat to the reaction material to convert the hydrocarbon into an output flow that includes hydrogen gas and carbon particulates; and

an output thermally coupled to the input to transfer at least a portion of heat in the output flow to the reaction material in the input.

12 . The pyrolysis reactor of claim 11 , further comprising a burner positioned to direct a hot flue gas through the one or more flow channels in the reaction chamber.

13 . The pyrolysis reactor of claim 12 wherein the burner is coupled to the output of the pyrolysis reactor to receive and combust at least a portion of the output flow to generate the hot flue gas.

14 . The pyrolysis reactor of claim 11 wherein the one or more flow channels are oriented in a vertical direction to reduce fouling of the one or more flow channels from the output.

15 . The pyrolysis reactor of claim 11 , further comprising:

a chamber at least partially surrounding the one or more flow channels; and

one or more heating components positioned in the chamber, wherein:

in a first state, the chamber is configured to contain a gas and conduct heat from the one or more heating components to the one or more flow channels; and

in a second state, the chamber is configured to hold a vacuum.

16 . The pyrolysis reactor of claim 11 wherein the one or more flow channels are sized to consume the reaction material at a consumption rate between 10 and 70,800 million British thermal units per year.

17 . The pyrolysis reactor of claim 11 wherein the one or more flow channels are sized to consume the reaction material at a consumption rate between 0.018 and 6105 standard cubic feet per minute.

18 . The pyrolysis reactor of claim 11 wherein the one or more flow channels are sized to consume the reaction material at a consumption rate between 10 and 3,350,000 million British thermal units per year.

19 . The pyrolysis reactor of claim 11 , further comprising a carbon separation system fluidly coupled to the output to separate the hydrogen gas from the carbon particulates in the output flow.

20 . The pyrolysis reactor of claim 11 , further comprising a carbon removal component at least partially within the reaction chamber, wherein the carbon removal component includes one or more of:

mechanical scraping component;

a fluid scraping component;

a sloped surface of the one or more flow channels; or

a precipitation component.

21 . A method for generating hydrogen gas for local distribution, consumption, and/or storage, the method comprising:

receiving, at an input of a pyrolysis reactor, a fuel gas comprising a hydrocarbon;

preheating, in the input, the fuel gas using residual heat in an output flow from the pyrolysis reactor;

heating, within one or more flow channels of the pyrolysis reactor, the fuel gas to a reaction temperature, wherein, at the reaction temperature, at least a portion of the hydrocarbon in the fuel gas converts into hydrogen gas and carbon particulates; and

separating the hydrogen gas and carbon particulates.

22 . The method of claim 21 , further comprising combusting, in a burner of the pyrolysis reactor, at least a portion of the hydrogen gas to heat the one or more flow channels of the pyrolysis reactor.

23 . The method of claim 21 wherein preheating the fuel gas includes preheating the fuel gas to a temperature of at least 500° C.

24 . The method of claim 21 wherein the fuel gas is received at a rate between 0.018 and 6105 standard cubic feet per minute.

25 . The method of claim 21 wherein the fuel gas is received at a rate between 10 and 3,350,000 million British thermal units per year.

Assignments (5)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 21, 2026
From: MODERN HYDROGEN, INC.
To: MODERN HYDROGEN (ASSIGNMENT FOR THE BENEFIT OF CREDITORS), LLC
Reel/Frame 075742/0046 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 21, 2026
From: MODERN HYDROGEN (ASSIGNMENT FOR THE BENEFIT OF CREDITORS), LLC
To: SHELL USA INC.
Reel/Frame 075742/0092 →
CHANGE OF NAME Recorded May 6, 2025
From: MODERN ELECTRON, INC.
To: MODERN HYDROGEN, INC.
Reel/Frame 071189/0342 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 26, 2025
From: ASHTON, JUSTIN B.; GROENEWALD, ROELOF E.; HUGHES, KEVIN J.; KOKONASKI, WILLIAM; MANKIN, MAX N.; PAN, TONY S.; WOOD, LOWELL L.; LORR, JOHN J.; GOYAL, AMIT; RADAELLI, GUIDO; SESHADRI, VIKRAM
To: MODERN HYDROGEN, INC.
Reel/Frame 070340/0375 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 26, 2025
From: KANNAN, ARVIND
To: MODERN ELECTRON, LLC
Reel/Frame 070343/0783 →
Continuity (4)
Continuation 17337326 · Jun 2, 2021
Provisional Application 63113931 · Nov 15, 2020
Provisional Application 63034385 · Jun 3, 2020
Related Publication 20240217815A1 · Jul 4, 2024
References Cited (42)
US 3460524A · Lazaridis · 1969 [cited by applicant]
US 4797091A · Neumann · 1989 [cited by applicant]
US 4884555A · Huang · 1989 [cited by applicant]
US 5101633A · Keller et al. · 1992 [cited by applicant]
US 5407347A · Bortz · 1995 [cited by applicant]
US 5470224A · Bortz · 1995 [cited by applicant]
US 5589599A · Mcmullen et al. · 1996 [cited by applicant]
US 5797356A · Khizh · 1998 [cited by applicant]
US 6036480A · Hughes et al. · 2000 [cited by applicant]
US 7007477B2 · Widener · 2006 [cited by applicant]
US 7537623B2 · Etievant et al. · 2009 [cited by applicant]
US 8312722B2 · York et al. · 2012 [cited by applicant]
US 9212058B2 · De Graffenried, Sr. · 2015 [cited by applicant]
US 9406957B2 · Jackson · 2016 [cited by applicant]
US 10787362B2 · De Graffenried, Sr. · 2020 [cited by applicant]
US 11826749B2 · Pannala et al. · 2023 [cited by applicant]
US 11897768B2 · Ashton et al. · 2024 [cited by applicant]
US 20020007594A1 · Muradov · 2002 [cited by applicant]
US 20080147241A1 · Tsangaris et al. · 2008 [cited by applicant]
US 20100035103A1 · Jackson · 2010 [cited by applicant]
US 20100043291A1 · Ljunggren · 2010 [cited by applicant]
US 20100175639A1 · Al-Dawood et al. · 2010 [cited by applicant]
US 20130213256A1 · McAlister · 2013 [cited by applicant]
US 20170159930A1 · Lin et al. · 2017 [cited by applicant]
US 20200294779A1 · Ashton et al. · 2020 [cited by applicant]
US 20210380407A1 · Goyal et al. · 2021 [cited by applicant]
US 20220315424A1 · Ashton et al. · 2022 [cited by applicant]
US 20220387952A1 · Groenewald et al. · 2022 [cited by applicant]
US 20230003381A1 · Mueller-Hagedorn et al. · 2023 [cited by applicant]
CN 106854127A · 2017 [cited by applicant]
CN 209508163U · 2019 [cited by applicant]
CN 112390227A · 2021 [cited by applicant]
JP 2002543033A · 2002 [cited by applicant]
JP 2019200996A · 2019 [cited by applicant]
WO WO9958614 · 1999 [cited by applicant]
WO 02057395A1 · 2002 [cited by applicant]
WO WO2010127961 · 2010 [cited by applicant]
WO WO2019226416 · 2019 [cited by applicant]
WO WO2021102521 · 2021 [cited by applicant]
WO WO2021247768 · 2021 [cited by applicant]
International Search Report and Written Opinion for International Patent Application No. PCT/US21/35541, Applicant: Modern Electron, Inc., mailed Sep. 17, 2021, 13 pages. [cited by applicant]
Lohse-Busch et al., “Technology Assessment of a Fuel Cell Vehicle: 2017 Toyota Mirai”, Argonne National Laboratory, Report # ANL/ESD-18/12, Jun. 2018, pp. 80. [cited by applicant]