Polycyclic aromatic molecules, pitch and graphite, having low impurities and large crystalline structure, and products made therefrom
High-purity polycyclic aromatic hydrocarbons (PAHs) and the byproducts thereof, and methods for producing such products are disclosed. The PAHs may comprise an aromaticity index of about 0.65 to about 0.80. The PAHs may have quinoline insolubles and sulfur impurities of less than about 0.1 wt. % each. A tar or pitch comprising the high-purity PAHs and a method of producing such tar or pitch are disclosed. A synthetic graphite comprising high-purity PAHs is also disclosed. A method of making carbon pellets from high-purity PAHs is also disclosed.
1 . High-purity polycyclic aromatic hydrocarbons comprising:
an aromaticity index of about 0.65 to about 0.80;
less than about 0.1 wt. % quinoline insolubles; and
less than about 0.1 wt. % sulfur.
2 . The high-purity polycyclic aromatic hydrocarbons of claim 1 , comprising about 0.05 wt. % to 0.00 wt. % quinoline insolubles.
3 . The high-purity polycyclic aromatic hydrocarbons of claim 1 , comprising about 0.05 wt. % to 0.00 wt. % sulfur.
4 . The high-purity polycyclic aromatic hydrocarbons of claim 1 , having an aromaticity index of about 0.70 to about 0.74.
5 . The high-purity polycyclic aromatic hydrocarbons of claim 1 , wherein the high-purity polycyclic aromatic hydrocarbons contain less than 5% by volume of single-ring phenols.
6 . The high-purity polycyclic aromatic hydrocarbons of claim 1 , wherein the high-purity polycyclic aromatic hydrocarbons contain over 80% by volume of a mixture of 2-ring, 3-ring and 4 or more-ring aromatic hydrocarbons.
7 . The high-purity polycyclic aromatic hydrocarbons of claim 1 , wherein the high-purity polycyclic aromatic hydrocarbons are co-generated with solid carbon.
8 . The high-purity polycyclic aromatic hydrocarbons of claim 7 , wherein the co-generated solid carbon has a surface area from about 7 m 2 /g to about 520 m 2 /g.
9 . A tar or pitch comprising the high-purity polycyclic aromatic hydrocarbons of claim 1 .
10 . A synthetic graphite comprising the high-purity polycyclic aromatic hydrocarbons of claim 1 .
11 . The synthetic graphite of claim 10 , wherein the graphite comprises crystals of carbonized and graphitized high-purity polycyclic aromatic hydrocarbons having a lateral dimension (La) between about 400 Å and about 1500 Å and/or having a stacking height (Lc) between about 50 Å and about 2600 Å.
12 . A method of making carbon pellets comprising:
providing the high-purity polycyclic aromatic hydrocarbons of claim 1 and solid carbon;
applying pressure to a mixture of the high-purity polycyclic aromatic hydrocarbons and solid carbon to press the mixture into compressed pellets; and
heating the compressed pellets at a temperature of about 600° C. to about 1000° C. to produce the carbon pellets.
13 . The method of claim 12 , wherein providing the high-purity polycyclic aromatic hydrocarbons and the solid carbon comprises co-generating the high-purity polycyclic aromatic hydrocarbons and the solid carbon in a reaction zone from a feed stream.
14 . The method of making carbon pellets of claim 12 , wherein the solid carbon has a surface area from about 7 m 2 /g to about 520 m 2 /g.
15 . The method of making carbon pellets of claim 12 , wherein up to about 30 MPa of pressure is applied to the mixture.
16 . The method of making carbon pellets of claim 12 , wherein the heating comprises heating the compressed pellets for about 15 minutes to about 60 minutes.
17 . A method of making a pitch from high-purity polycyclic aromatic hydrocarbons comprising:
making carbon pellets according to claim 12 ;
heating the carbon pellets to a temperature of about 500° C. to about 1200° C.; and
using vacuum distillation to remove desorbed polycyclic aromatic hydrocarbons, leaving the pitch.
18 . The method of claim 17 , wherein heating the carbon pellets comprises using a microwave plasma and a gas to heat the carbon pellets.
19 . The method of claim 17 further comprising, after the vacuum distillation, applying heat of about 200° C. to about 300° C. to the pitch to remove low boiling point polycyclic aromatic hydrocarbons.
20 . A method of generating high-purity polycyclic aromatic hydrocarbons according to claim 1 comprising:
concurrently processing methane gas and coal within a microwave plasma reactor to generate polycyclic aromatic hydrocarbons, wherein in situ methylation of the coal occurs within a reaction zone of the microwave plasma reactor.
21 . The method of claim 20 , wherein the methane gas is injected tangentially to a plasma in the reaction zone.
22 . A method of making carbon pellets comprising:
providing high-purity polycyclic aromatic hydrocarbons and solid carbon, wherein the high-purity polycyclic aromatic hydrocarbons comprise:
an aromaticity index of about 0.10 to about 0.30,
less than about 0.1 wt. % quinoline insoluble, and
less than about 0.1 wt. % sulfur;
applying pressure to a mixture of the high-purity polycyclic aromatic hydrocarbons and the solid carbon to press the mixture into compressed pellets; and
heating the compressed pellets at a temperature of about 600° C. to about 1000° C. to produce the carbon pellets.
23 . The method of claim 22 , wherein providing the high-purity polycyclic aromatic hydrocarbons and the solid carbon comprises co-generating the high-purity polycyclic aromatic hydrocarbons and the solid carbon in a reaction zone from a feed stream.
24 . The method of making carbon pellets of claim 22 , wherein the solid carbon has a surface area from about 7 m 2 /g to about 520 m 2 /g.
25 . The method of making carbon pellets of claim 22 , wherein about 1.5 to about 150 kPa of pressure is applied to the mixture.
26 . The method of making carbon pellets of claim 22 , wherein the heating comprises heating the compressed pellets for about 15 minutes to about 60 minutes.
27 . A method of making a pitch from high-purity polycyclic aromatic hydrocarbons comprising:
making carbon pellets according to claim 22 ;
heating the carbon pellets to a temperature of about 500° C. to about 1200° C.; and
using vacuum distillation to remove desorbed polycyclic aromatic hydrocarbons, leaving the pitch.
28 . The method of claim 27 , wherein heating the carbon pellets comprises using a microwave plasma and a gas to heat the carbon pellets.
29 . The method of claim 27 , further comprising, after the vacuum distillation, applying heat of about 200° C. to about 300° C. to the tar or pitch to remove low boiling point polycyclic aromatic hydrocarbons.