Lubricating oil compositions for electric vehicles
A lubricating oil composition for an automotive vehicle with an electric motor and/or generator is provided. The lubricating oil composition includes: a. a major amount of an oil of lubricating viscosity having a kinematic viscosity at 100° C. in a range of about 1.5 mm 2 /s to about 20 mm 2 /s; b. an sulfur-based additive including a thiadiazole and a sulfurized polyolefin of formula (I): where R 1 is hydrogen or methyl, and R 2 is a C8-C40 hydrocarbyl group, the sulfur-based additive providing sulfur to the lubricating oil composition in an amount of 0.01 wt. % to 0.2 wt. %, based on the total weight of the lubricating oil composition; c. a phosphorus compound; and d. an ashless polyisobutenyl succinimide-based dispersant containing boron. The lubricating oil composition provides exceptional volume resistivity, detergency, thermal and oxidative stability, wear resistance, and corrosion resistance at high temperatures.
1 . A lubricating oil composition for an automotive vehicle with an electric motor and/or generator, comprising:
a. a major amount of an oil of lubricating viscosity having a kinematic viscosity at 100° C. in a range of about 1.5 mm 2 /s to about 20 mm 2 /s;
b. a thiadiazole and a sulfurized polyolefin of formula (I):
where R 1 is hydrogen or methyl, and R 2 is a C8-C40 hydrocarbyl group, the sulfur-based additive providing sulfur to the lubricating oil composition in an amount of 0.01 wt. % to 0.2 wt. %, based on the total weight of the lubricating oil composition;
c. a phosphorus compound; and
d. an ashless polyisobutenyl succinimide-based dispersant containing boron present in an amount of 0.3 wt. % to 2.0 wt. % based on the total weight of the lubricating oil composition.
2 . The lubricating oil composition of claim 1 , wherein the sulfurized polyolefin of formula (I) provides the lubricating oil composition with a sulfur content of 0.01 wt. % to 0.2 wt. %, based on the total weight of the lubricating oil composition.
3 . The lubricating oil composition of claim 1 , wherein the thiadiazole provides the lubricating oil composition with a sulfur content of 0.005 wt. % to 0.2 wt. %, based on the total weight of the lubricating oil composition.
4 . The lubricating oil composition of claim 1 including sulfur in a total amount of 0.01 wt. % to 0.2 wt. %, based on the total weight of the lubricating oil composition.
5 . The lubricating oil composition of claim 1 , wherein the lubricating oil composition contains less than 50 ppm of metals and has a volume resistivity greater than 1.0×10 9 Ω·cm at 80° C.
6 . The lubricating oil composition of claim 1 , wherein the phosphorus compound includes at least one of a phosphate, a phosphate ester, an amine salt of a phosphate ester, a phosphonate a phosphonate ester, a phosphite, and a phosphite ester.
7 . The lubricating oil composition of claim 1 including phosphorus in a total amount of 0.005 wt. % to 0.2 wt. %, based on the total weight of the lubricating oil composition.
8 . The lubricating oil composition of claim 1 including a triazole-containing corrosion inhibitor.
9 . The lubricating oil composition of claim 1 , wherein the oil of lubricating viscosity includes a Group II base stock and a Group III base stock.
10 . The lubricating oil composition of claim 1 , wherein the sulfurized polyolefin of formula I is a sulfurized polyisobutylene oligomer of formula II:
wherein R1 is hydrogen or methyl, m is an integer from 1 to 9, and n is 0 or 1.
11 . A method of reducing corrosion and improving wear protection in the transmission system of an automotive vehicle with an electric motor and/or generator by lubricating the transmission system with a lubricating oil composition, the lubricating oil composition comprising:
a. a major amount of an oil of lubricating viscosity having a kinematic viscosity at 100° C. in a range of about 1.5 mm 2 /s to about 20 mm 2 /s;
b. a thiadiazole and a sulfurized polyolefin of formula (I):
where R1 is hydrogen or methyl, and R2 is a C8-C40 hydrocarbyl group, the sulfur-based additive providing sulfur to the lubricating oil composition in an amount of 0.01 wt. % to 0.2 wt. %, based on the total weight of the lubricating oil composition;
c. a phosphorus compound; and
d. an ashless polyisobutenyl succinimide-based dispersant containing boron present in an amount of 0.3 wt. % to 2.0 wt. % based on the total weight of the lubricating oil composition.
12 . The method of claim 11 , wherein the sulfur-based additive consists of the thiadiazole and the sulfurized polyolefin of formula (I).
13 . The method of claim 11 , wherein the sulfurized polyolefin of formula (I) provides the lubricating oil composition with a sulfur content of 0.01 wt. % to 0.2 wt. %, based on the total weight of the lubricating oil composition.
14 . The method of claim 11 , wherein the thiadiazole provides the lubricating oil composition with a sulfur content of 0.005 wt. % to 0.2 wt. %, based on the total weight of the lubricating oil composition.
15 . The method of claim 11 , wherein the lubricating oil composition includes sulfur in a total amount of 0.01 wt. % to 0.2 wt. %, based on the total weight of the lubricating oil composition.
16 . The method of claim 11 , wherein the lubricating oil composition contains less than 50 ppm of metals and has a volume resistivity greater than 1.0×10 9 Ω·cm at 80° C.
17 . The method of claim 11 , wherein the phosphorus compound includes at least one of a phosphate, a phosphate ester, an amine salt of a phosphate ester, a phosphonate a phosphonate ester, a phosphite, and a phosphite ester.
18 . The method of claim 11 , wherein the lubricating oil composition includes phosphorus in a total amount of 0.005 wt. % to 0.2 wt. %, based on the total weight of the lubricating oil composition.
19 . The method of claim 11 , wherein the lubricating oil composition includes a corrosion inhibitor containing nitrogen, and the oil of lubricating viscosity includes a Group II base stock and a Group III base stock.
20 . The method of claim 11 , wherein the lubricating oil composition includes a corrosion inhibitor comprising a tolyltriazole derivative, and wherein the oil of lubricating viscosity includes a Group II base stock and a Group III base stock.
21 . The method of claim 11 , wherein the lubricating oil composition comprises a corrosion inhibitor comprising a tolyltriazole derivative with an alkyl amine moiety, and wherein the oil of lubricating viscosity includes a Group II base stock and a Group III base stocks.