Granted Patent B2

US 12,529,148 · App. 18/376,439 · Granted Jan 20, 2026

Inventors: Juliano Avelar Araújo (Coimbra, PT); Rafael Rabello (Murtede, PT)

Assignee: Mahle International GmbH

C23C28/325F16J9/26

Abstract

Claims (64)

1 . A sliding member, comprising:

a metallic base;

at least one intermediate bonding layer composed of at least one metal and disposed on the metallic base such that the at least one intermediate bonding layer covers at least part of a surface of the metallic base; and

a multilayer protective coating disposed on the intermediate bonding layer;

wherein the multilayer protective coating includes a plurality of first layers and a plurality of second layers arranged in an alternating manner;

wherein the multilayer protective coating further includes a plurality of periodicity layer groups, each periodicity layer group of the plurality of periodicity layer groups defined by a first layer of the plurality of first layers and an adjacent second layer of the plurality of second layers;

wherein each of the plurality of first layers and each of the plurality of second layers are composed of Al-containing chromium nitride;

wherein the plurality of first layers each have a higher Al content than each of the plurality of second layers;

wherein a thickness ratio of the first layer to the second layer in each periodicity layer group of the plurality of periodicity layer groups is from 1 to 10;

wherein the multilayer protective coating has a total Al content of 15 to 40 atom-%; and

wherein:

a total thickness of the at least one intermediate bonding layer and the multilayer protective coating is from 6 μm to 70 μm;

a hardness of the multilayer protective coating is from 1600 to 2600 HV; and/or

the multilayer protective coating has a porosity lower than 6%.

2 . The sliding member according to claim 1 , wherein the metallic base is composed of at least one of:

steel having 10 to 17 mass-% Cr;

carbon steel; and

cast iron.

3 . The sliding member according to claim 2 , wherein the metallic base is nitrided.

4 . The sliding member according to claim 1 , wherein the at least one intermediate bonding layer includes at least one of Cr, Ni, and Co.

5 . The sliding member according to claim 1 , wherein the thickness ratio of the first layer to the second layer in each periodicity layer group of the plurality of periodicity layer groups is from 1.3 to 10.

6 . The sliding member according to claim 1 , wherein:

the plurality of first layers include 20 to 40 atom-% of Al; and

the plurality of second layers include 10 to 25 atom-% of Al.

7 . The sliding member according to claim 1 , wherein each periodicity layer group of the plurality of periodicity layer groups has a thickness of less than 20 nm.

8 . The sliding member according to claim 1 , wherein the hardness of the multilayer protective coating is from 1900 to 2000 HV.

9 . The sliding member according to claim 1 , wherein an internal compressive stress of the multilayer protective coating is from 1000 to 2500 MPa.

10 . The sliding member according to claim 1 , wherein the porosity of the multilayer protective coating is lower than 3%.

11 . The sliding member according to claim 1 , wherein the multilayer protective coating is a cathodic arc deposited layer.

12 . An internal combustion engine, comprising the sliding member according to claim 1 .

13 . The internal combustion engine according to claim 12 , wherein the sliding member is one of a piston ring, a tappet, a valve, and a cam.

14 . A compressor, comprising the sliding member according to claim 1 .

15 . The compressor according to claim 14 , wherein the sliding member is one of a piston ring, a tappet, a valve, and a cam.

16 . The sliding member according to claim 1 , wherein:

the hardness of the multilayer protective coating is 1900 to 2000 HV;

an internal compressive stress of the multilayer protective coating is 1400 to 2000 MPa; and

the porosity of the multilayer protective coating is lower than 3%.

17 . The sliding member according to claim 1 , wherein:

the total thickness of the at least one intermediate bonding layer and the multilayer protective coating is from 10 μm to 50 μm;

each periodicity layer group of the plurality of periodicity layer groups has a thickness of 5 to 15 nm; and

the thickness ratio of the first layer to the second layer in each periodicity layer group of the plurality of periodicity layer groups is from 1.7 to 5.

18 . A sliding member, comprising:

a metallic base;

at least one intermediate bonding layer composed of at least one metal and disposed on the metallic base; and

a multilayer protective coating disposed on the intermediate bonding layer, the multilayer protective coating including a plurality of first layers and a plurality of second layers arranged in an alternating manner;

the multilayer protective coating further including a plurality of periodicity layer groups each defined by a first layer of the plurality of first layers and an adjacent second layer of the plurality of second layers;

wherein each of the plurality of first layers and each of the plurality of second layers are composed of Al-containing chromium nitride;

wherein, in each periodicity layer group of the plurality of periodicity layer groups, a thickness ratio of the first layer to the second layer is from 1.5 to 5;

wherein the plurality of first layers each include 27 to 32 atom-% of Al;

wherein the plurality of second layers each include 18 to 20 atom-% of Al;

wherein the multilayer protective coating has a total Al content of 15 to 40 atom-%; and

wherein a total thickness of the at least one intermediate bonding layer and the multilayer protective coating is from 10 μm to 50 μm.

19 . A sliding member, comprising:

a metallic base;

at least one intermediate bonding layer disposed on the metallic base, the at least one intermediate bonding layer composed of at least one metal; and

a multilayer protective coating disposed on the intermediate bonding layer, the multilayer protective coating including a plurality of first layers and a plurality of second layers arranged in an alternating manner;

the multilayer protective coating further including a plurality of periodicity layer groups each defined by a first layer of the plurality of first layers and an adjacent second layer of the plurality of second layers;

wherein each of the plurality of first layers and each of the plurality of second layers are composed of Al-containing chromium nitride;

wherein, in at least one periodicity layer group of the plurality of periodicity layer groups, i) the first layer has a higher Al content than the second layer and ii) a thickness ratio of the first layer to the second layer is from 1.5 to 5;

wherein the multilayer protective coating has a total Al content of 15 to 40 atom-%; and

wherein:

a total thickness of the at least one intermediate bonding layer and the multilayer protective coating is from 6 μm to 70 μm;

a hardness of the multilayer protective coating is from 1600 to 2600 HV; and/or

the multilayer protective coating has a porosity lower than 6%.

Assignments (1)

Priority Claims (1)

Continuity (1)

References Cited (15)