Spray-applied polyurethane insulation material for tunnels in cold regions, its application, and its construction method
The present invention provides a spray-applied polyurethane insulation material for tunnels in cold regions, its application, and its construction method. The spray-applied polyurethane insulation material for tunnels in cold regions is composed of raw materials with a mass ratio of 0.8-1.2 of material A and material B. By mass parts, material A includes 90-100 parts of polyether polyol, 90-100 parts of polyester polyol, 5-10 parts of chain extender, 1-4 parts of catalyst, 10-20 parts of flame retardant, 0.5-3 parts of water, and 1-3 parts of surfactant. The B component is diphenylmethane diisocyanate. The flame retardant is composed of flame retardant A and flame retardant B in a mass ratio of 10:1-2.5. The spray-applied polyurethane insulation material of the present invention is used to construct tunnel structures in cold regions, providing good flame retardant and insulation effects.
1 . A method for construction of tunnels in cold regions using a spray-applied polyurethane insulation material, wherein the method comprises:
forming a tunnel structure comprising, from outside to inside, a tunnel rock wall, a primary shotcrete layer, a geotextile layer, a self-adhesive waterproof board layer, a spray-applied polyurethane foam layer, and a secondary lining concrete layer, wherein the spray-applied polyurethane foam layer is formed by spraying the spray-applied polyurethane insulation material on a surface of the self-adhesive waterproof board layer,
wherein the spray-applied polyurethane insulation material
comprises a material A and a material B in a mass ratio of 0.8-1.2;
by mass parts, the material A includes 90-100 parts of polyether polyol, 90-100 parts of polyester polyol, 5-10 parts of chain extender, 1-4 parts of catalyst, 10-20 parts of flame retardant, 0.5-3 parts of water, and 1-3 parts of surfactant;
the material B is diphenylmethane diisocyanate;
the flame retardant comprises a flame retardant A and a flame retardant B in a mass ratio of 10:1-2.5;
the molecular structure of the flame retardant A is:
wherein the flame retardant B is prepared by
mixing DOPO, methacryloxypropyltrimethoxysilane, vinyltri(β-methoxyethoxy) silane, and triethylamine in a mass ratio of 5-6:1.8-2.5:1.5-2:0.1-0.15 as raw materials for standby;
placing the raw materials in a supercritical CO 2 reactor and sealing, then introducing CO 2 gas, with the reactor pressure at 15-16.5 MPa, adjusting the reactor temperature to 40-48° C., reacting for 4-7 hours to obtain the graft product of silane and DOPO; and
mixing TiO 2 and the graft product of silane and DOPO in a mass ratio of 1.5-2.2:1, placing in a supercritical CO 2 reactor and sealing, then introducing CO 2 gas, with the reaction system temperature at 45-55° C., and the reaction system pressure at 17-19 MPa, reacting for 3-5 hours, washing the reaction product with anhydrous ethanol, and then drying to obtain the flame retardant B.
2 . The method for construction of tunnels in cold regions according to claim 1 , wherein the thickness of the primary shotcrete layer in the tunnel structure is 100-280 mm; the thickness of the self-adhesive waterproof board layer is 1-1.5 mm; the thickness of the spray-applied polyurethane foam layer is 50-70 mm; and the thickness of the secondary lining concrete layer is 400-600 mm.
3 . The method for construction of tunnels in cold regions according to claim 1 , wherein forming the tunnel structure comprises:
setting a grid steel frame on the tunnel rock wall, spraying concrete to embed the grid steel frame in the shotcrete, forming an integral structure with the concrete, and forming the primary shotcrete layer;
fixing the geotextile to the primary shotcrete layer through steel nails in a penetrating manner, forming the geotextile layer; overlapping adjacent geotextile layers, and bonding the overlapping parts through high-temperature hot melt with a hot air gun;
adhering the self-adhesive waterproof board to the surface of the geotextile; bonding the self-adhesive waterproof board layer to the geotextile layer through several self-adhesive tapes, and fixing the bonding parts with expansion screws, overlapping adjacent self-adhesive waterproof board layers; welding the overlapping parts with double seam hot melt welding;
spraying the spray-applied polyurethane insulation material for tunnels in cold regions on the surface of the self-adhesive waterproof board, forming the spray-applied polyurethane foam layer; and
pouring lining concrete on the surface of the spray-applied polyurethane foam layer, forming the secondary lining concrete layer.
4 . The method for construction of tunnels in cold regions according to claim 3 , wherein spraying the spray-applied polyurethane insulation material for tunnels in cold regions includes the following steps: construction is carried out when the on-site temperature is higher than −10° C.; the foaming time is about 1-2 s, and curing is 25-40 s; for the first two layers, each layer is sprayed with a thickness of 3-5 mm, after the second layer, each layer is sprayed with 20-30 mm; the spraying speed is 1-2 kg/min; the spray gun moving speed is 0.5 m/s; after the first and second layers are sprayed, a layer of polyurethane waterproof coating is sprayed on the surface of the polyurethane foam.
5 . The method for construction of tunnels in cold regions according to claim 1 , wherein the polyether polyol includes a polyether polyol a, a polyether polyol b, and a polyether polyol c in a mass ratio of 1:1:0.8-1.2;
wherein the polyether polyol a is prepared using sucrose and sorbitol as initiators, with a functionality of 2-4, viscosity of 2500-3000 mPa·s, and hydroxyl value of 310-360 mgKOH/g;
wherein the polyether polyol b is prepared using phenol as an initiator through a Mannich reaction, with a functionality of 4-5, viscosity of 1500-2000 mPa·s, and hydroxyl value of 270-300 mgKOH/g; and
wherein the polyether polyol c is prepared using sucrose and diethylene glycol as initiators, with a functionality of 2-4, viscosity of 2500-3000 mPa·s, and hydroxyl value of 310-360 mgKOH/g.
6 . The method for construction of tunnels in cold regions according to claim 1 , wherein the polyester polyol includes a polyester polyol a and a polyester polyol b in a mass ratio of 1:0.9-1.3;
wherein the polyester polyol a is a polycondensation product obtained by reacting polyol and dicarboxylic acid at 140-200° C., with a functionality of 2, viscosity of 9000-15000 mPa·s, and hydroxyl value of 500-600 mgKOH/g; the polyol is selected from one or more of diethylene glycol, trimethylolpropane, pentaerythritol, and 1,4-butanediol; the dicarboxylic acid is phthalic anhydride; and
wherein the polyester polyol b is a carbon dioxide-based polyol, with a viscosity of 2000-3000 mPa·s, hydroxyl value of 300-400 mgKOH/g, and functionality of 2.
7 . The method for construction of tunnels in cold regions according to claim 1 , wherein the surfactant is an organosilicon surfactant AK 8806 and AK 8810 in a mass ratio of 1:0.5-0.8.
8 . The method for construction of tunnels in cold regions according to claim 1 , wherein the chain extender is 1,4-butanediol and pentaerythritol in a mass ratio of 1:0.3-0.5.
9 . The method for construction of tunnels in cold regions according to claim 1 , wherein the catalyst is selected from one or more of stannous octoate, dibutyltin dilaurate, triethylenediamine, triethanolamine, rhodium chloride, and strontium chloride.