Method for preparing perfluorodialkyl ether and apparatus for preparing perfluorodialkyl ether
The present invention relates to a method for preparing a perfluorodialkyl ether, comprising the steps of: (A) preparing a perfluorodialkyl ether from a compound represented by Formula 1 in the presence of a metal fluoride; and (B) isolating the perfluorodialkyl ether, and to an apparatus for preparing perfluorodialkyl ether, comprising: a reactor for preparing a perfluorodialkyl ether from a compound represented by Formula 1 in the presence of a metal fluoride; a reactant supplier for introducing the compound represented by Formula 1 into the reactor; and a discharge unit for discharging the perfluorodialkyl ether from the upper portion of the reactor.
1 . A method for preparing a perfluorodialkyl ether comprising the steps of:
(A) preparing a perfluorodialkyl ether from a compound represented by Formula 1 below in a presence of a metal fluoride as a Lewis acid; and
(B) isolating the perfluorodialkyl ether:
in Formula 1, n is an integer from 1 to 3.
2 . The method of claim 1 , wherein the step (B) is performed after the step (A) is finished.
3 . The method of claim 2 , wherein a cycle including the steps (A) and (B) is repeatedly performed a plurality of times,
the method further comprises, between the respective cycles, the step of additionally introducing a compound represented by Formula 1 below:
in Formula 1, n is an integer from 1 to 3.
4 . The method of claim 1 , wherein in the step (A), the compound represented by Formula 1 is continuously supplied from an outside,
the perfluorodialkyl ether isolated in the step (B) is continuously discharged to the outside.
5 . The method of claim 1 , wherein the step (B) is to isolate the perfluorodialkyl ether by gas-liquid isolation.
6 . The method of claim 1 , wherein the perfluorodialkyl ether is represented by Formula 2 below:
C n F 2n+1 —O—CF 2 —CF 3 [Formula 2]
in Formula 2, n is an integer from 1 to 3.
7 . The method of claim 1 , wherein the metal fluoride includes at least one selected from the group consisting of antimony pentafluoride, aluminum trifluoride, cobalt trifluoride and a combination thereof.
8 . The method of claim 2 , wherein in the step (A), the compound represented by Formula 1 and the metal fluoride are mixed in a molar ratio of 1:0.1 to 1:10.
9 . The method of claim 4 , wherein in the step (A), the compound represented by Formula 1 is continuously supplied from the outside at a flow rate of 0.5 parts by weight/min to 5 parts by weight/min based on 100 parts by weight of the metal fluoride.
10 . The method of claim 2 , wherein the step (A) is performed at −20° C. to 10° C.
11 . The method of claim 4 , wherein the step (A) is performed at −15° C. to 10° C.
12 . The method of claim 4 , wherein in the steps (A) and (B), an internal pressure is controlled to 0.2 bar or more as a gauge pressure.