Method for synthesizing a hydrogen-containing compound
The invention relates to a method for synthesising a hydrogen-containing compound, wherein a synthesis gas stream ( 1 ) comprising hydrogen and carbon oxides is fed to a methanol reactor arrangement ( 2 ) for partial conversion into methanol, wherein a methanol residual gas stream ( 3 ) is obtained from the methanol reactor arrangement ( 2 ), at least part of said methanol residual gas stream ( 3 ) being fed to a CO2 remover ( 4 ) from which a synthesis recycle stream ( 5 ) and a CO2 product stream ( 6 ) are obtained, said CO2 product stream ( 6 ) having a higher molar carbon dioxide content than the methanol residual gas stream ( 3 ), and wherein part of the synthesis recycle stream ( 5 ) is fed to the methanol reactor arrangement ( 2 ). The method according to the invention is characterised in that part of the synthesis recycle stream ( 5 ) is fed to a hydrogen separator ( 7 ) from which a separation stream ( 8 ) is obtained which has a higher molar hydrogen content than the synthesis recycle stream ( 5 ). The invention also relates to a corresponding system for synthesising a hydrogen-containing compound.
1 . A method for synthesizing a hydrogen-containing compound by,
feeding a synthesis gas stream ( 1 ) comprising hydrogen and carbon oxides to a methanol reactor arrangement ( 2 ) for partial conversion into methanol;
obtaining a methanol residual gas stream ( 3 ) from the methanol reactor arrangement ( 2 ), feeding at least part of the methanol residual gas stream ( 3 ) to a CO2 remover ( 4 ) to obtain a synthesis recycle stream ( 5 ) and a CO2 product stream ( 6 ), wherein the CO2 product stream ( 6 ) has a higher molar carbon dioxide proportion than the methanol residual gas stream ( 3 );
feeding a part ( 5 a ) of the synthesis recycle stream ( 5 ) to the methanol reactor arrangement ( 2 ), wherein a part ( 5 b ) of the synthesis recycle stream ( 5 ) is fed to a hydrogen separator ( 7 ) to obtain a separation stream ( 8 ), wherein the separation stream ( 8 ) has a higher molar hydrogen proportion than the synthesis recycle stream ( 5 );
obtaining a reform recycle stream ( 14 ) from the hydrogen separator ( 7 ) and feeding the reform recycle stream ( 14 ) to a synthesis gas reactor arrangement ( 9 ) for producing the synthesis gas stream ( 1 ), wherein the reform recycle stream ( 14 ) has a higher molar methane proportion than the synthesis recycle stream ( 5 ); and
obtaining a further reform recycle stream ( 15 ) from the CO2 remover ( 4 ) and feeding the further reform recycle stream ( 15 ) to the synthesis gas reactor arrangement ( 9 ).
2 . The method according to claim 1 , wherein the synthesis gas stream ( 1 ) is produced from a carbon-containing energy carrier stream ( 10 ) in the synthesis gas reactor arrangement ( 9 ).
3 . The method according to claim 2 , wherein the synthesis gas stream ( 1 ) is produced from the carbon-containing energy carrier stream ( 10 ) in the synthesis gas reactor arrangement ( 9 ) by autothermal reforming.
4 . The method according to claim 1 , wherein before the synthesis gas stream ( 1 ) is fed to the methanol reactor arrangement ( 2 ), at least part of the synthesis gas stream is fed to a shift conversion ( 38 ) for a water-gas shift reaction.
5 . The method according to claim 1 , wherein the methanol reactor arrangement ( 2 ) comprises a methanol separation device ( 18 ) for producing the methanol residual gas stream ( 3 ) and a crude methanol stream ( 19 ) from a reactor product stream ( 20 ).
6 . The method according to claim 1 , wherein the hydrogen separator ( 7 ) comprises a membrane device for separating hydrogen having a low-pressure side.
7 . The method according to claim 6 , wherein a nitrogen-containing purge gas stream is fed to the low-pressure side of the membrane device for diluting the hydrogen in the separation stream ( 8 ).
8 . The method according to claim 1 , wherein the CO 2 remover ( 4 ) comprises a scrubbing arrangement ( 26 ) for scrubbing CO 2 from the methanol residual gas stream ( 3 ).
9 . The method according to claim 8 , wherein the scrubbing arrangement ( 26 ) scrubs the CO 2 out of the methanol residual gas stream ( 3 ) by chemical scrubbing and/or by physical scrubbing.
10 . The method according to claim 9 , wherein the scrubbing arrangement ( 26 ) comprises a cold circuit ( 27 a ) having a scrubbing medium with methanol and a regeneration device ( 28 ) configured to yield CO 2 from the scrubbing medium.
11 . The method according to claim 8 , wherein the CO 2 remover ( 4 ) comprises a compressor arrangement ( 27 ) for increasing the pressure of the scrubbed CO 2 , wherein the compressor arrangement ( 27 ) comprises a plurality of compressor stages ( 32 ) connected in series.
12 . The method according to claim 11 , wherein the compressor arrangement ( 27 ) is fed with a plurality of partial streams of scrubbed CO2 between respectively different compressor stages ( 32 ) of the plurality for increasing the pressure.
13 . A system for synthesizing a hydrogen-containing compound by the method of claim 1 , the system comprising:
the methanol reactor arrangement ( 2 ), to which is fed the synthesis gas stream ( 1 ) comprising hydrogen and carbon oxides for partial conversion into methanol and for obtaining the methanol residual gas stream ( 3 ),
the CO2 remover ( 4 ), to which at least part of the methanol residual gas stream ( 3 ) is fed for obtaining the synthesis recycle stream ( 5 ) and the CO2 product stream ( 6 ), said CO2 product stream ( 6 ) having a higher molar carbon dioxide proportion than the methanol residual gas stream ( 3 ) and part of the synthesis recycle stream ( 5 ) being fed to the methanol reactor arrangement ( 2 ),
the hydrogen separator ( 7 ) to which at least part of the synthesis recycle stream ( 5 ) is fed to obtain the separation stream ( 8 ), wherein the separation stream ( 8 ) has a higher molar hydrogen proportion than the synthesis recycle stream ( 5 ); and
the synthesis gas reactor arrangement ( 9 ) for producing the synthesis gas stream ( 1 ).
14 . The method according to claim 1 , wherein the separation stream ( 8 ) is fed to a fired heating device ( 16 ) for combustion.
15 . The method according to claim 6 , wherein the separation stream ( 8 ) is obtained from a low-pressure side of the membrane device and a reform recycle stream ( 14 ) is obtained from a high-pressure side of the membrane device.
16 . The method according to claim 15 , wherein the separation stream ( 8 ) is obtained from the membrane device at a lower pressure than the reform recycle stream ( 14 ).
17 . The method according to claim 1 , wherein the hydrogen separator ( 7 ) is arranged downstream from the CO 2 remover ( 4 ).