Positive active material, positive electrode plate, lithium-ion battery, and electrical device
Provided are a positive active material, a positive electrode plate, a lithium-ion battery, and an electric device. The positive active material includes lithium iron phosphate particles. A volume percentage of the lithium iron phosphate particles having a particle size smaller than 1 μm is x, and a volume percentage of the lithium iron phosphate particles having a particle size greater than 5 μm is z, z/x ranging from 0.5 to 2.8.
1 . A positive active material, comprising lithium iron phosphate particles, wherein:
a volume percentage of the lithium iron phosphate particles having a particle size smaller than 1 μm is x, x is 14%;
a volume percentage of the lithium iron phosphate particles having a particle size not smaller than 1 μm and not greater than 5 μm is y, y ranges from 51% to 55%;
a volume percentage of the lithium iron phosphate particles having a particle size greater than 5 μm and smaller than 20 μm is z, z ranges from 31% to 35%;
z/x ranges from 2.2 to 2.5;
a volume of a unit cell of the lithium iron phosphate particles is V in units of Å 3 , V ranges from 294.2 to 294.3; and
(z/x)*(V/300) ranges from 2.16 Å 3 to 2.45 Å 3 .
2 . A positive electrode plate, comprising:
a positive current collector; and
a positive active substance layer coated on the positive current collector, the positive active substance layer comprising a positive active material, the positive active material comprising lithium iron phosphate particles, wherein:
a volume percentage of the lithium iron phosphate particles having a particle size smaller than 1 μm is x, x is 14%;
a volume percentage of the lithium iron phosphate particles having a particle size not smaller than 1 μm and not greater than 5 μm is y, y ranges from 51% to 55%;
a volume percentage of the lithium iron phosphate particles having a particle size greater than 5 μm and smaller than 20 μm is z, z ranges from 31% to 35%;
z/x ranges from 2.2 to 2.5;
a volume of a unit cell of the lithium iron phosphate particles is V in units of Å 3 , V ranges from 294.2 to 294.3; and
(z/x)*(V/300) ranges from 2.16 Å 3 to 2.45 Å 3 .
3 . A lithium-ion battery, comprising:
a housing; and
an electrode assembly disposed in the housing, the electrode assembly comprising a negative electrode plate and a positive electrode plate, wherein the positive electrode plate comprises a positive current collector and a positive active substance layer coated on the positive current collector, the positive active substance layer comprising a positive active material, the positive active material comprising lithium iron phosphate particles, wherein:
a volume percentage of the lithium iron phosphate particles having a particle size smaller than 1 μm is x, x is 14%;
a volume percentage of the lithium iron phosphate particles having a particle size not smaller than 1 μm and not greater than 5 μm is y, y ranges from 51% to 55%;
a volume percentage of the lithium iron phosphate particles having a particle size greater than 5 μm and smaller than 20 μm is z, z ranges from 31% to 35%;
z/x ranges from 2.2 to 2.5;
a volume of a unit cell of the lithium iron phosphate particles is V in units of Å 3 , V ranges from 294.2 to 294.3; and
(z/x)*(V/300) ranges from 2.16 Å 3 to 2.45 Å 3 .
4 . An electrical device, comprising the lithium-ion battery according to claim 3 .