Method of making negative electrode material
A method of making negative electrode material having silicon and silicate includes the steps of providing raw materials for contact fusion, heating the raw materials to form materials with a contact-fusion state, mixing silicon and the materials after forming contact-fusion to form a composite material, and vaporizing the composite materials on the deposition zone after the mixing step. The heating step is performed at the temperatures between the lowest melting temperature of the materials with the contact-fusion state and 1400° C. The deposited composite materials can be optionally heat treated, pulverized, and/or coated with carbon. Also provided is a negative electrode material of silicon and silicate made from the steps described above. The negative electrode material of silicon and silicate can be an Li—Mg silicate having silicon powder dispersed therein, the Li—Mg silicate forming a uniform interface on surfaces of the silicon powder.
1 . A method of making negative electrode material comprising silicon and silicate, comprising the steps of:
providing raw materials for contact-fusion;
heating the raw materials to form materials with a contact-fusion state;
mixing silicon and the materials after forming contact-fusion to form a composite material; and
vaporizing the composite materials after the mixing step,
wherein the heating step is performed at the temperatures between the lowest melting temperature of the materials with the contact-fusion state and 1400° C.
2 . The method according to claim 1 , wherein the raw materials in the providing step include SiO 2 , Li 2 O and MgO.
3 . The method according to claim 2 , wherein the raw materials in the providing step include MgO—SiO 2 powder and Li 2 CO 3 powder.
4 . The method according to claim 2 , wherein the raw materials have a melting point that is 1400° C. or higher.
5 . The method according to claim 1 , wherein the raw materials in the providing step include at least one of a Li 2 O precursor and an MgO precursor having a melting point that is 900° C. or lower and at least one of SiO 2 , Li 2 O and MgO having a melting point that is 1400° C. or higher.
6 . A method of making negative electrode material comprising silicon and silicate, comprising the steps of:
providing raw materials for contact-fusion;
heating the raw materials to form materials having a contact-fusion state;
mixing silicon and the materials after forming contact-fusion to form composite materials;
vaporizing the composite materials after the mixing step; and
at least one of the steps of heat treating the vaporized composite materials, pulverizing the vaporized composite materials, and coating the vaporized composite materials with carbon, wherein the heating step is performed at the temperatures between the lowest melting temperature of the materials with the contact fusion state and 1400° C.