Granted Patent B2

US 12,567,442 · App. 17/858,572 · Granted Mar 3, 2026

Inventor: Richard Bradshaw (Tucson, AZ)

Assignee: International Business Machines Corporation

G11B5/73923G11B5/7373G11B5/78

Abstract

Claims (37)

1 . A method, comprising:

forming an underlayer of a magnetic recording medium, the underlayer comprising:

encapsulated nanoparticles each comprising a magnetic nanoparticle encapsulated by an aromatic polymer, and

a polymeric binder binding the encapsulated nanoparticles; and

curing the underlayer by irradiating the underlayer for causing crosslinking of the polymeric binder; and

forming a magnetic recording layer directly on the cured underlayer,

wherein forming the underlayer includes mixing the polymeric binder with the encapsulated nanoparticles and a solvent to form a mixture; spray coating the mixture onto a structure as a sprayed-on aerosol coating; at least partially drying the sprayed-on aerosol coating; and radiating the at least partially dried coating for causing crosslinking of the polymeric binder to restrict further expansion or contraction in the underlayer,

wherein the solvent includes water,

wherein the binder is hydrophobic, and

wherein the polymeric binder collapses onto the encapsulated nanoparticles as the solvent is removed during the drying.

2 . The method as recited in claim 1 , wherein the magnetic recording layer is substantially not intermixed with the underlayer.

3 . The method as recited in claim 1 , wherein the magnetic nanoparticles have an average magnetic field strength of less than 200 Oersted (Oe).

4 . The method as recited in claim 1 , wherein an average concentration of the encapsulated nanoparticles in the underlayer is greater than 35 vol %.

5 . The method as recited in claim 1 , wherein the underlayer is characterized as having an onset of at least 35° centigrade in a tensile storage modulus (E′) vs. temperature plot.

6 . The method as recited in claim 1 , wherein the underlayer is characterized as having an absolute value of a tensile storage modulus (E′) thereof greater than 10 GPa.

7 . The method as recited in claim 1 , wherein the underlayer is electrically conductive.

8 . The method as recited in claim 1 , wherein an average diameter of the magnetic nanoparticles is in a range of 2 nanometers to 15 nanometers.

9 . The method as recited in claim 1 , wherein the aromatic polymer includes a carbamate.

10 . The method as recited in claim 1 , wherein an average thickness of the aromatic polymer is in a range of 1 nanometer to 8 nanometers.

11 . The method as recited in claim 1 , wherein the magnetic recording medium is a magnetic recording tape.

12 . The method as recited in claim 1 , wherein the solvent includes the water and tetrahydrofuran (THF).

13 . The method as recited in claim 12 , wherein the water and the THF are present in the solvent in relative concentrations that render the solvent azeotropic.

14 . The method as recited in claim 12 , wherein the water is present in the solvent in a range of 7 wt % to 8 wt % relative to a total weight of the solvent.

15 . The method as recited in claim 1 , wherein the cured underlayer is electrically conductive along an entire length thereof, wherein the encapsulated nanoparticles are randomly aligned in the cured applied mixture.

16 . The method as recited in claim 1 , wherein the encapsulated nanoparticles are randomly aligned in the cured underlayer.

17 . A method, comprising:

forming an underlayer of a magnetic recording medium by spray coating a mixture of a magnetic nanoparticles, aromatic polymer, and polymeric binder onto a structure as a sprayed-on aerosol coating, wherein the mixture includes a solvent comprising water and a relatively more volatile organic co-solvent;

at least partially drying the sprayed-on aerosol coating in a manner that drives chains of the polymeric binder to uncoil and move toward a theta condition thereof; and

curing the underlayer by irradiating the underlayer for causing crosslinking of the polymeric binder while the polymeric binder is in the theta condition.

18 . A method, comprising:

forming an underlayer of a magnetic recording medium, the underlayer comprising:

encapsulated nanoparticles each comprising a magnetic nanoparticle encapsulated by an aromatic polymer, and

a polymeric binder binding the encapsulated nanoparticles; and

curing the underlayer by irradiating the underlayer for causing crosslinking of the polymeric binder,

wherein forming the underlayer includes mixing the polymeric binder with the encapsulated nanoparticles and a solvent to form a mixture; applying the mixture onto a structure; at least partially drying the applied mixture; and radiating the at least partially dried applied mixture for causing crosslinking of the polymeric binder,

wherein the polymeric binder collapses onto the encapsulated nanoparticles as the solvent is removed during the drying.

19 . The method as recited in claim 6 , wherein the solvent comprises a relatively more volatile component and a relatively less volatile component, wherein the drying is performed such that the relatively more volatile component leaves first during the drying for urging the binder toward a theta condition thereof and for causing the polymeric binder to collapse onto the encapsulated nanoparticles during the drying, wherein the at least partially dried applied mixture is cured to cause crosslinking to restrict further expansion or contraction in the underlayer.

Assignments (1)

Continuity (2)

References Cited (235)