Through-glass via-hole formation method
A through-glass via-hole formation method includes: forming a hole-shaped deformed region extending in a thickness direction of a glass substrate by irradiating the glass substrate with a laser beam at an energy intensity not exceeding an ablation threshold of the glass substrate; and forming a via-hole through the glass substrate along the deformed region by immersing the glass substrate in an etching solution such that the deformed region is etched and removed, wherein an etching solution having a first concentration is used as the etching solution to allow the via-hole to have a first aspect ratio, and an etching solution having a second concentration greater than the first concentration is used as the etching solution to allow the via-hole to have a second aspect ratio smaller than the first aspect ratio.
1 . A through-glass via-hole formation method, comprising:
forming a hole-shaped deformed region extending from an upper surface to a lower surface of a glass substrate by irradiating the glass substrate with a laser beam at an energy intensity not exceeding an ablation threshold of the glass substrate, thereby causing a permanent physicochemical structural deformation in the irradiated region such that the irradiated region is etched faster than a non-irradiated region;
immersing the glass substrate in a first etching solution having a first concentration to preferentially etch and remove the deformed region and open a via-hole through the glass substrate with a first aspect ratio; and
subsequently immersing the glass substrate in a second etching solution having a second concentration greater than the first concentration to increase a diameter of the via-hole relative to its length and reduce the aspect ratio to a second aspect ratio smaller than the first aspect ratio,
wherein a difference in etching velocity between the deformed region and the non-irradiated region when using the first etching solution is greater than a difference in etching velocity between the deformed region and the non-irradiated region when using the second etching solution,
wherein the aspect ratio is defined as a ratio of a via-hole length to a via-hole diameter.
2 . The through-glass via-hole formation method according to claim 1 , wherein the deformed region has a cross-sectional area smaller than a cross-sectional area of the via-hole formed after the subsequently immersing step.
3 . The through-glass via-hole formation method according to claim 1 , wherein lowering a temperature of the first etching solution enables the via-hole to have a greater aspect ratio than the first aspect ratio.