Light-emitting element solvent, photodegradable thickener, light-emitting element ink, and method for manufacturing display device
A method for manufacturing a display device comprises the steps of: spraying, on a target substrate having a first electrode and a second electrode formed thereon, an element ink comprising a first element solvent and light-emitting elements dispersed in the first element solvent; forming a second element solvent in which at least some bonds of the first element solvent are decomposed by irradiating light to the first element solvent and mounting the light-emitting elements on the first electrode and the second electrode; and removing the second element solvent.
1 . A light-emitting element solvent dispersing semiconductor crystals, the light-emitting element solvent comprising:
a photodegradable functional group in which at least one chemical bond is capable of being decomposed by irradiated light and
a first functional group and a second functional group different from each other and bonded to the photodegradable functional group,
wherein the at least one chemical bond of the photodegradable functional group is capable of being decomposed by the irradiated light to form at least one photodegraded fragment,
wherein the first functional group and the second functional group are each independently represented by Chemical Formula 1, and
wherein the light-emitting element solvent is any one of compounds represented by Chemical Formulae 2 through 5:
wherein n is an integer of 1 to 5, a sum of an n value of the first functional group and an n value of the second functional group is in a range of 2 to 6, and
R 5 is any one selected from a C1-C5 alkyl group, a C2-C5 alkenyl group, a C2-C5 alkynyl group, a C1-C5 alkyl ether group, and a C2-C5 alkenyl ether group, and
and
wherein R 1 and R 2 are represented by Chemical Formula 1, a sum of an n value in Chemical Formula 1 of R 1 and an n value in Chemical Formula 1 of R 2 is in a range of 2 to 6, and
R 3 and R 4 are each independently any one selected from a C1-C10 alkyl group, a C2-C10 alkenyl group, a C2-C10 alkynyl group, a C1-C10 alkyl ether group, and a C2-C10 alkenyl ether group.
2 . The light-emitting element solvent of claim 1 , being a compound represented by Chemical Formula 6:
3 . The light-emitting element solvent of claim 1 , wherein a first element solvent is represented by Chemical Formulae 2 through 5, and
when the first element solvent irradiated with the light, the first element solvent forms a second element solvent comprising the at least one photodegraded fragment.
4 . The light-emitting element solvent of claim 3 , wherein the at least one photodegraded fragment is bonded to one selected from the first functional group and the second functional group.
5 . The light-emitting element solvent of claim 3 , wherein a molecular weight of the second element solvent is 50% or less of a molecular weight of the first element solvent.
6 . The light-emitting element solvent of claim 5 , wherein the first element solvent has a viscosity of 7 to 15 cp, and
the second element solvent has a viscosity of 5 cp or less.
7 . A light-emitting element ink comprising:
a light-emitting element comprising a semiconductor crystal and an insulating film around an outer peripheral surface of the semiconductor crystal; and
a light-emitting element solvent in which one or more light-emitting elements are dispersed,
wherein the light-emitting element solvent comprises:
a photodegradable functional group in which at least one chemical bond is capable of being decomposed by irradiated light; and
a first functional group and a second functional group bonded to the photodegradable functional group and each independently represented by Chemical Formula 1, and
the light-emitting element solvent is any one of compounds represented by Chemical Formulae 2 through 5:
wherein n is an integer of 1 to 5, a sum of an n value of the first functional group and an n value of the second functional group is in a range of 2 to 6, and
R 5 is any one selected from a C1-C5 alkyl group, a C2-C5 alkenyl group, a C2-C5 alkynyl group, a C1-C5 alkyl ether group, and a C2-C5 alkenyl ether group, and
wherein R 1 and R 2 are represented by Chemical Formula 1, a sum of an n value in Chemical Formula 1 of R 1 and an n value in Chemical Formula 1 of R 2 is in a range of 2 to 6, and
R 3 and R 4 are each independently any one selected from a C1-C10 alkyl group, a C2-C10 alkenyl group, a C2-C10 alkynyl group, a C1-C10 alkyl ether group, and a C2-C10 alkenyl ether group.
8 . The light-emitting element ink of claim 7 , wherein the light-emitting element solvent is a compound represented by Chemical Formula 6:
9 . The light-emitting element ink of claim 7 , wherein the at least one chemical bond of the photodegradable functional group of the light-emitting element solvent is capable of being decomposed by the irradiated light to form at least one photodegraded fragment, and
the at least one photodegraded fragment is bonded to at least one of the first functional group or the second functional group.
10 . The light-emitting element ink of claim 9 , wherein a viscosity of the light-emitting element solvent is reduced as the at least one chemical bond of the photodegradable functional group is decomposed by the irradiated light.
11 . The light-emitting element ink of claim 10 , wherein the semiconductor crystal comprises:
a first semiconductor layer doped with a first conductivity type;
a second semiconductor layer doped with a second conductivity type having a different polarity from the first conductivity type; and
an active layer between the first semiconductor layer and the second semiconductor layer.