Methods of cooling glasses post-ion exchange
Methods of manufacturing a glass-based article comprise: exposing an alkali-aluminosilicate glass-based substrate comprising opposing first and second surfaces defining a substrate thickness (t) to an ion exchange treatment to produce an ion exchanged glass-based substrate; and thereafter cooling the ion exchanged glass-based substrate in an environment having a starting temperature that is less than or equal to 200° C. and then reducing the temperature at a rate of greater than or equal to 3.3° C./minute to form the glass-based article.
1 . A method of manufacturing a glass-based article comprising:
conducting an ion exchange treatment and a cooling in a vessel that defines: a reservoir containing a molten salt bath, a head space within the vessel above the molten salt bath, and a vent in fluid communication with the head space, wherein a movable partition resides within the vessel such that a first position of the movable partition puts the reservoir in fluid communication with the head space and a second position of the movable partition separates the reservoir from the head space;
the ion exchange treatment comprising: exposing an alkali-aluminosilicate glass-based substrate comprising opposing first and second surfaces defining a substrate thickness (t) to a molten salt bath disposed in the reservoir to form an ion exchanged glass-based substrate, the substrate thickness (t) being greater than or equal to 25 micrometers and less than or equal to 125 micrometers; and
thereafter the cooling of the ion exchanged glass-based substrate in the head space comprising:
moving the movable partition to the second position;
setting a starting temperature of the head space to less than or equal to 200° C.; and
reducing the starting temperature at a rate of greater than or equal to 3.3° C./minute and less than or equal to 25° C./minute;
wherein upon cooling for a cooling duration, the glass-based article is formed.
2 . The method of claim 1 , wherein the rate is greater than or equal to 6.0° C./minute.
3 . The method of claim 1 , wherein:
the ion exchange treatment comprises:
moving the movable partition to the first position;
immersing the alkali-aluminosilicate glass-based substrate in the molten salt bath and moving the movable partition to the second position;
obtaining the ion exchanged glass-based substrate after a treatment duration defined by time that the alkali-aluminosilicate glass-based substrate resides in the molten salt bath;
moving the movable partition to the first position and withdrawing the ion exchanged glass-based substrate from the molten salt bath into the head space; and
holding the ion exchanged glass-based substrate in the head space in place above the molten salt bath for a drip duration defined by time after withdrawal of the ion exchanged glass-based substrate out the reservoir and into the head space before the cooling begins, wherein any residual salt drips off of the ion exchanged glass-based substrate back into the reservoir.
4 . The method of claim 3 , wherein the drip duration excludes any setting of a temperature of the head space to a temperature of greater than 200° C.
5 . The method of claim 1 , wherein the molten salt bath is at a temperature in the range of greater than or equal to 360° C. to less than or equal to 500° C.
6 . The method of claim 1 , wherein the cooling duration is less than or equal to 60 minutes.
7 . The method of claim 1 , wherein the cooling duration is less than or equal to 30 minutes.
8 . The method of claim 1 , wherein the cooling is conducted until the head space is at a temperature of less than or equal to 70° C.
9 . The method of claim 1 , wherein the cooling is conducted until the head space is at a temperature in the range of greater than or equal to 50° C. to less than or equal to 70° C.
10 . The method of claim 1 , wherein the glass-based substrate is lithium-free.
11 . The method of claim 1 , wherein the glass-based substrate comprises in mole percentages: 66-70% SiO 2 , 9-12% Al 2 O 3 , 14-16% Na 2 O, 4.5-5.5% MgO, 0.01-0.09% CaO, and 0.10-0.20% SnO.
12 . The method of claim 1 , wherein the glass-based substrate comprises in mole percentages ±0.5%: 69% SiO 2 , 10% Al 2 O 3 , 15% Na 2 O, 5% MgO, 0.1% CaO, and 0.2% SnO.
13 . The method of claim 1 , wherein the glass-based article comprises a maximum compressive stress (CS max ) of greater than or equal to 780 MPa.
14 . The method of claim 1 , wherein the glass-based article comprises a maximum compressive stress (CS max ) of greater than or equal to 780 MPa and a depth of layer (DOL K ) of greater than or equal to 0.19·t.
15 . The method of claim 1 , wherein prior to the ion exchange treatment, the glass-based substrate is preheated in the head space.
16 . The method of claim 1 , the glass-based substrate comprises a plurality of glass-based substrates loaded into a fixture.
17 . A glass-based article made in accordance with claim 1 .
18 . The glass-based article of claim 17 comprising a maximum compressive stress (CS max ) of greater than or equal to 750 MPa.
19 . The glass-based article of claim 17 comprising a depth of layer (DOL K ) with respect to potassium of greater than or equal to 0.19·t micrometers.
20 . The glass-based article of claim 17 comprising a maximum compressive stress (CS max ) of greater than or equal to 750 MPa and a depth of layer (DOL K ) of greater than or equal to 0.19·t.
21 . A consumer electronic product comprising:
a housing comprising a front surface, a back surface, and side surfaces;
electrical components at least partially within the housing, the electrical components comprising at least a controller, a memory, and a display, the display at or adjacent the front surface of the housing; and
a cover disposed over the display;
wherein a portion of at least one of the housing and the cover comprises the glass-based article of claim 17 .