Supercapacitor with NiO/Fe
A nanocomposite electrode including a substrate, a binding compound, a conductive additive, and NiO/Fe 2 VO 4 nanoparticles. The NiO/Fe 2 VO 4 nanoparticles have a substantially spherical shape. A mixture of the binding compound, the conductive additive and the NiO/Fe 2 VO 4 nanoparticles, is at least partially coated on a first surface of the substrate. A method of making the NiO/Fe 2 VO 4 nanoparticles is described.
1 . A supercapacitor device, comprising:
two symmetrically facing nanocomposite electrodes, wherein each nanocomposite electrode comprises:
a substrate;
a binding compound;
a conductive additive; and
NiO/Fe 2 VO 4 nanoparticles,
wherein the NiO/Fe 2 VO 4 nanoparticles have a substantially spherical shape,
wherein a mixture of the binding compound, the conductive additive and the NiO/Fe 2 VO 4 nanoparticles is at least partially coated on a first surface of the substrate, and
wherein the first surfaces of the nanocomposite electrodes coated with the mixture face inwards; and
wherein an anhydrous gel electrolyte is disposed between and is in contact with the first surfaces.
2 . The supercapacitor of claim 1 , wherein the NiO/Fe 2 VO 4 nanoparticles have an average diameter of 1-20 nanometers (nm).
3 . The supercapacitor of claim 1 , wherein the NiO/Fe 2 VO 4 nanoparticles are aggregated and have an average aggregate size of 1 to 50 micrometers (μm).
4 . The supercapacitor of claim 1 , wherein the NiO/Fe 2 VO 4 nanoparticles are aggregated and form an interconnected chain.
5 . The supercapacitor of claim 1 , wherein the NiO/Fe 2 VO 4 nanoparticles form an interconnected chain while dispersed in a matrix of the conductive additive.
6 . The supercapacitor of claim 1 , wherein the mixture comprises 5-10 wt. % of the binding compound, 70-90 wt. % of the conductive additive, and 1-20 wt. % of the NiO/Fe 2 VO 4 nanoparticles, based on a total weight of the mixture.
7 . The supercapacitor of claim 1 , wherein the mixture comprises 70-90 wt. % C, 0.5-5 wt. % V, 1-10 wt. % Fe, and 1-10 wt. % Ni based on the total weight of the mixture.
8 . The supercapacitor of claim 1 , wherein the elements V, C, Fe, and Ni are homogeneously distributed on the first surface of the substrate.
9 . The supercapacitor of claim 1 , wherein the substrate is made from at least one material selected from the group consisting of stainless steel, aluminum, nickel, copper, platinum, zinc, tungsten, and titanium.
10 . The supercapacitor of claim 1 , wherein the conductive additive is at least one selected from the group consisting of graphite, activated carbon, reduced graphene oxide, carbon nanotubes, carbon nanofibers, and carbon black.
11 . The supercapacitor of claim 1 , wherein the binding compound is at least one selected from the group consisting of polyvinylidene fluoride (PVDF) and N-methyl pyrrolidone (NMP).
12 . The supercapacitor of claim 1 , wherein the first surface of the substrate is hydrophilic.
13 . The supercapacitor of claim 1 , wherein the first surface of the substrate has a water contact angle less than 37°.
14 . The supercapacitor device of claim 1 , wherein the electrolyte is a glycerol/KOH gel electrolyte.
15 . The supercapacitor device of claim 1 , having a specific capacitance of 250-300 Farad per gram (F/g) at a current density of 1-5 ampere per gram (A/g).
16 . A battery, comprising 2-10 of the supercapacitor devices of claim 1 connected in parallel and/or series.